A kind of water-based vacuum-absorbing plastic of pvc furniture film that can be rolled up and preparation method thereof
A membrane water-based, vacuum suction technology, applied in the direction of non-polymer adhesive additives, adhesive types, ester copolymer adhesives, etc., can solve problems such as pollution, flammable and explosive, and consumer health hazards at home , to achieve the effect of high bonding strength and strong bonding
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[0031] (1) Preparation of the monomer addition phase: 23.012 kg of methyl methacrylate monomer (Guangzhou Zhongye Chemical Co., Ltd.), 20.548 kg of methyl acrylate monomer (Shanghai Mairuier Chemical Technology Co., Ltd.) ), 0.44kg of glycidyl methacrylate monomer (Jiangxi Ruixiang Chemical Co., Ltd.), 0.00368 parts of isooctyl 3-mercaptopropionate (Sinopharm Chemical Reagent Co., Ltd.) chain transfer reagent and 2kg of ER-40 (ADEKA company) nonionic emulsifier dissolves 40min with the speed stirring of 500rpm;
[0032] (2) Preparation of the primer phase: 1.3kg of DowFax TM 8390 (DOW company) anionic emulsifier, 0.7kg of ER-40 (ADEKA company) nonionic emulsifier, 0.11kg of AMP-95 (Dow company) pH buffer, 0.08kg of potassium persulfate (Wujiang Sanyuan fine Chemical Co., Ltd.) initiator joins the deionized water of 39kg, stirs and dissolves with the speed of 400rpm, and begins to heat up;
[0033] (3) Polymerization stage: when the temperature of the base phase rises to 81°...
Embodiment 1
[0038] According to the formula amount of Example 1 in Table 1, the bonding resin is first added to a dispersing sand mill (SDF400 experimental dispersing sand mill, Jiangyin Shuangfeng Chemical Machinery Co., Ltd.), and begins to stir at a speed of 1500rpm; , ethanol co-solvent mixed and added to the dispersion sand mill; then E-668H wax additive, 3-aminopropyltriethoxysilane coupling agent, LeAD154 wetting agent, DF 3163 defoamer and DeuRheo WT-120 thickener were added in sequence, and finally the stirring speed was adjusted to 2000 rpm, stirred for 1 hour and filtered to obtain the PVC furniture film water-based vacuum plastic.
Embodiment 2
[0040] According to the formula quantity of Example 2 in Table 1, the bonding resin is first added to a dispersing sand mill (SDF400 experimental dispersing sand mill, Jiangyin Shuangfeng Chemical Machinery Co., Ltd.), and begins to stir at a speed of 2000rpm; , ethanol co-solvent mixed and added to the dispersion sand mill; then E-668H wax additive, 3-aminopropyltriethoxysilane coupling agent, LeAD154 wetting agent, DF 3163 defoamer and DeuRheo WT-120 thickener were added in sequence, and finally the stirring speed was adjusted to 2500 rpm, stirred for 1 hour and filtered to obtain the PVC furniture film water-based vacuum plastic.
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