Polyphenylene sulfide resin composition with low dielectric constant and preparation method thereof

A polyphenylene sulfide resin, low dielectric constant technology, applied in the field of engineering plastics, can solve the problems of low metal drawing force, low drawing force, low dielectric constant of polyphenylene sulfide resin composition, etc. Excellent flammability

Active Publication Date: 2018-07-27
SHENZHEN HALCYON NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polyphenylene sulfide resin composition solves the problems of high dielectric constant of polyphenylene sulfide resin, low pull-out force with metal, and insufficient flame retardant effect
[0008] Another aspect of the present invention provides a method for preparing a polyphenylene sulfide resin composition with a low dielectric constant. The polyphenylene sulfide resin composition prepared by the

Method used

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  • Polyphenylene sulfide resin composition with low dielectric constant and preparation method thereof
  • Polyphenylene sulfide resin composition with low dielectric constant and preparation method thereof
  • Polyphenylene sulfide resin composition with low dielectric constant and preparation method thereof

Examples

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Effect test

Embodiment 1

[0062] Embodiment 1: The polyphenylene sulfide resin composition of this embodiment includes the following components in parts by mass:

[0063]

[0064]

[0065] The preparation method of the polyphenylene sulfide resin composition in the present embodiment is as follows:

[0066] According to the proportion, the above PPS resin, cage silsesquioxane, toughening agent, antioxidant, heat stabilizer and lubricant are mixed to obtain a mixture;

[0067] Add glass fiber to the mixture, put it into an extruder, carry out melt extrusion and granulation, stir evenly, and obtain a polyphenylene sulfide resin composition.

[0068] The heating temperature of the extruder is set as follows: Zone 1 160~200℃, Zone 2 220~250℃, Zone 3 230~270℃, Zone 4 250~290℃, Zone 5 270~310℃, Zone 6 280~320℃ And machine head 260 ~ 280 ℃.

Embodiment 2

[0069] Embodiment 2: The polyphenylene sulfide resin composition of this embodiment includes the following components in parts by mass:

[0070]

[0071] The preparation method of the polyphenylene sulfide resin composition of this example is the same as that of Example 1.

Embodiment 3

[0072] Embodiment 3: The polyphenylene sulfide resin composition of this embodiment includes the following components in parts by mass:

[0073]

[0074] Among them, the glass fiber is chopped glass fiber with low dielectric constant, the toughening agent is glycidyl methacrylate copolymer and styrene / butadiene / styrene block copolymer, and the heat stabilizer is metal oxide and ultraviolet ray A mixture of light absorbers.

[0075] The preparation method of the nano-injection-molded polyphenylene sulfide resin composition in this example is the same as that in Example 2.

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Abstract

The invention provides a polyphenylene sulfide resin composition with low dielectric constant and a preparation method thereof. The polyphenylene sulfide resin composition is mainly composed of, in parts by mass, 20-80 parts of PPS resin, 15-40 parts of glass fibers, 0.3-5 parts of cage-shaped silsesquioxane, 3-15 parts of a toughening agent, 0.3-3 parts of an antioxidant, 0.5-3 parts of a heat stabilizer, 0.3-3 parts of a lubricant, and 0-3 parts of a nucleating agent. The polyphenylene sulfide resin composition has low dielectric constant, and the dielectric constant is 2.8-3.3 under a 1 GHztest condition; the polyphenylene sulfide resin composition has high drawing force after integral injection molding with metals, the drawing force reaches 220 kgf/cm<2> or more, and the polyphenylenesulfide resin composition is suitable for an NMT technology; the heat resistance is good, and the processing temperature is 280 DEG C or more, and the highest processing temperature can reach 320 DEGC; the polyphenylene sulfide resin composition has good flame retardant effect.

Description

technical field [0001] The invention relates to the technical field of engineering plastics, in particular to a low dielectric constant polyphenylene sulfide resin composition and a preparation method. Background technique [0002] Nano Injection Molding Technology (NMT) is a technology that directly injects plastic onto the metal surface to achieve perfect bonding with the metal. It can be used to replace traditional bonding methods such as gluing, in-mold cladding, and metal riveting to achieve light, thin, For short and small purposes, the products manufactured by nano-molding technology have a very broad potential market and have both low price advantages and processing costs. [0003] The fifth generation of mobile phone mobile communications, abbreviated as 5G. The planned transmission rate of 5G mobile communication will be as high as 10-50Gbps, which is more than 10 times the transmission rate of 4G mobile communication. The arrival of 5G technology has made the sc...

Claims

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Application Information

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IPC IPC(8): C08L81/02C08L83/04C08K13/04C08K7/24C08K7/14
CPCC08K2201/011C08L81/02C08L2201/02C08L2205/03C08L83/04C08K13/04C08K7/24C08K7/14
Inventor 曹艳霞谭光凤陆永健赖华林邓冬颜
Owner SHENZHEN HALCYON NEW MATERIALS
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