Pigment composition containing phthalocyanine blue 15:2 and preparation method thereof
A pigment composition, phthalocyanine blue technology, applied in the direction of organic dyes, chemical instruments and methods, azo dyes, etc., can solve the problems of environmental pollution, heat resistance, poor anti-flocculation and anti-crystallization properties, and inability to treat waste acid.
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Embodiment 1
[0087] A pigment composition containing phthalocyanine blue 15:2, which is made up of the following components:
[0088] Phthalocyanine blue 15:0 1000Kg, copper phthalocyanine chlorinated derivatives 85Kg, copper phthalocyanine sulfonated derivatives 60Kg;
[0089] Wherein, the preparation method of described phthalocyanine blue 15:0 is as follows:
[0090] S11 copper phthalocyanine pretreatment
[0091] Under vacuum conditions, mix the crude copper phthalocyanine and sulfuric acid solution with a mass concentration of 5% at a weight ratio of 1:8 for beating for 1 hour, then stir at 95°C for 6 hours, add water to cool down to 70°C, wash with water in a filter press until neutral, and dry Obtain pure copper phthalocyanine;
[0092] copper phthalocyanine activation
[0093] The pure copper phthalocyanine was mixed with anhydrous sodium sulfate at a weight ratio of 5:1 and ground in a ball mill at a grinding temperature of 70°C for 12 hours;
[0094] S12 Add activated copper ...
Embodiment 2
[0109] A kind of pigment composition that contains phthalocyanine blue 15:2, and its difference with embodiment 1 is:
[0110] It is made of the following components: phthalocyanine blue 15:0 1000Kg, copper phthalocyanine chlorinated derivatives 120Kg, copper phthalocyanine sulfonated derivatives 50Kg.
[0111] It has been determined that the content of phthalocyanine blue 15:2 in this embodiment is 70% by weight.
Embodiment 3
[0113] A kind of pigment composition that contains phthalocyanine blue 15:2, and its difference with embodiment 1 is:
[0114] It is made of the following components: phthalocyanine blue 15:0 500Kg, copper phthalocyanine chlorinated derivatives 50Kg, copper phthalocyanine sulfonated derivatives 80Kg.
[0115] It has been determined that the content of phthalocyanine blue 15:2 in this embodiment is 66% by weight.
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