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Method for preparing high emissivity anodized film layer

An anodic oxidation film and anodic oxidation technology, applied in anodic oxidation and other directions, can solve the problems of reducing the stability of parts and large cracks, and achieve the effects of reducing flow marks, fast coloring, and uniform coloring effect

Inactive Publication Date: 2018-11-09
湖北安登环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the increase in the thickness of the oxide film can increase the protective effect of the film layer, but in the space environment of alternating cold and heat, the thicker the film layer, the greater the probability of cracks, which reduces the stability of the part in the space environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Select an aluminum sheet made of 5A06, with a length of 100mm, a width of 50mm, and a thickness of 5mm, which is anodized and colored. Take the example of preparing 5L bath solution for each process.

[0057] (1) Pretreatment

[0058]1) Prepare a chemical degreasing solution with the concentration of sodium phosphate 50g / L, sodium carbonate 25g / L, add 250g sodium phosphate, 125g sodium carbonate, and water to the degreasing tank, and use it after the solution is fully dissolved. Put the aluminum sheet into the degreasing liquid to clean the oil stain on the surface, the temperature is 50°C, and the time is 15 minutes. After degreasing, put the test piece into running hot water to wash once, and then put it into running cold water to wash once.

[0059] 2) Prepare the alkali etching solution with a concentration of 30g / L sodium hydroxide, add 150g sodium hydroxide to the alkali etching tank, and the rest is water, and use it after the solution is fully dissolved. Put ...

Embodiment 2

[0070] Select an aluminum sheet made of 5A06, with a length of 100mm, a width of 50mm, and a thickness of 5mm, which is anodized and colored. Take the example of preparing 5L bath solution for each process.

[0071] (1) Pretreatment

[0072] 1) Prepare a chemical degreasing solution with a concentration of 60g / L sodium phosphate and 30g / L sodium carbonate, add 300g sodium phosphate, 150g sodium carbonate, and water to the degreasing tank, and use it after the solution is fully dissolved. Put the aluminum sheet into the degreasing liquid to clean the surface oil, the temperature is 60°C, and the time is 25min. After degreasing, put the test piece into running hot water to wash once, and then put it into running cold water to wash once.

[0073] 2) Prepare the alkali etching solution with a concentration of 40g / L sodium hydroxide, add 200g sodium hydroxide to the alkali etching tank, and the rest is water, and use it after the solution is fully dissolved. Put the degreased al...

Embodiment 3

[0084] Select an aluminum sheet made of 5A06, with a length of 100mm, a width of 50mm, and a thickness of 5mm, which is anodized and colored. Take the example of preparing 5L bath solution for each process.

[0085] (1) Pretreatment

[0086] 1) Prepare a chemical degreasing solution with a concentration of 70g / L sodium phosphate and 35g / L sodium carbonate. Add 350g sodium phosphate, 175g sodium carbonate and the rest to the degreasing tank, and use it after the solution is fully dissolved. Put the aluminum sheet into the degreasing liquid to clean the surface oil, the temperature is 70°C, and the time is 30min. After degreasing, put the test piece into running hot water to wash once, and then put it into running cold water to wash once.

[0087] 2) Prepare the alkali etching solution with a concentration of 50g / L sodium hydroxide, add 250g sodium hydroxide to the alkali etching tank, and the rest is water, and use it after the solution is fully dissolved. Put the degreased ...

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PUM

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Abstract

The invention discloses a method for preparing a high emissivity anodized film layer, and belongs to the technical field of surface treatment of aluminum and aluminum alloy, the method can provide a dense, uniform and non-cracking anodized film; the method comprises steps of (1) pretreatment; (2) anodization; (3) reaming oxidation; (4) coloring pretreatment; and (5) coloring; the anodized film layer prepared by a sulfuric acid-adipic acid adioxide oxidation process step is thin ( about 5-7m), dense, uniform, and low-porosity, cracks in the film layer due to changes in space environment can beavoided, and the problem of film cracking can be solved. The anodized film prepared by the method has a relatively high emissivity.

Description

technical field [0001] The invention belongs to the technical field of surface treatment of aluminum and its aluminum alloy, and relates to a method for preparing a high-emissivity anodized film layer. Background technique [0002] The anodized thermal control coating on the surface of the spacecraft mainly includes bright anodized thermal control coating and black anodized thermal control coating. The former is to form a thin layer of oxide film transparent to sunlight on the surface of polished aluminum by using anodic oxidation process, while the aluminum surface of the substrate has a high reflectivity to sunlight. By controlling the thickness of the oxide film, it can be changed The reflectivity of the film layer, thereby adjusting the absorption / emission ratio of the film layer. The latter utilizes the porosity of the oxide film to absorb other substances to form an outer surface with a high absorption rate. After the oxide film is treated, its thermal radiation prop...

Claims

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Application Information

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IPC IPC(8): C25D11/08C25D11/10C25D11/16C25D11/24
CPCC25D11/08C25D11/10C25D11/16C25D11/24
Inventor 程永青
Owner 湖北安登环保科技有限公司