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Organic conductive polymer modified proton membrane and preparation method thereof

A conductive polymer and proton membrane technology, applied in the field of thin films, can solve the problems of poor dispersion of inorganic materials, affecting the service life of batteries, and low quality of finished membranes, and achieve the effects of high uniformity and stability, good conductivity and strong mechanical properties.

Inactive Publication Date: 2018-09-04
温州市赢创新材料技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Inside the fuel cell, the proton exchange membrane provides a channel for the migration and transport of protons, so that the protons pass through the membrane from the anode to the cathode, and form a circuit with the electron transfer of the external circuit to provide current to the outside world. Therefore, the performance of the proton exchange membrane has a great influence on the performance of the fuel cell Performance plays a very important role, and its quality directly affects the service life of the battery; at present, there are a large number of products that reinforce the proton membrane with inorganic materials, but due to the poor dispersion of inorganic materials, the quality of the finished membrane is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A kind of organic conductive polymer modified proton membrane, it is made up of the raw material of following weight part:

[0024] Organic polymer solution 20, diisocyanate 1, trichloroisocyanuric acid 2, benzotriazole 0.7, polyphenylene ether 60, β-hydroxyalkylamide 1, silicon micropowder 10.

[0025] Described organic polymer solution is made up of the raw material of following parts by weight:

[0026] Aniline 40, Dicumyl Peroxide 1, Palm Wax 3, Dimethylaminopropylamine 1, Magnesium Stearate 0.8.

[0027] Described a kind of organic conductive polymer modified proton membrane, the preparation method of described organic polymer solution, comprises the following steps:

[0028] (1) Take dicumyl peroxide, add it to 10 times its weight in isopropanol, and stir evenly;

[0029] (2) Take palm wax, add it to 4 times its weight in absolute ethanol, put it in a constant temperature water bath at 90°C, keep it warm and stir for 10 minutes to obtain an alcoholic solution; ...

Embodiment 2

[0039] A kind of organic conductive polymer modified proton membrane, it is made up of the raw material of following weight part:

[0040] Organic polymer solution 30, diisocyanate 2, trichloroisocyanuric acid 3, benzotriazole 1, polyphenylene ether 70, β-hydroxyalkylamide 2, silicon micropowder 14.

[0041] Described organic polymer solution is made up of the raw material of following parts by weight:

[0042] Aniline 50, Dicumyl Peroxide 1.3, Palm Wax 4, Dimethylaminopropylamine 2, Magnesium Stearate 1.

[0043] Described a kind of organic conductive polymer modified proton membrane, the preparation method of described organic polymer solution, comprises the following steps:

[0044] (1) Take dicumyl peroxide, add it to 13 times its weight in isopropanol, and stir evenly;

[0045] (2) Take palm wax, add it to 7 times its weight in absolute ethanol, put it into a constant temperature water bath at 95°C, keep it warm and stir for 20 minutes to obtain an alcoholic solution; ...

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PUM

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Abstract

The invention discloses an organic conductive polymer modified proton membrane and a production method thereof. The organic conductive polymer modified proton membrane comprises, by weight, 20-30 parts of an organic polymer solution, 1-2 parts of diisocyanate, 2-3 parts of trichloroisocyanuric acid, 0.7-1 part of benzotriazole, 60-70 parts of polyphenylene ether, 1-2 parts of beta-hydroxyalkylamide and 10-14 parts of silicon micro-powder. The composite proton membrane has the advantages of high uniform stability, good electrical conduction stability, strong mechanical property and high quality.

Description

technical field [0001] The invention belongs to the field of thin films, and in particular relates to an organic conductive polymer modified proton membrane and a preparation method thereof. Background technique [0002] Proton exchange membrane fuel cells have become the most competitive clean alternative power source for gasoline internal combustion engines. The materials used as PEM should meet the following conditions: good proton conductivity, small electroosmosis of water molecules in the membrane, and gas in the membrane. The permeability in the medium is as small as possible, the electrochemical stability is good, the dry-wet conversion performance is good, it has certain mechanical strength, good processability, and the price is reasonable; the proton exchange membrane fuel cell has low operating temperature, fast start-up, and high specific power. , simple structure, convenient operation and other advantages, it is recognized as the preferred energy source for elec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L79/02C08K13/06C08K9/04C08K3/36C08K5/29C08K5/00C08J5/22
CPCC08J5/2256C08J2371/12C08J2479/02C08K3/36C08K5/0091C08K5/29C08K9/04C08K9/08C08K13/06
Inventor 方万漂
Owner 温州市赢创新材料技术有限公司
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