199 results about "Aluminium paste" patented technology

The invention relates to a back surface field aluminium paste for solar cells. The aluminium paste comprises the following components in parts by weight: 65-80 parts of aluminium powder, 1-5 parts of inorganic adhesive, 10-30 parts of organic carrier and 1-2 parts of modifier. Sintered films with lower warpage can be obtained through the back surface field aluminium paste.

The invention belongs to the technical field of solar cells, and particularly discloses a solar cell capable of saving silver paste and a preparation process of the solar cell. The solar cell comprises a silicon chip, a full-aluminium paste layer is coated on the back of the silicon chip, a back silver-plated copper band is arranged on the surface of the full-aluminium paste layer on the back of the silicon chip, a pattern of auxiliary grid lines is arranged on the front of the silicon chip, a plurality of front silver-plated copper bands with bottoms coated with silver paste are arranged on the surface of the auxiliary grid lines; the front silver-plated copper bands are arranged at intervals, and are extended out from the side surface of the silicon chip towards the back of the silicon chip; the front silver-plated copper bands comprise main grid lines and an outward welding band, wherein the main grid lines are arranged on the front of the silicon chip at intervals and form a front electrode, and the welding band is bent and extends towards the back of the silicon chip and is provided with a soldering tin material welded with the silver-plated copper band at the bottom of the adjacent silicon chip. With adoption of the solar cell capable of saving silver paste and the preparation process of the solar cell, the use of silver paste can be reduced, the shading area is reduced, the efficiency of the solar cell is improved, and simultaneously, the silver-pated copper bands can be directly used as the welding band between cell plates, thereby simplifying the welding process, effectively reducing the production cost and being suitable for large-scale industrial production.

The invention relates to an aluminium paste for preparing a crystal silicon solar cell aluminium back surface field and a manufacture method thereof. The paste comprises the following components in percentage by weight: 40-80wt% of aluminium powder, 3-45wt% of aluminium-silicon alloy powder, 0.5-10wt% of lead-free glass powder, 10-26wt% of organic solvent, 2-12wt% of thickening agent and 0.3-6wt% of organic addition agent. The manufacture method for the aluminium paste comprises the following steps: preparing the aluminium-silicon alloy powder; preparing the lead-free glass powder; preparing an organic carrier; proportioning all components; and synthetizing slurry. The aluminium paste has the advantages of reasonable component proportion, simple preparation technology, good adhesive force between the prepared aluminium paste and a solar cell silicon substrate, low slurry production cost, high peeling strength of the aluminium back surface field prepared by sintering, good formation of the aluminium back surface field, small cell sheet flexibility and high cell photoelectric conversion rate, and is suitable for industrial production, and the solar cell photoelectric conversion efficiency can be effectively improved.

The invention discloses a photosensitive aluminium paste for plasma display site-selection electrodes. The aluminium paste includes the following components: by a weight ratio, 36-59 parts of aluminium powder, 2-20 parts of conductive oxygen-free ceramic powder, 2-7 parts of an inorganic binder, 12-28 parts of an organic carrier, 6-15 parts of a photopolymerization monomer, 3-8 parts of a photoinitiator, and 2-3 parts of an additive. The photosensitive aluminium paste of the invention is added with the conductive oxygen-free ceramic powder, reducing the amount of used aluminium powder and the cost.

The invention discloses an environment-friendly crystalline silicon solar-cell back surface field silver-aluminium paste and a preparation method thereof. The silver-aluminium paste comprises the following components in percentage by weight: 15-35% of silver powder, 30-70% of aluminium powder, 10-15% of organic carrier, 1-5% of adhesive, 3.5-13% of solvent and 0.5-2% of dispersant. The organic carrier is prepared by dissolving 10-30% of ethyl cellulose resin in 70-90% of organic solvent. In the paste, environment-friendly glass powder without harmful substances is used as the adhesive, and an environment-friendly organic reagent is used as a solvent and a diluter; and thus, the prepared silver-aluminium paste does not contain six substances (Pb, Cd, Hg, Cr(VI), polybrominated diphenyl PBB and polybrominated diphenyl ether PBDE) inhibited by European Union RoHS Instruction, completely conforms to the Instruction 2005/84/EC on phthalic ester in European Union RoHS, realizes environment friendliness in deed, and is beneficial to the import and export of solar cells made in China and raw materials of the cells.

The invention discloses aluminium paste special for local aluminium back surface field crystalline silicon solar cells. The paste is prepared from, by mass, 70-80 parts of aluminium powder, 0.05-3 parts of inorganic bond, 17-27 parts of organic bond and 1-5 parts of additives in proportion. The invention further discloses a preparation method of the aluminium paste special for the local aluminium back surface field crystalline silicon solar cells. Compared with traditional aluminium paste, the aluminium paste specially applied to the local aluminium back surface field crystalline silicon solar cells has the advantages of good fluidity, small damage to passivating films, good contact with a window, density and uniformity in aluminium coatings, and the like. Average conversion efficiency of mass production of the aluminium paste applied to the local aluminium back surface field crystalline silicon solar cells is more than or equal to 20.0%, and tested aluminium back surface field adhesion tension is more than or equal to 10N via EVA tearing test after the cells are laminated and encapsulated.

The invention discloses a preparation method of a back-contact electrode structure of a crystal silicon solar cell. The method comprises the steps of performing silk-screen printing of aluminium paste containing frit on a SiNx film passivation layer on a crystal silicon chip formed with the SiNx film passivation layer by deposition, and then performing the silk-screen printing of complete aluminium paste, and finally sintering at high temperature to prepare the back-contact electrode structure. The method of the invention has simple working procedures and low cost, and is suitable for mass production and for preparing the crystal silicon solar cell with high transformation efficiency in the condition that the silicon chip is continuously thinned.

The invention provides aluminium paste for a silicon solar battery, which comprises the following materials: 1-3% of glass powder, 45-60% of first powered aluminum, 20-45% of second powered aluminium, 1-10% of powered aluminium alloy, 15-20% of first organic carrier, 21-5% of second organic carrier, 0.1-0.5% of dispersing agent, 0.1-0.5% of deforming agent and 0-1% of metallic oxide. The aluminium paste for the silicon solar battery, provided by the invention, has the advantages of being capable of preventing silicon slices from warping and alumina beads from forming after baking and having strong adhesive force.

The invention discloses a preparation method of a back junction N type solar battery, a back junction N type solar battery, a back junction N type solar battery assembly and a back junction N type solar battery system. According to the preparation method of the back junction N type solar battery, an N type crystalline silicon substrate is processed; a slotted structure penetrating a passivation film is formed on the back surface of the N type crystalline silicon substrate; aluminium paste is printed on the back surface of the N type crystalline silicon substrate, thus forming a back aluminium electrode; silver paste is printed on the back surface of the N type crystalline silicon substrate, thus forming a back silver master gate electrode; the silver paste is printed on the front surface of the N type crystalline silicon substrate, thus forming a front electrode; and sintering is carried out, thus forming the back junction N type solar battery. The method, the battery, the assembly and the system provided by the invention has the advantages that the passivation film on the back surface is slotted; the aluminium paste is printed; the aluminium paste forms partial contact with the p+ doped layer on the back surface, only at the location of the slotted pattern; compared with the method of printing the electrode by aluminium doped silver paste, the method provided by the invention has the advantages of improving the open-circuit voltage of the battery, greatly reducing silver paste consumption of the battery sheet and reducing the preparation cost of the battery sheet.

The invention discloses a method for preparing a polycrystalline silicon solar cell by RIE texturing. The method comprises the following steps that (1) plasma dry etching is used for removing a front surface damage layer of a polycrystalline silicon chip, and then RIE texturing is conducted; (2) a chained wet chemical processing method is used for sequentially conducting back face etching polishing, RIE damage layer removing and post cleaning processing on the silicon chip; (3) the texturing surface of the silicon chip is subjected to phosphorus source diffusion in a back-to-back chip inserting mode; (4) the diffused silicon chip is subjected to wet etching, surface PSG is removed, and then a passivation antireflection film is deposited on the front surface of the silicon chip; (5) back silver and aluminium paste are printed on the back face of the silicon chip and then are dried; then front silver is printed on the front surface of the silicon chip and then is sintered, and accordingly the polycrystalline silicon solar cell can be obtained. According to the method, the technology steps can be reduced, the using amount of chemicals is also reduced simultaneously, and the operation cost of an enterprise is greatly lowered.

The invention discloses an all Al-BSF crystal silicon cell and a preparation method thereof. The all Al-BSF crystal silicon cell comprises a silicon wafer layer (7), wherein a P+ passivation layer (5) and an Al-BSF conducting layer (4) are sequentially bonded on a back face of the silicon wafer layer (7); and a back electrode (6) is arranged on the Al-BSF conducting layer (4). The method comprises the following steps of: printing one layer of aluminium paste on all positions of a back face of a solar cell expect for edges; printing the back electrode; and forming the P+ passivation layer on an electrode area through sintering. Due to the structure of the cell, direct contact of silver and a silicon wafer is avoided, so that the complex defects of a back electrode area is greatly reduced; the photoelectric conversion efficiency of the crystal silicon cell can be greatly improved; and compared with a preparation manner of a general cell, an overlapping area of the back electrode and BSF can be neglected, and the width of the electrode can be reduced, so that the production cost is reduced.

The invention relates to a crystal silicon cell back field back pole and a printing technology thereof. Aluminium paste is printed on the back surface of a crystal silicon sheet and is dried at certain temperature to form an aluminium back field; and back electrode slurry is printed on the dried aluminium paste surface to form a back electrode pattern. According to the printing technology, the area of the crystal silicon cell aluminium back field can be increased, crystal silicon back surface compound is reduced, and the gettering effect of the aluminium back field is increased, and the electric performance of the crystal silicon cell is effectively improved.

The invention discloses a P-type PERC double-faced solar cell employing laser marking alignment and a preparation method thereof. The P-type PERC double-faced solar cell comprises back electrodes, a back side silicon nitride film, an alumina film, P-type silicon, an N-type emitter electrode, a front side silicon nitride film and positive silver electrodes which are sequentially arranged from bottom to top. Each back electrode is formed by a back electrode main grid and a back aluminum grid line which are vertically crossed and are connected with each other, the back side silicon nitride film is provided with several grooves traversing the back side silicon nitride film and the alumina film to form laser grooving zones, the P-type silicon is exposed in the grooves, the parts, of the back aluminum grid lines, arranged in the grooves are connected with the P-type silicon, the back side silicon nitride film is provided with laser marks, relative positions of the laser marks and the laser grooving zones are preset, by positioning the laser marks and in dependence on the distance between the laser grooving zones and the laser marks, the printing back aluminum grid lines are aligned. According to the invention, aluminium paste on the back side of each silicon chip can accurately cover the laser grooving zones, and the fraction defective of the double-faced PERC solar cells can be effectively reduced.

The invention discloses nano silicon boron slurry and a method for preparing N type composite emitter and an improved P type solar cell with the nano silicon boron slurry. The nano silicon boron slurry is used as a carrier, and local boron adulteration of the grating line coverage area of the solar cell back through laser or high-temperature treatment can be realized. The method is combined with the aluminum paste sintering process to prepare an N-type composite emitter cell when an N type cell is produced so that the problems that the ordinary aluminum paste sintering process only forms emitters in the aluminum paste coverage area and the emitters in the silver grating line coverage area are not continuous can be solved, and the photovoltaic conversion efficiency of the N type aluminum emitter cell is improved. The method is combined with the original aluminum paste sintering process to prepare the improved P type cell when the P type cell is produced so that the problems that the original P type cell only forms a back surface field in the aluminum slurry coverage area and the back surface field in the silver grating line coverage area is not continuous can be solved.

The invention relates to crystalline silicon solar cell back surface field aluminum paste and a preparation method thereof. The crystalline silicon solar cell back surface field aluminum paste comprises, by weight, 74 parts of aluminum powder, 20-25 parts of organic bonds, 1-4 parts of lead-free glass powder and 0.1-2 parts of additives, wherein the organic bond comprises, by weight, 40-70 parts of terpineol, 5-10 parts of butyl carbitol, 5-10 parts of butyl carbitol acetic ester, 3-10 parts of ethyl cellulose, 5-15 parts of dibutyl phthalate and one part of sorbitol anhydride stearate; the lead-free powder comprises, by weight, 30-60 parts of Bi2O3, 5-15 parts of B2O3, 3 parts of BiF3, 10-20 parts of SiO2, 5-10 parts of ZnO, 1-5 parts of TiO2, 10-20 parts of Al2O3 and 1-3 parts of P2O5; and the additive is spherical copper powder with the purity larger than 99% and the fineness being 20000 meshes. The aluminum powder, the organic bonds, the lead-free glass powder and the additives are evenly mixed and then rolled by a three-roll grinder until the fineness is smaller than or equal to 10 mum and the viscosity is 30-60Pa*s. The crystalline silicon solar cell back surface field aluminum paste is high in photoelectric conversion efficiency and adhesive force, the adhesive force conversion efficiency after high temperature aging declines, and the water-boiling resistance is good.

The invention provides non-floating type silicon dioxide coated waterborne aluminium paste and a preparation method thereof. The non-floating type silicon dioxide coated waterborne aluminium paste is characterized in that the aluminium paste is self-assembled silicon dioxide colloidal particles; SiO2 colloids with negative electricity are evenly and compactly absorbed on the front surface of aluminium powder with positive electricity; the particle size of the aluminium powder with positive electricity is 5-50nm; and the thickness of the silicon dioxide film coated on the aluminium powder surface is 1-10nm. The non-floating type aluminium paste has various types, the tinting strength of the non-floating type aluminium paste is increased from low to high, the grain size of the non-floating type aluminium paste is reduced from thick to thin, and the appearance of the non-floating type aluminium paste is from white, bright to darker and is more and more finer; and in addition, a series of acid-resisting products can reduce influences of industrial smog, acid rain and other adverse environments on paints.

A provided aluminium paste anode electrophoresis tank liquid is composed of anode electrophoresis paint, aluminium paste, an aluminium paste auxiliary agent, a solvent and deionized water. A provided aluminium paste anode electrophoresis technology comprises the following steps: (1) pretreating a base material; (2) putting the pretreated base material in the aluminium paste anode electrophoresis tank liquid for electrophoresis, and controlling all technological parameters; (3) washing by using pure water; and (4) solidifying and drying. Various technological problems in the prior art are broken through, the developed liquid and technology are suitable for aluminium paste anode electrophoresis, an electrophoresis film with the thickness of 15-30 mu m is obtained, and the film is uniform in thickness, high in hardness, good in adhesive force, good in wear resistance, flat in appearance, slivery white and strong in metal texture, and possesses both corrosion resistance and decorative property.

The invention discloses a special high temperature-resistant coating on an outer wall of a tobacco-curing furnace, which consists of the following components according to parts by weight: 30-40 parts of organic silicon resin, 5-10 parts of aluminium paste, 8-12 parts of titanium white, 30-40 parts of mixed stuffing, 0.5-1.5 parts of organic bentonite, 2-4 parts of PM, 1-3 parts of PMA (Propylene Glycol Monomethyl Acetate), and 4-6 parts of absolute ethyl alcohol, wherein the mixed stuffing consists of the following components according to parts by weight: 35-45 parts of low-melting point glass powder, 10-20 parts of hollow ceramic microspheres, 10-20 parts of zinc phosphate, 5-15 parts of aluminum tripolyphosphate and 18-22 parts of talcum powder. The special high temperature-resistant coating on the outer wall of the tobacco-curing furnace mainly has the advantages that a viscosity number reaches 85s, the percentage of solid reaches 65%, surface dry only needs 16 minutes, hard dry only needs 6 hours, the thermal endurance is strong, and the coating is not stripped for 6h at 500 DEG C. The coating has the advantages of high temperature resistance, rust prevention, quick drying, heat insulation, environmental protection and the like, can satisfy the use requirements on the outer wall of the tobacco-curing furnace, and is especially applicable for the tobacco-curing furnace.

The invention relates to a lead-free glass powder for the aluminium paste of a solar cell and a preparation method for the same. The lead-free glass powder comprises the following components in percentage by weight: 20-29% of bismuth oxide, 5-15% of boron oxide, 21-39% of silicon oxide, 5-30% of zinc oxide, 1-10% of calcium oxide, 1-10% of antimony oxide and 0.5-5% of tin oxide, wherein the total of the percentages by weight of the raw material components is 100%; the median particle diameter of the glass powder is 2 mum, and the maximum particle diameter of the glass powder is 5 mum; and the softening temperature of the glass powder is 400-550 DEG C. Compared with the prior art, the lead-free glass powder for the aluminium paste of a solar cell disclosed by the invention is low in the content of the bismuth oxide component, high in the contents of the silicon oxide component and the boron oxide component, good in wettability with a silicon substrate, and capable of forming good bonding with the silicon substrate; and moreover, the glass powder is capable of avoiding damages on the substrate due to the over-reaction of the glass powder and the silicon substrate during sintering, beneficial to the epitaxial growth of the silicon substrate to form a P+ layer, and capable of increasing the electric performance of the cell slice.

The invention discloses a solar cell wafer and a printing screen thereof. The number of the meshes of the two edge engraved areas of the printing screen parallel with the printing direction is less than the number of the meshes of the other engraved area. By changing the parameter of part of the edge engraved areas of the printing screen, the thickness of aluminium paste printed on the whole silicon wafer is enabled to be uniform, the surface of the edge area with thin aluminium is prevented from becoming rough or producing aluminium balls due to temperature fluctuation when sintering temperature is high, the sintering temperature regulation range is broadened, consequently, the surface electric contact capability between the front electrode, the back electrode and the back electric field of the solar cell wafer can be enhanced by increasing the sintering temperature, and thereby the conversion efficiency of a solar cell can be increased ultimately.

The invention discloses a production method of superfine spherical aluminium powder, which comprises the steps of ball-milling coarse aluminium powder in a ball mill under the shielding of nitrogen, crushing the coarse aluminium powder to fine flake aluminum powder, placing the flake aluminum powder into a powder feeder, replacing gas in a plasma spraying system with inert gas to form an oxygen-free atmosphere, then starting the plasma spraying system, adjusting the power of a plasma spray gun to reach a setting value, starting the powder feeder, allowing the aluminium powder to pass through a plasma arc of the plasma spray gun under gas delivery, allowing the fine flake aluminum powder heated by the plasma arc of the plasma spray gun to be melt into small liquid drops, and rapidly cooling the small liquid drops to the superfine spherical aluminium powder in a cooling kettle. The production method has the advantages that the produced aluminium powder is spherical, good in dispersity, high in activity, uniform in size distribution and narrow in particle size distribution, is 1-5 micrometers in particle size, and can be completely applied to aluminium paste for back surface fields of silicon solar cells, raw materials are used fully, the production efficiency is high, and the materials are not wasted.

The invention relates to a preparation method of an organic binding agent for silicon solar cell aluminum paste, belonging to the technical field of solar cells. The preparation method comprises the following steps: dissolving polyalcohol in water, adding cellulose, polylactic acid, 2-ethylhexyl acrylate, acrylamide and surfactant, and stirring uniformly to obtain a mixture I; heating the mixture I, dropwisely adding acrylic acid and initiator, and keeping the temperature to obtain a mixture II; cooling the mixture II, and regulating the pH value to 6.0-8.0 to obtain a mixture III; and adding diethanolamine and aluminum sol into the mixture III, and stirring uniformly. When being applied to solar cell aluminum paste, the organic binding agent prepared by the method can enhance the binding strength and lower the resistivity, and has low fragment rate especially when the solid content of the aluminum sol is controlled at 20%.

The invention provides an aluminum strip for cigarette package ink. A preparation process is as the follows: under a heating condition, carrying out functionalization modification on a surface of an aluminum sheet by cooperation of partial free acrylic acid and/or acrylic acid ester in a solution and cellulose functional molecules, carrying out a free radical polymerization reaction on residual acrylic acid and/or acrylic acid ester on the surface of the aluminum sheet to form a polymer serving as molded resin, and carrying out pressure filtration, hydraulic extrusion molding and vacuum staticbaking on the materials to obtain the aluminum strip. The preparation raw materials comprise a solvent, an initiator, aluminum paste, a component A and a component B, wherein the component A comprises at least one selected from hydroxypropyl methacrylate, methyl methacrylate, hydroxyethyl acrylate, isobornyl acrylate, butyl acrylate and methacrylic acid, and the component B comprises at least oneselected from cellulose acetate butyrate, cellulose acetate propionate and cellulose nitrate. According to the invention, functionalization of the surface of the aluminum sheet and one-step generation of the molded resin are realized, and the aluminum strip product has excellent metal effect, striping property and printing adaptability.

The invention discloses an aluminium paste for a laser pore-forming partial back contact-passivating emitter crystalline silicon solar cell and a preparation method and an application thereof. The aluminium paste comprises the following components in percentage by weight: 50.00-75.00% of micro-size aluminium powder, 0.50-2.00% of glass powder, 15.00-30.00% of organic intermediate, 0.02-1.00% of inorganic additive and 1.00-2.50% of organic additive, and the sum of the components of the aluminium paste is 100% in percentage by weight. The required aluminium paste is prepared by steps of dosing, dual-planetary stirring, three-roller machine grinding, screening and filtering. When the aluminium paste is applied, the aluminium paste is printed on a monocrystalline wafer by a 325-mesh silk screen, and then the monocrystalline wafer is dried and sintered. An aluminium back field is formed in the pore-forming place in the back surface of the battery piece by the aluminium paste; the aluminium paste is relatively strong in adhesion with the passivating layer in the non-pore-forming places; and in addition, pill of aluminium or aluminium protruding parts are not formed on the surface of an aluminium film, so that the formed aluminium electrode is excellent in the electrical performance.