Oilfield profile control agent and preparation method thereof
A profile control agent, oil field technology, applied in chemical instruments and methods, drilling composition and other directions, can solve the problems of fast water absorption and expansion of particles, loss of water plugging and profile control effect, and volume reduction of water injection wave, so as to improve oil recovery. Time, reduce oil production costs, and avoid construction waste.
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[0029] The present invention also provides the preparation method of above-mentioned oil field profile control agent, comprises the following steps:
[0030] (1) dehydrating the polyester polyol to obtain dehydrated polyester polyol;
[0031] (2) keeping the dehydrated polyester polyol and the hexamethylene diisocyanate at 79-96° C. for 1-5 hours to obtain a polyurethane prepolymer;
[0032] (3) Cool down the polyurethane prepolymer to below 35°C, mix it with the solvent and the chloroprene rubber, raise the temperature of the obtained mixture to 40-45°C within 5-20 minutes, and pour it into the mixture Add the sealing agent dropwise, control the dropping time to 0.5-20 hours, keep warm for 3-9 hours, then add the plasticizer, the catalyst and the solvent, and stir for 0.5-1 hour to obtain oil field profile control agent.
[0033] In the present invention, there is no special limitation on the dehydration method of polyester polyol, and the dehydration can be carried out by ...
Embodiment 1
[0039] Add 48wt% polyester polyol (PE) into the reaction kettle, raise the temperature to 120 degrees Celsius, and dehydrate under vacuum for 30 minutes. After cooling down to 40 degrees Celsius, 8 wt% hexamethylene diisocyanate (HDI) was added, the temperature was controlled at 85 degrees Celsius, and the temperature was kept for 2.5 hours. Cool down to 25 degrees Celsius, add 15wt% xylene and 10wt% chloroprene rubber in turn, heat up to 40 degrees Celsius in 5 minutes, add 8wt% ethyl lactate dropwise, control the dropping time for 0.5 hours, keep warm for 3 hours, then add 2wt% Acetone, 7wt% dibutyl phthalate and 2wt% triethylenediamine are stirred for 0.5 hours, cooled to below 40 degrees Celsius, released from the reaction kettle, filled into iron packaging drums, and become the oilfield profile control agent. The physical and chemical indicators of the product are shown in Table 1:
[0040] Table 1 Example 1 Oilfield profile control agent physical and chemical indicators...
Embodiment 2
[0046] Add 50wt% polyester polyol (PE) into the reaction kettle, raise the temperature to 120 degrees Celsius, and dehydrate under vacuum for 30 minutes. After cooling down to 40 degrees Celsius, 10 wt% hexamethylene diisocyanate (HDI) was added, the temperature was controlled at 85 degrees Celsius, and the temperature was kept for 2.5 hours. Cool down to 35 degrees Celsius, add 12wt% xylene and 8wt% neoprene in sequence, heat up to 40 degrees Celsius in 5-20 minutes, add 8wt% caprolactam dropwise, control the dropping time for 12 hours, and keep warm for 7 hours, then add 3wt% % acetone, 7wt% dibutyl phthalate, 2wt% dibutyltin diethylhexanoate, stir for 1 hour, cool down to below 40 degrees Celsius, release from the reaction kettle, and fill it into an iron packaging barrel, which is the oil field Profile control agent. The physical and chemical indicators of the product are shown in Table 2:
[0047] Table 2 Example 2 Oilfield profile control agent physical and chemical in...
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