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A kind of preparation method of graphene-coated conductive fiber

A conductive fiber and graphene technology, applied in the direction of animal fiber, fiber treatment, fiber type, etc., can solve the problems of poor bonding ability, poor conductivity, and less conductive coating, so as to enhance the conductivity and improve the conductivity. , to avoid the effect of poor electrical conductivity

Active Publication Date: 2020-05-12
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although the above method can coat the conductive material on the fiber, due to the poor binding ability, after washing, the conductive coating becomes less or disappears, and the conductivity is significantly deteriorated.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A method for preparing graphene-coated conductive fiber. The protein fiber is immersed in a positively charged graphene oxide dispersion at a temperature of 10°C. The pH of the protein fiber is> pI, the surface is negatively charged, and positively charged graphene oxide is adsorbed. After taking it out, it is rinsed and dried with deionized water, and then the graphene oxide on the fiber surface is reduced to graphene by a chemical reduction method to obtain a graphene-coated conductive fiber. Among them, the mass ratio of the negatively charged protein fibers on the surface to the positively charged graphene oxide dispersion is 1:100. The preparation method of the positively charged graphene oxide dispersion is as follows: the negatively charged concentration is 0.5 mg / mL Add 5mM AlCl to the graphene oxide dispersion 3 Solution to prepare a positively charged graphene oxide dispersion with a concentration of 0.1 mg / mL, a negatively charged graphene oxide dispersion and A...

Embodiment 2

[0030] A method for preparing graphene-coated conductive fiber. The modified negatively charged polyacrylonitrile fiber is immersed in a positively charged graphene oxide dispersion at a temperature of 15°C, and deionized water is taken out for rinsing and After drying, soaking in negatively charged graphene oxide dispersion liquid, taking it out, rinsing with deionized water and drying, reducing the graphene oxide on the fiber surface to graphene by high temperature thermal reduction method to obtain graphene coated conductive fiber. The mass ratio of the polyacrylonitrile fiber with negatively charged surface to the positively charged graphene oxide dispersion is 1:100, and the positively charged graphene oxide dispersion refers to the negatively charged concentration of 1.5mg / mL oxidation Add FeCl at a concentration of 0.1M to the graphene dispersion 3 The positively charged graphene oxide dispersion with the concentration of 0.5 mg / mL prepared in the solution, the negatively...

Embodiment 3

[0033] A method for preparing graphene-coated conductive fiber. The modified negatively charged PET fiber is immersed in a positively charged graphene oxide dispersion at a temperature of 20°C, and deionized water is taken out to rinse and dry. Then soak into the negatively charged graphene oxide dispersion, take it out, rinse and dry with deionized water, then soak again into the positively charged graphene oxide dispersion, take out the deionized water to rinse and dry, and finally remove it by UV Graphene oxide on the fiber surface is reduced to graphene to obtain graphene-coated conductive fiber. The mass ratio of the negatively charged PET fiber to the positively charged graphene oxide dispersion is 1:80, and the positively charged graphene oxide dispersion refers to graphite oxide with a concentration of 4.0 mg / mL that is negatively charged. 200mM TiCl was added to the ene dispersion 4 The positively charged graphene oxide dispersion with the concentration of 2.0 mg / mL pr...

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Abstract

The invention relates to a preparation method of a graphene coating conductive fiber. The preparation method comprises the steps that graphene oxide is assembled on a fiber by electrostatic interaction, and then subjected to reduction treatment to obtain the graphene coating conductive fiber, wherein the assembly is achieved by immersing the fiber with charges on the surface in a graphene oxide dispersion at a temperature of 10 to 30 DEG C for one or more times, the graphene oxide in the adjacent two immersed graphene oxide dispersions is oppositely charged each time, the soaking time is 5 to10 min each time, and post-treatment is conducted after each soaking; multiple soaking is 2 to 8 times; the conductivity of the obtained graphene coating conductive fiber is 10 to 1.5 multiply 10<3>S / m, and the conductivity remains above 95% or more after washing for 100 times. The preparation method is simple, the fiber coating efficiency is effectively improved by an electrostatic assembly method, the used coating layer is all graphene, the electrical conductivity and water washing performance of the fiber are significantly improved, and the preparation method of the graphene coating conductive fiber has a great application prospect.

Description

Technical field [0001] The invention belongs to the field of preparation of graphene conductive fibers, and relates to a method for preparing graphene coated conductive fibers. Background technique [0002] Smart fiber is an important direction for future fiber development. New electronic smart fiber based on the integration of electronic technology with sensing, communication, artificial intelligence and other technologies is one of the important varieties, and its basic unit is conductive fiber. However, most of the current synthetic fibers are not conductive. In order to make them conductive, most of them are modified with conductive materials such as metal / metal oxide particles, conductive polymers, and carbon nanomaterials. The modification methods in the prior art can be mainly divided into blending spinning and surface coating. Compared with blended spinning, the surface coating method is simple and easy. [0003] Graphene is a two-dimensional carbon nanomaterial that has ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M11/74D06M101/10D06M101/28D06M101/32D06M101/02
CPCD06M11/74D06M2101/02D06M2101/10D06M2101/28D06M2101/32
Inventor 柯福佑陈烨王华平宋非张慧颖李明明
Owner DONGHUA UNIV
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