A kind of metal rust inhibitor satisfying spray adhesion and preparation method thereof
A technology of metal anti-rust agent and adhesion, applied in the direction of metal material coating process, coating, anti-corrosion coating, etc., can solve the problems of health hazards for operators, affecting the performance and quality of workpieces, and large environmental hazards, etc., to increase Anti-rust performance, good resistance to corrosive media, and the effect of safety guarantee
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Embodiment 1
[0033]In this embodiment, the metal antirust agent that meets the spraying adhesion is prepared from raw materials including the following components and parts by weight: 24 parts of polyquaternium-hyperbranched benzimidazole block polymer, 15 parts of polyacrylate , 6 parts of surfactant, 1 part of organic phosphonic acid compound, 6 parts of ferrocene, 6 parts of defoamer, 4 parts of hydroxypropyl methylcellulose, 1 part of pH regulator and 82 parts of deionized water.
[0034] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0035] Step (A): Add 0.06 mol of 1,12-dibromododecane, 0.084 mol of 1,4-dimethylpiperazine and 75 ml of dimethyl sulfoxide into a 1000 ml dry three-necked flask. After reacting for 3 hours, add 0.002mol of N-methylimidazole and 0.002mol of N-methylmorpholine, react at 55°C for 3 hours, and distill off the solvent under reduced pressure to obtain polyquaternium salt;
[0036] St...
Embodiment 2
[0045] This embodiment satisfies the metal antirust agent of spraying adhesion, prepared from the raw materials comprising the following components and parts by weight: polyquaternium salt-hyperbranched benzimidazole block polymer 26 parts, polyacrylate 12 parts , 7 parts of surfactant, 1.2 parts of organic phosphonic acid compound, 5.8 parts of ferrocene, 7 parts of defoamer, 5 parts of hydroxypropyl methylcellulose, 0.8 part of pH regulator and 78 parts of deionized water.
[0046] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0047] Step (A): Add 0.1 mol of 1,12-dibromododecane, 0.092 mol of 1,4-dimethylpiperazine and 85 ml of dimethyl sulfoxide into a 1000 ml dry three-neck flask. After reacting for 6 hours, add 0.0022mol of N-methylimidazole and 0.0022mol of N-methylmorpholine, react at 45°C for 6 hours, and distill the solvent under reduced pressure to obtain polyquaternium salt;
[0048] Ste...
Embodiment 3
[0057] In this embodiment, the metal antirust agent that meets the spraying adhesion is prepared from raw materials including the following components and parts by weight: 21 parts of polyquaternium-hyperbranched benzimidazole block polymer, 13 parts of polyacrylate , 5 parts of surfactant, 0.6 part of organic phosphonic acid compound, 4.4 parts of ferrocene, 5 parts of defoamer, 4 parts of hydroxypropyl methylcellulose, 0.5 part of pH regulator and 74 parts of deionized water.
[0058] Wherein, the preparation method of polyquaternium-hyperbranched benzimidazole block polymer comprises the following steps:
[0059] Step (A): Add 0.08 mol of 1,12-dibromododecane, 0.09 mol of 1,4-dimethylpiperazine and 90 ml of dimethyl sulfoxide into a 1000 ml dry three-necked flask. After reacting for 5 hours, add 0.0025mol of N-methylimidazole and 0.0025mol of N-methylmorpholine, react at 52°C for 5 hours, and distill the solvent under reduced pressure to obtain polyquaternium salt;
[0060...
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