High-glossiness automobile black film and preparation method therefor
A black film, automotive technology, applied in the direction of pressure-sensitive film/sheet, film/sheet adhesive, non-polymer organic compound adhesive, etc., can solve the problem of poor stone impact resistance and scratch resistance, Problems such as poor shrinkage effect of the aluminum plate and low gloss of the black film can achieve the effect of prolonging the service life, improving the competitiveness of the vehicle, and having a good ventilation function
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Example Embodiment
[0038] Example 1
[0039] A high-gloss automotive black film, see figure 1 , From top to bottom, it is composed of positioning paper 1, bright coating 2, PVC black film 3, acrylic pressure sensitive adhesive 4 and release paper 5.
[0040] The positioning paper 1 is used for temporary protection of the PVC black film 3.
[0041] The formulation of the bright coating 2 consists of the following parts by weight: 43 parts of diethyl p-toluenesulfonyloxymethylphosphonate, 2.7 parts of tin light stabilizer, 0.25 parts of 8% zinc octoate, and propylene glycol methyl ether acetate 5.3 parts, 29.5 parts of polyisocyanate, 8 parts of cellulose acetate and 14 parts of methyl ethyl ketone.
[0042] The formula of the acrylic pressure-sensitive adhesive 4 consists of the following parts by weight: 6 parts of acrylic acid, 26 parts of ethyl acetate, 0.9 parts of dibenzoyl peroxide, 41 parts of toluene, 27.5 parts of isooctyl acrylate and crosslinking agent 1.6 copies.
[0043] Wherein, the crossl...
Example Embodiment
[0055] Example 2
[0056] The high-gloss automotive black film of this embodiment and its preparation method are similar to those of Embodiment 1, with the only difference being:
[0057] The formulation of the bright coating 2 consists of the following parts by weight: 41 parts of diethyl p-toluenesulfonyloxymethylphosphonate, 3 parts of tin light stabilizer, 0.2 parts of 8% zinc octoate, and propylene glycol methyl ether acetate 5.5 parts, 28 parts of polyisocyanate, 6 parts of butyl cellulose acetate and 15 parts of methyl ethyl ketone.
[0058] The formula of the acrylic pressure-sensitive adhesive 4 consists of the following parts by weight: 5 parts of acrylic acid, 27 parts of ethyl acetate, 0.8 parts of dibenzoyl peroxide, 42 parts of toluene, 25 parts of isooctyl acrylate and crosslinking agent 1.8 copies.
[0059] Wherein, the crosslinking agent is 3-methyltetrahydrothiazole-2-thione.
[0060] The difference between the preparation method of the high-gloss automobile black fi...
Example Embodiment
[0062] Example 3
[0063] The high-gloss automotive black film of this embodiment and its preparation method are similar to those of Embodiment 1, with the only difference being:
[0064] The formulation of the bright coating 2 consists of the following parts by weight: 45 parts of diethyl p-toluenesulfonyloxymethylphosphonate, 2.5 parts of tin light stabilizer, 0.3 parts of 8% zinc octoate, and propylene glycol methyl ether acetate 5 parts, 31 parts of polyisocyanate, 9 parts of butyl cellulose acetate and 13 parts of methyl ethyl ketone.
[0065] The formula of the acrylic pressure-sensitive adhesive 4 consists of the following parts by weight: 7 parts of acrylic acid, 25 parts of ethyl acetate, 1 part of dibenzoyl peroxide, 40 parts of toluene, 30 parts of isooctyl acrylate and crosslinking agent 1.4 copies.
[0066] The difference between the preparation method of the high-gloss automobile black film provided in this embodiment and the embodiment 1 is:
[0067] The heat preservati...
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