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A method to improve the performance of new organic solar cells generated by interfacial recombination to generate carriers
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A solar cell and interfacial recombination technology, applied in the field of solar cells, can solve the problems of low conversion efficiency and achieve the effect of improving conversion efficiency
Active Publication Date: 2021-07-16
SHENZHEN LOTUT INNOVATION DESIGN CO LTD
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Problems solved by technology
However, the free carriers of this new type of battery are generated through the joint action of excitons and excitons, so that the conversion efficiency of this type of solar cell is relatively low.
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Embodiment 1
[0028] A method for improving the performance of a novel organic solar cell generated by interface recombination comprising the following steps:
[0029] The first step is to clean the substrate; put the patterned ITO glass into acetone, ethanol, isopropanol and deionized water for 20 minutes, and then dry it with nitrogen, and set it aside;
[0030] In the second step, the solution was spin-coated with a layer of 39nm-41nm PEDOT:PSS (purchased from Heraeus) on the treated ITO substrate, and baked at 150 °C for 30 min. Put the dried ITO substrate coated with PEDOT:PSS into the vacuum chamber to grow the active layer, interface modification layer and electrodes in sequence;
[0031] In the third step, a layer of 20 nm F16ZnPc (purchased from Sigma Aldrich) film was grown on PEDOT:PSS at a rate of 0.7 nm / min;
[0032] The fourth step is to grow another n-type material C on the F16ZnPc layer 60 (purchased from Sigma Aldrich), the growth rate is 1.5 nm / min, and the thickness of ...
Embodiment 2
[0037] A method for improving the performance of a novel organic solar cell generated by interface recombination comprising the following steps:
[0038] The first step is to clean the substrate; put the patterned ITO glass into acetone, ethanol, isopropanol and deionized water for 20 minutes, and then dry it with nitrogen, and set it aside;
[0039] In the second step, the solution was spin-coated with a layer of 39nm-41nm PEDOT:PSS (purchased from Heraeus) on the treated ITO substrate, and baked at 150 °C for 30 min. Put the dried ITO substrate coated with PEDOT:PSS into the vacuum chamber to grow the active layer, interface modification layer and electrodes in sequence;
[0040] In the third step, a layer of 20 nm F16ZnPc (purchased from Sigma Aldrich) film was grown on PEDOT:PSS at a rate of 0.7 nm / min;
[0041]In the fourth step, Alq3 with a thickness of 1nm, 5nm, and 10 nm is grown on the F16ZnPc film as a barrier layer. The thickness of Alq3 (Sigma Aldrich) is controll...
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Abstract
A method to improve the performance of new organic solar cells generated by interfacial recombination to generate carriers. The novel organic solar cell comprises a substrate anode, a hole transport layer, an organic light absorbing layer 1, an organic light absorbing layer 2, an electrontransport layer and a cathodeelectrode from bottom to top. It is characterized in that an effective interface layer intervenes between the organic light-absorbing layer 1 and the organic light-absorbing layer 2, which effectively promotes the interaction between the excitons in the organic light-absorbing layer 1 and the organic light-absorbing layer 2 at the interface, and is more conducive to free current carrying The generation of electrons improves the conversion efficiency of the battery. The present invention intervenes into C by using interface layer Alq3 60 In organic solar cells composed of two materials, F16ZnPc and F16ZnPc, the conversion efficiency of the cells is improved. Intervention of Alq3 increases C 60 The interaction between the excitons of F16ZnPc and the excitons of F16ZnPc on the interface can obtain more free carriers, increase the current and voltage of the battery, and finally improve the conversion efficiency of this type of organic solar cell.
Description
technical field [0001] The invention relates to the technical field of solar cells, in particular to a method for improving the conversion efficiency of a new type of organic solar cell in which an interface layer is inserted into an organic light-absorbing layer to obtain free carriers through interfacial recombination. Background technique [0002] Due to the advantages of simple preparation, light weight, low cost and large-area production, organic solar cells are favored by many researchers. Although the efficiency of organic solar cells has exceeded the energy conversion efficiency of 13%, it is still necessary to further improve the efficiency of the cells for industrialization. In order to further improve the efficiency of organic solar cells, it is very important to understand such cell interface processes, which include interfacial free carrier generation, exciton recombination, charge and exciton interaction and other processes. Among these processes, the generati...
Claims
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