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Equipment and method for directly using coal gasification hot gas to produce direct reduced iron in a gas-based shaft furnace

A gas-based shaft furnace and hot gas technology, applied to shaft furnaces, furnaces, furnace types, etc., can solve the problems of low efficiency and high investment in the rotary kiln process, and achieve the effects of high efficiency, good economy, and small investment

Active Publication Date: 2019-10-11
NORTHEASTERN UNIV LIAONING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the mature coal-based direct reduction process in my country is only the rotary kiln process, but the high investment and low efficiency of the rotary kiln process discourage most manufacturers

Method used

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  • Equipment and method for directly using coal gasification hot gas to produce direct reduced iron in a gas-based shaft furnace

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Such as figure 1 As shown, it includes a fluidized bed coal gasifier 1, in which pulverized coal is placed, and oxygen and water vapor are introduced into it. By adjusting the ratio of oxygen and water vapor, the H of the synthesized gas produced is 2 and CO molar ratio is 1.2-1.7. 8-12%wt, preferably 10%wt, of dolomite powder can be mixed into the coal powder to reduce the sulfur content in the synthesis gas. The operating pressure in the fluidized bed coal gasifier 1 is 0.3 MPa-0.6 MPa, the temperature of the generated syngas can reach as high as 980°C, and the generated slag can be used as raw material for cement plants.

[0036] The syngas is mixed with the shaft furnace top gas that has been heat-exchanged and dedusted, and the lower-temperature heat-exchanged and dedusted shaft furnace top gas quenches the syngas to 800°C-850°C, in fact, it can be no higher than 850°C. The mixed gas is called hot raw gas.

[0037] The hot crude gas is passed into the gravity du...

Embodiment 2

[0049] A kind of iron making method, uses pulverized coal, steam and oxygen to prepare syngas under 0.3MPa operation pressure, the H of syngas 2 / CO is 1.2. The shaft furnace top gas with heat exchange and dedusting at 50°C is fed into the synthesis gas, and the two are mixed to obtain hot crude gas at 850°C. Dedust the hot crude gas to obtain a dust content of 9g / m 3 Purified crude gas.

[0050] Pass the purified crude gas into the reforming workspace, the temperature of the workspace is 1200°C, and the workspace is provided with a reforming furnace charge with a particle size of 50mm, including 65%wt coke, 25%wt dolomite and 10%wt converter Steel slag. CO removal in reforming space 2 and H 2 After S, reformed gas is obtained, its temperature is 1100°C, H 2 / CO is 1.2.

[0051] Pass the heat-exchanged and dedusted shaft furnace top gas at 50°C into the reformed gas to obtain synthetic reformed gas. Centrifugal dedusting of synthetically upgraded coal gas. Purified sy...

Embodiment 3

[0053] A kind of ironmaking method, use steam, oxygen and pulverized coal containing 12%wt dolomite powder to prepare synthesis gas under 0.5MPa operating pressure, by adjusting the ratio of water vapor and oxygen, the H of synthesis gas 2 / CO is 1.7. The shaft furnace top gas with heat exchange and dedusting at 30°C is fed into the synthesis gas, and the two are mixed to obtain hot crude gas at 800°C. Gravity dedusting is carried out on the hot crude gas first, and the carryover obtained by gravity dedusting is added back to the pulverized coal; then cyclone dedusting is carried out, and the dust obtained by cyclone dedusting is used to recover waste heat. Get dust content 3g / m 3 Purified crude gas.

[0054] Pass the purified crude gas into the reforming workspace, the temperature of the workspace is 1100°C, and the workspace is provided with reforming furnace charge with a particle size of 100mm, including 85%wt coke, 10%wt dolomite and 5%wt converter Steel slag. CO remo...

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Abstract

The invention relates to an equipment and method for directly using coal gasification hot gas to produce direct reduced iron in a gas-based shaft furnace, which includes: using pulverized coal, water vapor and oxygen to prepare synthesis gas, wherein H 2 / CO is 1.2-1.7, the temperature after adding the shaft furnace top gas for heat exchange and dust removal is not greater than 850℃; dust removal; use the reforming furnace charge to modify and remove CO at a temperature of 1100℃-1250℃ 2 and H 2 S, the temperature of modified gas is 900℃-1100℃, H 2 / CO is 1.2-1.7; mixed with the heat-exchanged and dust-removed shaft furnace top gas to obtain 850℃-900℃ synthetic modified gas; after dust removal, the synthetic modified gas is passed into the shaft furnace equipped with iron ore to obtain DRI. This invention combines China's energy characteristics and combines coal gasification with a gas-based shaft furnace direct reduction process, which overcomes the dependence of the gas-based direct reduction method on natural gas and avoids the need for coal gasification heat to be cooled, transformed, purified, and reheated. It is used in the long and complex process of direct reduction ironmaking in shaft furnace production; it has the advantages of short process, low energy consumption, excellent reducing gas composition, and low pollution.

Description

technical field [0001] The invention relates to the metallurgical field of direct reduction in shaft furnaces, in particular to a method in which coal gasification heat gas is directly used in a gas-based shaft furnace to produce direct reduced iron. [0002] The invention also relates to a device for directly using coal gasification hot coal gas to produce direct reduced iron in a gas-based shaft furnace. Background technique [0003] Direct reduction of iron is a method of obtaining metallic iron by reducing it below the softening temperature of iron ore (or iron-containing agglomerates) using gas, liquid fuel or non-coking coal as energy sources. Its products are porous and low-density sponge-like structure, known as DRI (DirectReduced Iron-direct reduced iron) or sponge iron. Direct reduced iron has excellent properties in terms of energy saving and environmental protection. With the rapid development of the world's iron and steel industry and the increasing attention ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B13/02
CPCC21B13/0073C21B13/02Y02P10/122Y02P10/143
Inventor 储满生李胜康李峰周渝生王国栋唐珏柳政根王佳鑫王正平刘云太
Owner NORTHEASTERN UNIV LIAONING