The invention discloses a silver-doped
copper zinc tin sulfur selenium light
absorption layer film material. The
film material is prepared by virtue of the following method: (1) adding 0.07 to 0.13 mol / L of
metal copper salt and
metal silver salt into an
organic solvent, stirring until the
metal copper salt and the metal silver salt are completely dissolved, adding 0.03 to 0.07 mol / L of metal
tin salt, further stirring until the metal
tin salt is dissolved, then adding 0.03 to 0.09 mol / L of metal
zinc salt, stirring until the metal
zinc salt is completely dissolved, finally adding 2 mol / L of
sulfur-containing compound, and stirring until the
sulfur-containing compound is completely dissolved to form a stable ACZTS precursor solution; (2) ultrasonically cleaning
molybdenum plated glass successively with
acetone, absolute ethyl
alcohol and deionized water; (3) spin-
coating the
molybdenum plated glass substrate with the precursor solution, and repeatedly spin-
coating and depositing; and (4) after the
spin coating is completed, selenizing the sample. The invention also discloses an application of the
film material in a
solar cell. By
doping Ag, the quality of the film can be improved, an open-circuit
voltage, a packing factor and
photovoltaic conversion efficiency of a device are effectively increased, and the experimental
repeatability and stability are also good.