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Concrete thixotropic agent and preparation method thereof

A thixotropic agent and concrete technology, used in the preparation of thixotropic agents and concrete thixotropic agents, can solve the problems that ordinary concrete cannot effectively maintain the shape, the design of the base plate does not meet the requirements, and the drainage slope cannot be smoothly realized. Ensure construction quality and service performance, significant technical economy, and the effect of improving construction quality

Inactive Publication Date: 2018-09-11
安徽瑞和新材料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] Aiming at the problems existing in the prior art, the present invention discloses a concrete thixotropic agent to prepare high thixotropic concrete, which solves the problem that ordinary concrete cannot be effectively maintained and shaped before hardening, resulting in the design of the superhigh base plate not meeting the requirements and drainage slope It cannot be realized smoothly and it is labor-intensive, time-consuming, labor-intensive and other problems to deal with

Method used

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  • Concrete thixotropic agent and preparation method thereof
  • Concrete thixotropic agent and preparation method thereof
  • Concrete thixotropic agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) Esterification: Add 226.0 parts of stearic acid and 183.8 parts of diethanolamine to a four-necked flask equipped with a thermometer, a stirrer, a constant pressure funnel, a nitrogen inlet tube, and a reflux condenser, and heat to 75°C to 80°C and stir Dissolve, add 0.62 parts of p-toluenesulfonic acid and 0.58 parts of phosphorous acid and continue to stir for 15 minutes; blow nitrogen to remove oxygen in the system; stir to reflux at 90°C to 100°C, react for 3 hours to 4 hours until no moisture is produced, stop The reaction results in an esterified intermediate.

[0034] (2) Quaternization: The temperature of the esterification intermediate is lowered to 65°C-70°C while stirring, and 85.8 parts of diethyl sulfate are added dropwise, and the dripping is completed at a constant speed within 25 minutes to 30 minutes; Heat at ~70°C for 3 hours to 3.5 hours; add 500 parts of water, stir and cool to 30°C.

[0035] (3) Preparation: Add 0.8 parts of fumed silica with a...

Embodiment 2

[0037] (1) Esterification: Add 148.4 parts of palmitic acid and 276.4 parts of triethanolamine into a four-neck flask equipped with a thermometer, a stirrer, a constant pressure funnel, a nitrogen inlet tube, and a reflux condenser, and heat to 70°C to 75°C and stir to dissolve , add 0.43 parts of p-toluenesulfonic acid and 0.47 parts of p-aminobenzenesulfonic acid and continue to stir for 15 minutes; blow nitrogen to remove the oxygen in the system; stir and heat up to 90°C to 95°C to reflux, and react for 3.5 hours to 4 hours until no moisture is produced , Stop the reaction to obtain the esterification intermediate.

[0038] (2) Quaternization: The temperature of the esterification intermediate is lowered to 60°C to 65°C while stirring, and 71.4 parts of diethyl sulfate is added dropwise, and the drop is completed at a constant speed within 20 minutes to 25 minutes; Heat at ~65°C for 3 hours to 3.5 hours; add 500 parts of water, stir and cool to 30°C.

[0039](3) Preparati...

Embodiment 3

[0041] (1) Esterification: Add 182.5 parts of myristic acid and 201.7 parts of diethanolamine into a four-neck flask equipped with a thermometer, a stirrer, a constant pressure funnel, a nitrogen inlet tube, and a reflux condenser, and heat to 60°C to 65°C and stir to dissolve , add 0.52 parts of p-aminobenzenesulfonic acid and 0.48 parts of phosphorous acid and continue to stir for 15 minutes; blow nitrogen to remove oxygen in the system; stir and heat up to 90°C to 95°C to reflux, react for 3 hours to 4 hours until no moisture is produced, stop The reaction results in an esterified intermediate.

[0042] (2) Quaternization: The temperature of the esterification intermediate is lowered to 50°C-60°C while stirring, and 110.0 parts of diethyl sulfate is added dropwise, and the drop is completed at a constant speed within 40 minutes to 50 minutes; Heat at ~60°C for 3.5 hours to 4 hours; add 500 parts of water, stir and cool to 30°C.

[0043] (3) Preparation: Add 2.2 parts of fu...

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Abstract

The invention discloses a concrete thixotropic agent and a preparation method thereof, which includes three steps: 1) esterification: under effect of an acidic compound catalyst, preparing an esterification intermediate from a long-chain fatty acid and an alcohol amine compound; 2) quaternization: preparing a quaternary ammonium salt polymer from the esterification intermediate under effect of anethylation agent; 3) blending: adding ultrafine powder and fibers to the quaternary ammonium salt polymer and performing high-speed dispersion to obtain a stable and uniform concrete thixotropic agentsolution. The concrete thixotropic agent has good thixotropic effect, and can improve constructability and usability of concrete when being applied to a bottom plate of ballastless tracks, furthermore achieving excellent rheological property and convenience in construction when the concrete is subjected to dynamic treatments such as pumping, pouring and vibration. During static standing after slope wiping and finishing treatments are completed, the concrete has excellent shape maintaining capability and has convenience in slope shaping; namely, after the slope wiping and finishing treatmentsof the concrete, water discharge performance and ultra-high slope can be effectively maintained.

Description

technical field [0001] The invention belongs to the technical field of concrete admixtures in building materials, in particular to a concrete thixotropic agent, and in particular to a preparation method of the thixotropic agent. Background technique [0002] Self-compacting concrete is referred to as SCC, which means that the mixture has high fluidity, gap permeability and segregation resistance. When pouring, it can be uniformly compacted only by its own weight without vibration, and it has the same characteristics as traditional vibration after hardening. Concrete is concrete with comparable mechanical properties, durability and volume stability. Self-compacting concrete is a kind of concrete with high workability, and the slump expansion of concrete is usually >550mm. Due to the outstanding self-filling performance of self-compacting concrete, it is suitable for structures such as densely reinforced, unable to vibrate, thin-walled and complex, and requiring noiseless ...

Claims

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Application Information

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IPC IPC(8): C04B24/28
CPCC04B24/28C04B40/0046C04B2103/0085C04B14/062C04B22/002C04B16/06
Inventor 陈国新祝烨然徐志峰杜志芹崔征付丹华
Owner 安徽瑞和新材料有限公司
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