Green and environmentally friendly mesoporous silicon nano-sustained-release gel for rapid and efficient removal of organic pollutants
An organic pollutant, green and environmentally friendly technology, applied in the direction of separation methods, dispersed particle separation, chemical instruments and methods, etc., can solve the problems of sealant loss of function, furniture wear and tear, and it is difficult to eliminate volatile organic compounds, so as to improve The effect of stability
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[0035] Preparation of bismuth vanadate
[0036] Dissolve 0.0015 mol of sodium vanadate and 0.006 mol of bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it in a constant temperature drying box After reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01 mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.
[0037] At room temperature, 8 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 15 parts by weight of bismuth vanadate, 0.08 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and the mixture was uniform to obtain the first mi...
Embodiment 1
[0039] In the container, dissolve 5 parts by weight of polyvinyl alcohol 2488 and 0.8 parts by weight of carbomer in 100 parts by weight of water; add 0.08 parts by weight of mesoporous silicon (Shanghai carboxyphenanthrene, MSNs-90) into the container, and Raise the temperature to 55 degrees Celsius and keep it for 24 hours; cool to normal temperature, add 2 parts by weight of imidazolidinone and 0.04 parts by weight of nano-modified niobium oxide photocatalytic oxidant, mix well, adjust the pH value to 7, and obtain a slow-release gel.
Embodiment 2
[0041] In a container, dissolve 2 parts by weight of polyvinyl alcohol 2488 and 0.6 parts by weight of carbomer in 100 parts by weight of water; add 0.05 parts by weight of mesoporous silicon (Shanghai carboxyphenanthrene, MSNs-90) into the container, and Raise the temperature to 55 degrees Celsius and keep it for 24 hours; cool to normal temperature, add 2 parts by weight of imidazolidinone and 0.05 parts by weight of nano-modified niobium oxide photocatalytic oxidant, mix well, adjust the pH value to 7, and obtain a slow-release gel.
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