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Method for extracting gold and silver in clay-graphite crucible slag through alkali roasting

A graphite crucible and clay technology is applied in the field of alkali roasting to extract gold and silver in clay graphite crucible slag, which can solve the problems of low recovery efficiency of gold and silver, affecting the recovery and extraction of gold and silver, and achieve the effect of improving the extraction rate.

Inactive Publication Date: 2018-12-21
CHENZHOU CITY JINGUI SILVER IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem that the refractory clay in the crucible slag seriously affects the recovery and extraction of gold and silver, resulting in low recovery efficiency of gold and silver, the present invention provides a novel wet / fire method combined method and process flow, which is effective for the recovery and extraction of gold and silver in the clay graphite crucible slag. Gold and silver for recycling

Method used

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  • Method for extracting gold and silver in clay-graphite crucible slag through alkali roasting
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  • Method for extracting gold and silver in clay-graphite crucible slag through alkali roasting

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Embodiment 1

[0045] 1) Use a pulverizer to crush, grind, and sieve the waste clay graphite crucible to obtain a clay graphite crucible slag powder with a particle size of 200 meshes. The content of each metal element in the clay graphite crucible slag powder obtained by analysis and detection is as follows: Au: 0.013% , Ag: 5.284%, Cu: 0.710%; weigh clay graphite crucible slag powder and sodium hydroxide according to the mass ratio of 1:1, add 2% of the total mass of clay graphite crucible slag powder, sodium hydroxide and lithium metaborate % of lithium metaborate is then mixed evenly, placed in a muffle furnace, baked at 600°C for 2 hours in an air atmosphere, then cooled naturally to room temperature, ground and pulverized into sample powder;

[0046] 2) The sample powder is stirred and cleaned with pure water for 30 minutes, and then filtered to separate the filtrate I and filter residue, and the filter residue is stirred and cleaned with a hydrochloric acid solution with a concentratio...

Embodiment 2

[0050] 1) Use a pulverizer to crush, grind, and sieve the waste clay graphite crucible to obtain a clay graphite crucible slag powder with a particle size of 150 meshes. The content of each metal element in the clay graphite crucible slag powder obtained by analysis and detection is as follows: Au: 0.013% , Ag: 5.284%, Cu: 0.710%; Weigh clay graphite crucible slag powder and sodium hydroxide according to the mass ratio of 2:1, add 0.5% of the total mass of clay graphite crucible slag powder, sodium hydroxide and lithium metaborate. % of lithium metaborate is then mixed evenly, placed in a muffle furnace, baked at 500°C for 1 hour in an air atmosphere, then cooled naturally to room temperature, ground and pulverized into sample powder;

[0051] 2) The sample powder is stirred and cleaned with pure water for 60 minutes, and then filtered to separate the filtrate I and filter residue, and the filter residue is stirred and washed with a hydrochloric acid solution with a concentrati...

Embodiment 3

[0055] 1) Use a pulverizer to crush, grind, and sieve the waste clay graphite crucible to obtain a clay graphite crucible slag powder with a particle size of 325 meshes. The content of each metal element in the clay graphite crucible slag powder obtained by analysis and detection is as follows: Au: 0.013% , Ag: 5.284%, Cu: 0.710%; Take clay graphite crucible slag powder and sodium hydroxide by mass ratio 1:2, add 3% of the total mass of clay graphite crucible slag powder, sodium hydroxide and lithium metaborate % of lithium metaborate is then mixed evenly, placed in a muffle furnace, baked at 700°C for 1.5 hours in an air atmosphere, then cooled naturally to room temperature, ground and pulverized into sample powder;

[0056] 2) The sample powder is stirred and cleaned with pure water for 120 minutes, and then filtered and separated to obtain filtrate I and filter residue, and the filter residue is stirred and washed with a hydrochloric acid solution with a concentration of 2mo...

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Abstract

The invention discloses a method for extracting gold and silver in clay-graphite crucible slag through alkali roasting. The method for extracting gold and silver in clay-graphite crucible slag throughalkali roasting comprises the following steps that clay-graphite crucible slag powder is mixed with sodium hydroxide and a fluxing agent, roasting is conducted at the temperature of 600 DEG C, and cooling, washing, pickling, filtering, drying and grinding are conducted to obtain concentrated slag; the concentrated slag is placed in a nitric acid solution to react with the nitric acid solution atthe normal temperature, then dilution and filtering are conducted to obtain leached residue I and leachate I, and the leachate I is reduced to extract silver; and the leached residue I is placed in nitrohydrochloric acid and is completely diluted and filtered after reacting with the nitrohydrochloric acid to obtain leached residue II and leachate II, and the leachate II is reduced to extract gold.According to the method for extracting gold and silver in clay-graphite crucible slag through alkali roasting, insoluble substances (aluminosilicate) and sodium hydroxide in clay are converted into dissoluble sodium silicate and sodium metaaluminate under the high-temperature melting condition, and then clay elements in the dissoluble sodium silicate and the sodium metaaluminate are effectively removed through washing and picking, so that clay-graphite crucible slag is prevented from being caked in the calcinating process, gold and silver are separated from other impurities, and the leachingrecovery rate of gold and silver is increased.

Description

technical field [0001] The invention belongs to the technical field of non-ferrous metal recovery, and in particular relates to a method for extracting gold and silver in clay graphite crucible slag by alkali roasting. Background technique [0002] When smelting metals by fire method, clay graphite crucibles are often used to cast the smelted metals, and a small amount of crude metal will penetrate into the crucibles during smelting and pouring. The crucible is used many times, and a large amount of metal will be enriched on the inner wall of the crucible. Especially when smelting gold, the clay graphite crucible used is enriched with more gold and silver. Gold and silver are high-value precious metals with extremely high economic recovery value. [0003] Ye Zhiqing announced a method for extracting indium and germanium from pyrometallurgical crucible slag by using the full wet method (patent application number CN201010169155. Indium, then MnO 2 Using concentrated sulfuri...

Claims

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Application Information

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IPC IPC(8): C22B7/00C22B1/02C22B11/00
CPCC22B1/02C22B7/001C22B7/007C22B11/023C22B11/044Y02P10/20
Inventor 田宁郴李环尹涛谢兆凤
Owner CHENZHOU CITY JINGUI SILVER IND CO LTD