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Aluminium paste anode electrophoresis tank liquid and aluminium paste anode electrophoresis technology

A technology of anodic electrophoresis and anodic electrophoretic paint, applied in the direction of electrophoretic plating, electrophoretic coating, electrolytic coating, etc., can solve the problems of large damage to the human body and the surrounding environment, large volatilization, long curing time, etc., so that it is not easy to oxidize and change color , low organic solvent content, good electrophoretic hiding power

Inactive Publication Date: 2015-12-16
东莞市霖辉金属表面处理材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the traditional aluminum-silver paste spraying organic solvent has a large amount of volatilization, which has a great harm to the human body and the surrounding environment, which is not conducive to environmental protection; in addition, the utilization rate of spraying materials is low, the waste is large, and the cost is relatively high; there are many spraying processes and long curing time , low production efficiency, complex equipment requirements, high processing environment requirements, sagging, dead angles, and uneven edges, all of which restrict the popularization and application of the aluminum-silver paste spraying process, and replace the aluminum-silver paste spraying process with the aluminum-silver paste electrophoresis process It is a new bright spot in the field of coating. Some people have studied and tried to obtain a suitable process, but the aluminum-silver paste electrophoresis process is not so easy to implement. Generally, the existing electrophoretic paint uses water-based paint, and the electrophoretic bath is acidic (or alkaline) properties), aluminum is an amphoteric metal, it will corrode when it encounters acid and alkali, it is also easy to oxidize and change color in the air, and the coating of silver paste is also easy to be damaged. In addition, the proportion of silver paste is relatively large, these factors cause aluminum In the process of trial production and production of silver paste anodic electrophoresis, problems such as darkening of paint, reduction of hiding power, coarse particles of paint film, oxidation blackening, yellowing, and silver paste precipitation are likely to occur, which directly affect the aluminum silver paste electrophoresis process. Popularization and application has become a difficulty in the combined application of aluminum silver paste and electrophoretic paint

Method used

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  • Aluminium paste anode electrophoresis tank liquid and aluminium paste anode electrophoresis technology
  • Aluminium paste anode electrophoresis tank liquid and aluminium paste anode electrophoresis technology
  • Aluminium paste anode electrophoresis tank liquid and aluminium paste anode electrophoresis technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0082] Example 1: Implementation steps of anodic electrophoresis process of aluminum-silver paste on iron substrate

[0083] (1) Ultrasonic (hot soak) degreasing and wax removal

[0084] Aqueous solution formula: sodium hydroxide (NaOH) 20g / L sodium carbonate (NaOH) 2 CO 3 )20g / L trisodium phosphate (Na 3 PO 4 )5g / LOP emulsifier 1g / L Operating temperature: 70°C Time: 30s Equipment requirements: use with ultrasonic

[0085] (2) Electrodegreasing

[0086] Aqueous solution formula: sodium hydroxide (NaOH) 20g / L sodium carbonate (NaOH) 2 CO 3 )10g / L trisodium phosphate (Na 3 PO 4 ) 30g / L Surfactant 1g / L Operating temperature: 50°C Current density: 5A / dm 2 Time: 1min

[0087] (3) Washing

[0088] running water

[0089] (4) pickling

[0090] Solution formula: HCl (d=1.19) 150g / L Operating temperature: room temperature Time: 2min

[0091] (5) Washing

[0092] running water

[0093] (6) Phosphating

[0094] Aqueous solution formula: zinc dihydrogen phosphate [Zn(H 2 ...

Embodiment 2

[0112] Embodiment 2: Implementation steps of anodic electrophoresis process of zinc alloy aluminum silver paste

[0113] (1) Ultrasonic (hot soak) degreasing and wax removal

[0114] Aqueous solution formula: sodium carbonate (Na 2 CO 3 )20g / L sodium silicate (Na 2 SiO 3 ) 20g / L Surfactant 1g / L Operating temperature: 40°C Time: until cleaning Equipment requirements: use with ultrasonic

[0115] (2) Cathodic electrolytic degreasing

[0116] Aqueous solution formula: Sodium Hydroxide (NaOH) 1g / L Sodium Carbonate (NaOH) 2 CO 3 )5g / L trisodium phosphate (Na 3 PO 4 ) 20g / L Surfactant 1g / L Operating temperature: 40°C Cathode current density: 5A / dm 2 Time: 0.5min

[0117] (3) Washing

[0118] running water

[0119] (4) Film removal (light emitting)

[0120] Aqueous solution formula: nitric acid (HNO 3 ) 2% (weight percent) temperature: room temperature time: 2s

[0121] (5) Washing

[0122] running water

[0123] (6) Passivation

[0124] Aqueous solution formula: ch...

Embodiment 3

[0142] Example 3: Implementation steps of aluminum alloy aluminum silver paste anodic electrophoresis process

[0143] (1) Ultrasonic (hot soak) degreasing and wax removal

[0144] Aqueous solution formula: sodium carbonate (Na 2 CO 3 )50g / L trisodium phosphate (Na 3 PO 4 )50g / L sodium silicate (Na 2 SiO 3 )30g / L Operating temperature: 80°C Time: until cleaning Equipment requirements: use with ultrasonic

[0145] (2) washing

[0146] running water

[0147] (3) Microetching

[0148] Aqueous solution formula: sodium hydroxide (NaOH) 80g / L Temperature: 70°C Time: 30s

[0149] (4) Washing

[0150] running water

[0151] Aqueous solution formula: concentrated nitric acid (HNO 3 )500g / L Temperature: room temperature Time: 15s

[0152] (6)Washing

[0153] running water

[0154] (7) Anodizing

[0155] Aqueous solution formula: sulfuric acid (H 2 SO 4 )200g / L aluminum ion (Al 3+ ) 15g / L Temperature: 25°C Current density 1.5g / L Voltage 20v Power supply: DC Time: 10min...

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Abstract

A provided aluminium paste anode electrophoresis tank liquid is composed of anode electrophoresis paint, aluminium paste, an aluminium paste auxiliary agent, a solvent and deionized water. A provided aluminium paste anode electrophoresis technology comprises the following steps: (1) pretreating a base material; (2) putting the pretreated base material in the aluminium paste anode electrophoresis tank liquid for electrophoresis, and controlling all technological parameters; (3) washing by using pure water; and (4) solidifying and drying. Various technological problems in the prior art are broken through, the developed liquid and technology are suitable for aluminium paste anode electrophoresis, an electrophoresis film with the thickness of 15-30 mu m is obtained, and the film is uniform in thickness, high in hardness, good in adhesive force, good in wear resistance, flat in appearance, slivery white and strong in metal texture, and possesses both corrosion resistance and decorative property.

Description

technical field [0001] The invention belongs to the technical field of electrophoresis, and in particular relates to a process method for applying aluminum-silver paste as a metal pigment to anode electrophoresis. Background technique [0002] Aluminum powder is commonly known as aluminum silver powder or silver powder because of its silvery-white metallic luster. Water-based paint. Aluminum pigment, also known as aluminum silver powder or aluminum silver paste, is an important variety of metal pigments. Aluminum silver paste is also called aluminum powder paste. It is a malleable external coating made by stirring and dispersing aluminum powder and organic solvents. Tough flakes of cladding, this kind of aluminum flake is characterized by smooth and flat surface, concentrated particle size distribution, regular shape, excellent light reflection ability and metallic luster, used as a pigment in paint, can make the paint film produce Obvious color flop effect, appearance ran...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/44C09D4/02C09D4/06C09D7/12C25D13/08
Inventor 谢辉
Owner 东莞市霖辉金属表面处理材料有限公司
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