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Three grade cyclic absorption treatment method and equipment in acid etching production lines

A technology of acid etching and treatment method, which is applied in the field of three-stage cyclic absorption treatment method and equipment, which can solve the problems of adjusting absorption efficiency and increasing construction costs, and achieve the effects of reducing etching costs, avoiding heat supplementation, and easy operation

Active Publication Date: 2018-08-21
SHENZHEN ZHONGKE OUTAIHUA ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, some manufacturers have adopted the method of chlorine gas treatment and reuse outside the acid etching production line. However, their method not only needs to add some special processing equipment, which increases the construction cost, but also needs to take certain measures to maintain the temperature of the etching solution. , and the actual absorption efficiency cannot be adjusted according to the ORP value, and the best treatment effect and cost have not yet been achieved. It is still necessary to develop an efficient, suitable and controllable treatment method and technology to make it better to recycle chlorine and reduce costs

Method used

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  • Three grade cyclic absorption treatment method and equipment in acid etching production lines

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Effect test

Embodiment 1

[0035] A treatment method using three-stage cyclic absorption in an acid etching production line, comprising the steps of:

[0036] (1) Electrolysis and regeneration solution circulation: The waste etching solution produced in the acid etching production line is sent to the electrolytic tank for electrolysis, metal copper is recovered, and the regeneration etching solution after removing copper ions is sent back to the acid etching production line for use; The waste etching solution mainly contains HCl, NaCl and Cu + 、Cu 2+ and other components; preferably, the regenerated etching solution after removing copper ions is transported to the liquid storage tank through the regenerated liquid delivery pump, and then lifted and pumped to the regenerated liquid supply tank through the regenerated liquid, according to the control index of the acid etching production line, through The regeneration liquid supply pump is automatically sent back to the acid etching production line for us...

Embodiment 2

[0042] On the basis of embodiment 1, the following preferred technical features are added:

[0043] In the step (2), the chlorine gas absorption cycle is a two-stage cycle, and two sets of independent systems work at the same time, and each stage includes an absorption cycle pump, a chlorine gas absorber and an absorption cycle tank; The inlet of the circulating pump is more than 2m apart and continuously flows into the acid etching production line.

[0044] While recirculating in the step (3), according to the ORP value of etching solution, determine the frequency conversion operation status of the absorption circulation pump corresponding to the chlorine absorber, to ensure the efficient and stable progress of the acid etching production line;

[0045] The negative pressure value of the electrolytic cell is controlled between 2-6Kpa, and the ORP value of the etching solution is controlled to be 480-600mV through chlorine gas absorption. The number of cycles of etching solut...

Embodiment 3

[0047] Send the etching solution of the acid etching production line to the electrolytic tank for electrolysis, and the negative pressure value of the electrolytic tank is controlled at 2KPa; the etching solution absorbs the chlorine gas from the electrolytic tank through the absorption circulation pump and the chlorine gas absorber, and controls the etching of each absorption circulation tank The number of liquid circulation is 1 time / h. Absorb Cl in the chlorine absorber 2 The gas-liquid ratio is controlled at 1:1, and the ORP value of the etching solution is controlled at 500mV; the absorbed waste gas is sent to the tail gas treatment tank; the absorbed etching solution is returned to the acid etching production line for use.

[0048] The result of the chlorine gas absorbed by the etching solution was: the absorption rate was 86.1%.

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Abstract

The invention discloses a three grade cyclic absorption treatment method and equipment in acid etching production lines. The three grade cyclic absorption treatment method comprises following steps: 1, electrolysis and regenerated liquid circulation; 2, chlorine gas absorption circulation; 3, etching solution circulation; 4, tail gas absorption circulation; and 5, tail gas treatment. According tothe three grade cyclic absorption treatment method, three grade cyclic absorption is adopted in acid etching production lines, so that absorption validity, rationality, and controllability are ensured, processing and recycling effect of Cl2 is ideal, absorption operation can be controlled based on ORP value, operation is convenient and stable, etching temperature is ensured to be stable, energy consumption is reduced, etching effect is improved, tail gas treatment load of the whole system is reduced, and secondary pollution is avoided.

Description

technical field [0001] The invention relates to the field of PCBs, in particular to a treatment method and equipment using three-stage cyclic absorption in an acid etching production line. Background technique [0002] In the construction of the national economy, PCB is the basic industry for the development of industrialization and informationization. With the continuous development of economic construction, the PCB industry has developed rapidly. Due to the by-products of various wastes in the PCB production process, they need to be treated, and the most difficult to handle and dispose of is the copper etching waste solution. [0003] At present, in technical research, the traditional electrolysis method is mostly used. Because this method has high copper recovery rate and high copper purity, but chlorine gas will be generated in the electrolysis, which needs to be treated before discharge to avoid environmental pollution. Additional oxidant is added to maintain the etch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/46C25C1/12C25C7/00
CPCC23F1/46C25C1/12C25C7/00Y02P10/20
Inventor 吴渤陈祥衡李明军石杨王青龙罗锌钰
Owner SHENZHEN ZHONGKE OUTAIHUA ENVIRONMENTAL PROTECTION TECH
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