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Seawater desulfurization recovery system evaluation simulation experiment method and device

A technology for simulating experiments and restoring systems. It is used in seawater treatment, chemical instruments and methods, and water pollutants. It can solve the problems of inability to systematically evaluate the processing capacity of the device, inconvenient evaluation, and complex changes in power plant loads.

Pending Publication Date: 2018-06-08
BEIJING LONGYUAN ENVIRONMENTAL ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, to evaluate the actual application effect of the above-mentioned patents, it is often necessary to establish a complete set of equipment in the power plant and operate it before actually detecting whether it meets the design requirements. This has the following shortcomings: First, the load of the power plant is complex, and the processing capacity of the equipment cannot be systematically evaluated ; Second, due to sea water quality and seasonal changes in different regions, the evaluation of the system needs to span time and space; third, the on-site evaluation cycle is long, the operating environment is poor, the evaluation is inconvenient, and the cost is high; Reliability; Fifth, there is no early evaluation method. Once the system is built and operated, it is found that there are design defects, and it is difficult to rebuild and the economic cost is high.

Method used

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  • Seawater desulfurization recovery system evaluation simulation experiment method and device
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  • Seawater desulfurization recovery system evaluation simulation experiment method and device

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Embodiment 1

[0029] A simulation experiment method for evaluation of seawater desulfurization recovery system, comprising the following steps:

[0030] (1) first add sodium sulfite in a part of natural seawater, obtain acid seawater after dissolving, and measure S (IV) concentration and pH value; The above-mentioned acid seawater (volume is V 1 ) is injected into the liquid storage tank through the filling port on the upper end cover of the liquid storage tank, and then add natural seawater through the filling port (the volume is V 2 ) is blended once (the volume after mixing is V 1 +V 2 );

[0031] (2) After the above filling is completed, quickly start the circulating water pump, and inject the primary mixed seawater into the oxidation tank through the circulating water pump (the liquid flow rate is Q L ), when the liquid level reaches the outlet of the oxidation tank, quickly start the aeration pump or start the DC power supply at the same time, and perform aeration chemical oxidatio...

Embodiment 2

[0037] Simulation experiment of seawater desulfurization recovery system evaluation

[0038] First use 26°C natural seawater and Na 2 SO 3 Prepare 1.27L of acidic seawater, wherein the concentration of S(IV) is 0.2g / L, and the pH is 3, fill it into the liquid storage tank, and then add 2.53L of the above-mentioned natural seawater to obtain 3.80L of once-blended seawater (acidic seawater Seawater / natural seawater is about 1:2), quickly start the circulating water pump, mix seawater once into the oxidation tank, and control Q L is 7.63L / min, when the liquid level reaches the outlet of the oxidation tank, start the aeration pump quickly to carry out aeration treatment, where Q G =3L / min, the height between the aeration head and the water outlet of the oxidation tank is 0.33m, start timing at the same time, measure and record the S(IV) concentration, pH and DO of the seawater mixed once for 1min, 2min, and 3min respectively, After reaching 3min, stop the above process. Recons...

Embodiment 3

[0048] Simulation experiment of seawater desulfurization recovery system evaluation

[0049] Use natural seawater and Na at 5°C, 10°C, 16°C or 22°C, respectively 2 SO 3 Prepare 1.27L of acidic seawater, wherein the concentration of S(IV) is 0.2g / L, and the pH is 3, fill it into the liquid storage tank, and then add 2.53L of the above-mentioned natural seawater to obtain 3.80L of once-blended seawater (acidic seawater Seawater / natural seawater is about 1:2), quickly start the circulating water pump, mix seawater once into the oxidation tank, and control QL When the liquid level reaches the outlet of the oxidation tank, start the aeration pump quickly to carry out aeration treatment or aeration combined electrochemical oxidation treatment (the anode uses electrochemically modified polyacrylonitrile-based carbon fiber brushes, and the cathode uses untreated carbon fiber brushes). Modified polyacrylonitrile-based carbon fiber brushes, the DC power supply adopts a constant current...

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Abstract

The invention discloses a seawater desulfurization recovery system evaluation simulation experiment method and device. The method comprises the following steps: adding sodium sulfite into natural seawater to obtain acidic seawater; then blending the acidic seawater with the natural seawater for the first time; pumping the preliminarily blended seawater into an oxidization pool; performing aeration-based chemical oxidization or aeration-based composite electrochemical oxidization treatment on the preliminarily blended seawater in the oxidization pool, and discharging gas through the oxidizationpool; enabling liquid flowing out of the oxidization pool to reflow into a liquid storage pool for mixing; when oxidization treatment time meets a requirement, ending the process, and completing thesimulation, with circulating water, of actual application that the preliminarily blended seawater is oxidized by a direct water drainage mode; finally, taking out part of the oxidized preliminarily blended seawater, blending the taken-out preliminarily blended seawater with the natural seawater for the second time to obtain secondarily blended seawater, namely the drained seawater. The seawater desulfurization recovery system evaluation simulation experiment method can change operation parameters of a seawater desulfurization recovery system, so as to detect and evaluate the treatment capacity, the energy consumption and the effect of the seawater desulfurization recovery system.

Description

technical field [0001] The invention relates to the technical field of industrial water treatment, in particular to a simulation experiment method and device for evaluation of seawater desulfurization recovery systems. Background technique [0002] Seawater desulfurization recovery system is an important part of seawater desulfurization technology. The drainage of the absorption tower is acidic (pH about 3), and due to the large amount of S(IV), the chemical oxygen demand (COD) is high, so it must be treated by the seawater recovery system before it can be discharged. The eluate from the absorption tower is first mixed with fresh seawater, the pH value rises from about 3 to about 5, and then enters the aeration tank. Forced convection of air into the aeration tank, so that the dissolved oxygen in the seawater gradually reaches saturation, and the dissolved oxygen oxidizes S(IV) to SO 4 2- , while CO in seawater 3 2- and the H in the effluent of the absorption tower + T...

Claims

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Application Information

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IPC IPC(8): C02F1/72C02F1/46C02F103/18C02F101/10C02F103/08
CPCC02F1/4604C02F1/72C02F2103/08C02F2103/18C02F2101/101
Inventor 徐海波王小立芦永红薛军田高峰张静伟
Owner BEIJING LONGYUAN ENVIRONMENTAL ENG CO LTD