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Reinforced flame-retarding PA6/POK (Polyamide 6/Polyketone) alloy material and preparation method thereof

A technology of alloy materials and flame retardants, applied in the field of reinforced flame retardant PA6/POK alloy materials and their preparation, can solve the problem of low molding efficiency of nylon 6 reinforced flame retardant materials, high wet volume resistivity, and the amount of flame retardants used Large and other problems, to achieve the effect of increasing wet volume resistivity, improving environmental protection performance, and reducing water absorption

Inactive Publication Date: 2018-05-01
横店集团得邦工程塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problems of low molding efficiency, poor dimensional stability, high wet volume resistivity, and large amount of flame retardants used in the current electrical industry for nylon 6 reinforced flame retardant materials, and provide a mechanical performance and processing method. Reinforced flame retardant PA6 / POK alloy material with excellent performance

Method used

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  • Reinforced flame-retarding PA6/POK (Polyamide 6/Polyketone) alloy material and preparation method thereof
  • Reinforced flame-retarding PA6/POK (Polyamide 6/Polyketone) alloy material and preparation method thereof
  • Reinforced flame-retarding PA6/POK (Polyamide 6/Polyketone) alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A kind of reinforced flame-retardant PA6 / POK alloy material, comprising by weight:

[0030]

[0031] Put the above materials into the mixer and mix them evenly, then put the mixed materials into the main lower barrel of the extruder and granulate through the extruder. During the extrusion process, 30 parts of chopped fibers pass through the side feeding Add by way, keep the vacuum open, the temperature of each temperature zone of the extruder is 210°C (zone 1), 230°C (zone 2), 220°C (zone 3), 210°C (zone 4), 175°C (zone 4) , 175°C (zone five), 180°C (zone six), 190°C (zone seven), 210°C (zone eight), and 235°C (head).

[0032] The vertical combustion performance of the above-mentioned composite material is 1.6mm V-0, the water absorption rate is 0.406%, and the wet volume resistivity is 3.8×10 14 Ω cm, the mechanical properties of the material are: tensile strength 150.5MPa, elongation at break 6.1%, bending strength 225.5MPa, notched impact strength 14.1kJ / m 2 , u...

Embodiment 2

[0034] The present embodiment differs from Example 1 in that: first take the following materials in parts by weight:

[0035]

[0036] Put the above materials into the mixer and mix them evenly, then put the mixed materials into the main lower barrel of the extruder and granulate through the extruder. During the extrusion process, 30 parts of chopped fibers pass through the side feeding Add by way, keep the vacuum open, the temperature of each temperature zone of the extruder is 210°C (zone 1), 230°C (zone 2), 220°C (zone 3), 210°C (zone 4), 175°C (zone 4) , 175°C (zone five), 180°C (zone six), 190°C (zone seven), 210°C (zone eight), and 235°C (head).

[0037] The vertical combustion performance of the composite material obtained above is 1.6mm V-0, the water absorption rate is 0.428%, and the wet volume resistivity is 4.7×10 14 Ω cm, the mechanical properties of the material are: tensile strength 151.6MPa, elongation at break 6.3%, bending strength 227.5MPa, notched impac...

Embodiment 3

[0039] The present embodiment differs from Example 1 in that: first take the following materials in parts by weight:

[0040]

[0041] Put the above materials into the mixer and mix them evenly, then put the mixed materials into the main lower barrel of the extruder and granulate through the extruder. During the extrusion process, 30 parts of chopped fibers pass through the side feeding Add by way, keep the vacuum open, the temperature of each temperature zone of the extruder is 210°C (zone 1), 230°C (zone 2), 220°C (zone 3), 210°C (zone 4), 175°C (zone 4) , 175°C (zone five), 180°C (zone six), 190°C (zone seven), 210°C (zone eight), and 235°C (head).

[0042] The vertical combustion performance of the composite material obtained above is 1.6mm V-0, the water absorption rate is 0.386%, and the wet volume resistivity is 4.6×10 14 Ω cm, the mechanical properties of the material are: tensile strength 152.5MPa, elongation at break 5.1%, bending strength 228.5MPa, notched impac...

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Abstract

The invention discloses a reinforced flame-retarding PA6 / POK (Polyamide 6 / Polyketone) alloy material. The reinforced flame-retarding PA6 / POK alloy material is characterized by being prepared from thefollowing components in parts by weight: 50 to 90 parts of nylon resin, 10 to 50 parts of polyketone resin, 10 to 20 parts of a flame retardant, 4 to 8 parts of a flame-retarding synergist, 3 to 6 parts of a compatilizer, 20 to 35 parts of chopped fibers, 0.35 to 0.65 part of an antioxidant and 0.4 to 0.7 part of a lubricant. The invention further discloses a preparation method of the reinforced flame-retarding PA6 / POK alloy material. The alloy material disclosed by the invention has the characteristics of low water absorption ratio, high wet-state volume resistivity, stable size, good mechanical properties, good environment friendliness and the like.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a reinforced flame-retardant PA6 / POK alloy material and a preparation method thereof. Background technique [0002] Nylon 6 (PA6) is widely used in electronic appliances, automobiles, home appliances and other industries. However, caprolactam, the monomer used to produce nylon 6, has certain toxicity and can decompose toxic nitrogen oxides when heated. The production of nylon 6 will cause certain harm to people and the environment in terms of monomer treatment and synthesis process. Therefore, as the domestic environment continues to deteriorate, the state's efforts to improve the environment are gradually increasing, so higher environmental protection requirements are also put forward for manufacturers of nylon 6. This not only increases the manufacturing cost of the enterprise, but also affects the production capacity, which leads to the continuous rise o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L61/02C08L51/06C08L51/04C08L51/00C08L73/00C08K13/06C08K9/06C08K7/14C08K5/03C08K3/22
Inventor 卢津强宋向前周立辉卢勇
Owner 横店集团得邦工程塑料有限公司
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