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Ethylene gas embedding material with slow release performance and embedding method

A slow-release performance, ethylene technology, applied in the fields of botanical equipment and methods, pest control, animal repellants, etc., can solve the problems of weak binding of ethylene and starch, poor storage stability, unstable complexes, etc. Achieve the effects of easy storage and transportation, improved stability, and controllable release

Inactive Publication Date: 2018-08-07
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the combination of ethylene and starch is too weak to cause the complex to be unstable, even if the decomposition rate is fast at dry room temperature, resulting in poor storage stability (Shi L.F., Fu X., Tan C.P., Huang Q.*, Zhang B. *Encapsulation of Ethylene Gas into Granular Cold-Water Soluble Starch: Structure and Release Kinetics. Journal of Agricultural and Food Chemistry, 2017, 65: 2189-2197)

Method used

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  • Ethylene gas embedding material with slow release performance and embedding method
  • Ethylene gas embedding material with slow release performance and embedding method

Examples

Experimental program
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Effect test

Embodiment 1

[0044] Cucurbit [5] urea (CB [5]) was placed in a miniature autoclave, the sample volume was 30% of the volume of the autoclave, and the autoclave was evacuated to -0.10Mpa. Introduce ethylene gas, react at 1.5Mpa, 25°C for 20 hours, open the outlet valve after the reaction, absorb unadsorbed ethylene with bromine water, and obtain cucurbituril powder product with ethylene adsorbed. The product is packed in a sealed bag and stored Store in dry, low temperature and dark conditions. The compound of 1.0g was weighed into a sealed bag and stored at 25°C for a period of time, and gas chromatography was used to detect the change of ethylene content in the compound during storage.

[0045] After testing, the recovery rate of the sample was 100%, and the adsorption rate of ethylene was 9.3% (w / w). The ethylene content in the composite is about 1% (w / w) after being placed at 25°C for 720 hours.

Embodiment 2

[0047] The experimental material used is cucurbit [6] urea (CB [6]), and other conditions are the same as in Example 1.

[0048] After testing, the recovery rate of the sample was 100%, and the adsorption rate of ethylene was 8.4% (w / w). The content of ethylene in the composite is about 0 after being placed at 25°C for 720h.

Embodiment 3

[0050] The experimental material used is cucurbit [7] urea (CB [7]), and other conditions are the same as in Example 1.

[0051] After testing, the recovery rate of the sample was 100%, and the adsorption rate of ethylene was 7.7% (w / w). The content of ethylene in the composite was zero after being placed at 25°C for 120 hours.

[0052] Due to space limitations, the parameters of the embedding method of this patent can be properly floated, and the floating range is as follows. The embedding method is to place cucurbitacin in a high-pressure reactor, and the amount added is 0% to 40% of the volume of the reactor. , evacuate the reactor, feed ethylene gas, control the pressure at 0.1-2.0Mpa, react at 15-35°C for 8-48 hours, open the outlet valve of the reactor after the reaction, absorb unadsorbed ethylene, and obtain release properties of vinyl-embedded products. After testing, the ethylene content in the obtained product can reach more than 9.3% (w / w), and it can release con...

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Abstract

The invention discloses an ethylene gas embedding material with slow release performance and an embedding method. The embedding method comprises the steps: putting cucurbituril into a high-pressure reaction kettle, wherein the adding amount of the cucurbituril is 10% to 40% of the volume of the reaction kettle; vacuumizing the reaction kettle; introducing ethylene gas, wherein pressure intensity is controlled as 0.1 to 2.0Mpa; reacting for 8 to 48h under 15 to 35 DEG C; opening an air outlet valve of the reaction kettle after reaction finishes and absorbing unabsorbed ethylene to obtain an ethylene embedding product with the slow release performance. Tests show that the content of ethylene in the obtained product can reach 9.3% (w / w) or more, and the ethylene can be continuously released for 720h under 25 DEG C. To an ethylene adsorption technology, the method has the advantages of simpleness, high efficiency and low cost; composite can exist stably; the product has a wide applicationprospect in the field of controlled-atmosphere refreshment of fruits and vegetables.

Description

technical field [0001] The invention relates to an embedding method of ethylene gas with slow-release performance, in particular to an embedding object and embedding method of ethylene gas with slow-release performance. Background technique [0002] Ethylene is an important non-polar gas that regulates plant ripening. It is known as "phytohormone" and can accelerate the ripening process of fruits or promote the germination of seeds. In the field of fruit and vegetable preservation, ethylene glycol is widely used to induce plants or fruits to release ethylene, but it has certain toxicity, and its safety has attracted much attention. [0003] Gases are usually stored and transported in high-pressure steel cylinders, but there are risks of leakage and explosion during use. Adsorbing the gas in a solid carrier can effectively avoid this defect. Gases physically trapped in a solid carrier have characteristics such as slow release, and have important applications when the demand...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/08A01N27/00A01P21/00
CPCA01N25/08A01N27/00
Inventor 张斌石林凡黄强扶雄
Owner SOUTH CHINA UNIV OF TECH
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