The invention belongs to the field of solar cells, and particularly relates to a
passivation contact composite layer and a
perovskite-
crystalline silicon laminated
solar cell. According to the
passivation contact composite layer structure, surface
passivation,
electron selective transmission and carrier recombination of the
silicon-bottom battery can be realized at the same time. The passivation contact composite layer comprises a SiO2 tunneling layer, a ZnO-based
electron selective transmission layer and a
hydrogen passivation cover layer. The wide-band-gap ZnO-based
electron selective transmission layer can avoid the problem of optical parasitic absorption caused by passivation contact of the
silicon thin film and has
high electron concentration and bulk
conductivity, and the ZnO-based electron selective transmission layer can further optimize the optical and electrical properties of the ZnO-based electron selective transmission layer by
doping one or more of B, Al, Ga and H elements. In addition, in order to form good contact, the
hydrogen passivation cap layer can be reserved or removed according to the
conductivity type and the device structure. The ZnO-based electron selective transmission layer can be covered with interface
layers such as MgOx, Mg, Al or Ti, so that the carrier recombination effect is further enhanced.