The invention relates to the technical field of
organic synthesis, in particular to a small-molecule
electron transport material containing a naphthalimide terminal group and preparation and application thereof.4-bromo-1, 8-
naphthalic anhydride is used as a
raw material, brominated naphthalimide terminal groups are obtained through imidization, then different conjugated fused ring core units are used as raw materials, and the small-molecule
electron transport material containing the naphthalimide terminal group is prepared through a one-
step method. And
coupling the conjugated fused ring core unit with naphthalimide through a
coupling reaction to obtain the small-molecule
electron transport material containing the naphthalimide terminal group. By virtue of
high electron affinity, strong electron withdrawing property, good
thermal stability and morphological stability and relatively strong designability of
structure and function of naphthalimide, the micromolecule electron transport material shows excellent
electron mobility, tight intermolecular accumulation and good three-dimensional charge transport characteristic; surface / interface defects can be effectively passivated, trap-assisted recombination is inhibited, and the
photoelectric conversion efficiency and the stability of the
perovskite solar cell are synergistically improved.