Method for preparing carbon nano tube fabric electrode and yarn electrode and application of electrode

A technology of carbon nanotubes and fabric electrodes, which is applied in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrodes, etc., can solve the problems of poor multiplier performance of fabric electrodes and yarn electrodes, decreased electrochemical performance of flexible electrodes, and complex processes. , to achieve the effects of outstanding electrochemical performance and mechanical stability, outstanding cycle stability, and simple preparation process

Inactive Publication Date: 2018-08-03
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention aims to solve the problem that there is currently no method for preparing flexible electrodes based on ordinary textile fabrics and yarns at the same time; it solves the problem that high-conductivity materials and textile fibers cannot form a close contact during the conductive treatment of existing ordinary textile fabric electrodes and yarn electrodes. The problem of bonding; solving the problem that ordinary textile yarns are difficult to prepare into fiber-type flexible electrodes; solving the problems of complex process and high cost in t

Method used

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  • Method for preparing carbon nano tube fabric electrode and yarn electrode and application of electrode
  • Method for preparing carbon nano tube fabric electrode and yarn electrode and application of electrode
  • Method for preparing carbon nano tube fabric electrode and yarn electrode and application of electrode

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specific Embodiment approach 1

[0025] Specific embodiment one: a kind of preparation method of carbon nanotube fabric electrode and yarn electrode, this method is carried out as follows:

[0026] 1. Dip the polyester fiber fabric or yarn in acetone for ultrasonic washing, then immerse in ethanol for ultrasonic washing, and finally immerse in deionized water for ultrasonic washing to obtain a polyester fiber fabric or yarn with impurities removed;

[0027] 2. Add tin protochloride to the mixed solvent, and then add HCl to obtain a sensitization solution; immerse the impurity-removed polyester fabric or yarn in the sensitization solution with stirring to obtain a sensitized polyester fabric or Yarn; wherein, the mixed solvent is mixed by methanol and deionized water by equal volume;

[0028] 3. Ultrasonic dispersion of carbon nanotubes in deionized water after acidification treatment to obtain a carbon nanotube dispersion;

[0029] 4. Immerse the sensitized polyester fiber fabric or yarn in the carbon nanotu...

specific Embodiment approach 2

[0031] Specific embodiment two: this embodiment is the same as specific embodiment one: the concentration of the carbon nanotube dispersion liquid described in step one is 2g L -1 ~20gL -1 . Others are the same as in the first embodiment.

specific Embodiment approach 3

[0032] Specific embodiment three: this embodiment is the same as specific embodiment one: the concentration of stannous chloride in the sensitization process described in step two is 0.005mol L -1 ~0.2mol L -1 , the concentration of HCl is 0.02mol L -1 ~0.5molL -1 . Others are the same as in the first embodiment.

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Abstract

The invention relates to a method for preparing a carbon nano tube fabric electrode and a yarn electrode and application of the electrode, and relates to an electrode preparation method and application of the electrode, and solves the problem that no conventional method can simultaneously prepare a flexible electrode based on an ordinary textile fabric and yarns. The method comprises sensitizing apolyester fiber fabric and a yarn for an ordinary textile with stannous chloride, preparing a fabric/carbon nano tube fabric electrode and a yarn/carbon nano tube yarn electrode, preparing a conductive polymer/fabric/carbon nano tube fabric electrode and a conductive polymer/yarn/carbon nano tube yarn electrode and applying the same to a flexible super capacitor. The method of the invention has the advantages of simple process, low cost and universal applicability. The planar and fiber-type symmetric super capacitors in which the fabric electrode and the yarn electrode are assembled also achieve excellent electrochemical performance.

Description

technical field [0001] The invention relates to a preparation method of a carbon nanotube fabric electrode and a yarn electrode and an application of the electrode. Background technique [0002] At present, with the development of portable and wearable electronic products, high-performance flexible electrodes have become an important research direction in the field of energy storage. Ordinary textile fabrics have mature preparation technology, can be produced on a large scale, and have abundant sources of raw materials; textile fabrics have a three-dimensional porous network structure, making them extremely flexible; textile fabrics have good air permeability. However, fabrics for textiles are not conductive and cannot be directly used as electrodes, so conductive treatment is required. Carbon nanotubes have high conductivity and large specific surface area, and the flexible electrode formed by compounding them on the surface of the fabric has both the advantages of fabric ...

Claims

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Application Information

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IPC IPC(8): H01G11/26H01G11/30H01G11/36H01G11/48H01G11/86
CPCH01G11/26H01G11/30H01G11/36H01G11/48H01G11/86Y02E60/13
Inventor 袁国辉李小龙刘荣许春阳白洋刘杨周晓明王永吉
Owner HARBIN INST OF TECH
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