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Green Fe-based alloy coating

An iron-based alloy and coating technology, applied in the field of surface coating materials, can solve the problems of high brittleness, high residual stress of pure iron coating, and easy oxidation of the plating solution.

Inactive Publication Date: 2018-06-08
刘辉
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high residual stress, high brittleness and easy oxidation of the plating solution, the pure iron coating has been limited in application for a long time.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment example 1

[0015] The raw materials for the preparation of the green iron-based alloy coating include: the base material is widely used GCrl5 bearing steel, and the size is 18×10mm. The preparation steps of the green iron-based alloy coating are as follows: the end face of the sample is subjected to 80 # 、320 # 、1000 # , 2000 # Sanding with water sandpaper. After the prepared sample was rinsed, it was placed in an acetone solution and ultrasonically cleaned for 5 minutes before use. The sample after the preliminary treatment is brush-plated according to the following process: the brush-plating voltage is 10V, the brush-plating line speed is 6-12m / min, and the brush-plating time is 10min, (the pH value of the plating solution is 1.5, and the temperature of the plating solution is 30 ℃). In the vacuum furnace, heat up to the set temperature with the furnace, keep it warm for 1 hour, cool down to 150°C with the furnace, and take it out for air cooling. The test temperatures were 450°C...

Embodiment example 2

[0017] On the basis of the Fe-W coating, the Fe-W-Cu coating is formed with Cu as the alloying element. The surface of the coating presents a "micro-cauliflower head" shape. Compared with the Fe-W coating, the aggregates have been significantly refined. The coating is well bonded to the substrate, and there are no structural defects such as pores and microcracks in the coating, and the structure is more Uniform and dense. It shows that when Cu element participates in the co-deposition of the coating, there is an obvious thinning effect on the coating, which reduces the growth stress of the coating. The deposition efficiency of the coating is equivalent to that of the Fe-W coating, which shows that the introduction of Cu element does not affect the deposition efficiency of the coating. In the coating, only the diffraction peaks representing the crystal orientations of α-Fe appear, and the intensity and width of the diffraction peak of the Fe-W coating are similar to those of t...

Embodiment example 3

[0019] The hardness of the three coatings is significantly higher than that of the substrate GCrl5, and the hardness of the alloyed coating is further improved after the addition of W and Cu elements, close to 700HV, which can meet the hardness requirements of most engineering parts. The wear amount of the Fe coating is higher than that of the substrate. The wear mechanism of Fe coating is abrasive wear. The Fe coating has high hardness and high brittleness, and is prone to brittle fracture and shedding in the process of friction and wear. After adding W element, the hardness of the coating is improved due to the dispersion strengthening of W, but due to the existence of the hard phase, it will only increase the possibility of the brittle detachment of the hard phase of the Fe coating, and cannot improve the tribological properties of the Fe coating. , and the Fe-W coating itself is not dense, so it leads to a greater amount of wear during the friction process. When Cu eleme...

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PUM

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Abstract

A green Fe-based alloy coating has enormous advantage and potential in the green remanufacturing engineering on the basis of a Fe-based electro-brush coating, chemical ions capable of realizing co-deposition are added on the basis of a Fe-based electro-brush plating system for preparation of the Fe-based alloy coating. With addition of W element capable of co-depositing with Fe ions, hardness of the Fe coating can be improved, the phenomenon of stress cracking is reduced, but the coating is low in density and poor in wear resistance; with further addition of Cu element with lubricity and excellent plastic flow capability, the coating structure can be refined, and wear resistance is improved. New-phase Fe3C is formed in the heat treatment process of three Fe-based coatings, and coating crystal grains grow with increase of the temperature; Fe and Fe-W coatings are hardened secondarily at the temperature in a range of 450-650 DEG C.

Description

Technical field [0001] The invention relates to a surface coating material, in particular to a green iron-based alloy coating. Background technique [0002] Brush plating is an important part of remanufacturing technology. At present, the brush plating coating widely used in engineering is nickel-based coating, but due to the high cost of the plating solution, the product is easy to cause contact allergy, and the residual nickel-containing plating solution has certain pollution to the environment. Therefore, it has been Restricted for use by EU countries. The development of an environment-friendly brush-plating system is one of the urgent problems to be solved in green remanufacturing technology. Since most remanufacturable equipment is made of iron-based materials, it is of great importance to develop an environment-friendly iron-based coating with a high degree of matching with the substrate structure and performance. Engineering significance one. However, due to the hi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D5/06C25D3/56
CPCC25D5/06C25D3/562
Inventor 刘辉
Owner 刘辉