A preparation method of composite photocatalytic material based on microbial template
A technology for composite photocatalysis and photocatalytic materials, which is applied in the field of composite photocatalytic material preparation based on microbial templates, can solve the coupling and synergistic effect of difficult composite photocatalytic materials, and it is difficult to realize zinc oxide-cadmium sulfide semiconductor heterojunction gold nanoparticles Problems such as nanoscale controllability of large and small loading sites, and difficulty in obtaining large-scale nanomaterials
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Embodiment 1
[0027] In this example, titanium dioxide is used as the photocatalytic material 5, Au is used as the catalytic loading material I6, and M13 phage is used as the biological template. The structure of M13 phage is as follows: figure 1 shown. The specific preparation process of the composite photocatalytic material is as follows:
[0028] 1) Use phage display technology to screen the polypeptide Ⅰ3 with specific adsorption and nucleation ability to the photocatalytic material titanium dioxide 5 and the polypeptide Ⅱ4 with specific adsorption and nucleation ability to the catalytic loading material ⅠAu6;
[0029] 2) Using genetic modification technology to express the polypeptide I3 with specific adsorption and nucleation ability on PⅧ protein 1 of M13 phage, and express the polypeptide II4 with specific adsorption and nucleation ability on PⅢ protein 2 of M13 phage, Its structure is as figure 2 shown;
[0030] 3) The concentration of 25mL genetic modification is 5×10 13 Pfu / ...
Embodiment 2
[0033] In this example, titanium dioxide is used as the photocatalytic material 5, Au is used as the catalytic supporting material I6, cadmium sulfide is used as the catalytic supporting material II8, and M13 phage is used as the biological template. The structure of M13 phage is as follows: figure 1 shown. The specific preparation process of the composite photocatalytic material is as follows:
[0034] 1) Use phage display technology to screen the polypeptide Ⅰ3 with specific adsorption and nucleation ability to the photocatalytic material titanium dioxide 5, the polypeptide Ⅱ4 with specific adsorption and nucleation ability to the catalytic loading material ⅠAu6, and the sulfidation of the catalytic loading material Ⅱ Cadmium 8 is a peptide III7 with specific adsorption and nucleation capabilities;
[0035] 2) Using genetic modification technology to express polypeptide I3 and polypeptide III7 with specific adsorption and nucleation ability on PⅧ protein 1 at different posi...
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