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Preparation method and application of a core-shell structure manganese-based spinel catalyst
Pending
CN122399881A
Oxidation-Reduction Activity
Molecular sieve
本发明提供了一种核壳结构锰基尖晶石催化剂的制备方法,该方法包括:溶剂热法制备尖晶石前体,双模板水热原位一步封装法合成以尖晶石为核,分子筛为壳的核壳状Mn2Co1O4@ZSM‑5催化剂,还提供了应用,该核壳结构锰基尖晶石催化剂用于NO与含氯挥发性有机物的协同脱除。本发明通过尖晶石核与分子筛壳的复合,构建氧化还原活性和酸性活性位,实现NO与含氯挥发性有机物的高效协同脱除,同时,该方法工艺简单、重现性好,能够一步实现ZSM‑5分子筛壳层在锰钴尖晶石核上的原位、均匀包裹,显著提升催化剂对NO和含氯挥发性有机物的协同脱除效率。
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Owner:
HEBEI UNIV OF TECH
High-entropy oxide catalysts, methods of making and using the same
Pending
CN122352368A
OXALIC ACID DIHYDRATE
Reduction Activity
The application discloses a high-entropy
oxide
catalyst and a preparation method and application thereof. The high-entropy
oxide
containing Ni, Co and Mn is prepared by an
oxalic acid
coprecipitation
method,
oxalate
and various
transition metal
ions are efficiently coordinated and precipitated, atomic-level uniform dispersion of
metal
elements is realized, a stable single-phase
spinel
structure is formed, and the oxidation-
reduction activity
, the
lattice oxygen
migration rate and the
surface oxygen
vacancy density of the material are greatly improved, and the deep degradation capacity of
chlorobenzene
is significantly enhanced.
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Owner:
JIANGSU UNIV OF TECH
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