Anti-dropping ink and preparation method thereof
An anti-shedding and ink technology, applied in the direction of ink, household utensils, applications, etc., can solve the problems of slow development, ink easy to fall off, low peeling strength, etc., achieve good adhesion, improve mechanical stability, and improve anti-shedding performance Effect
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Embodiment 1
[0024] A kind of anti-shedding printing ink, it is made up of the raw material of following weight part:
[0025] Bisphenol A modified phenolic resin 20, tert-butyl p-diphenol 2, polysorbate 1, barium naphthenate 0.2, nano silicon dioxide 5, stearic acid 5.
[0026] Described bisphenol A modified phenolic resin is made up of the raw material of following weight part:
[0027] Triethanolamine 10, oleic acid 8, bisphenol A3, phenol 30, 37% formaldehyde 50, sodium hydroxide 2, rosin 5, silane coupling agent kh5504.
[0028] The preparation method of described bisphenol A modified phenolic resin, comprises the following steps:
[0029] (1) Mix oleic acid and rosin, add it to toluene which is 3 times the weight of the mixture, stir evenly, raise the temperature to 75°C, add triethanolamine, keep stirring for 2 hours, add bisphenol A, stir evenly, and send Into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 95°C, heat and stir for 50 minutes, ...
Embodiment 2
[0036] A kind of anti-shedding printing ink, it is made up of the raw material of following weight part:
[0037] Bisphenol A modified phenolic resin 10, tert-butyl p-diphenol 1, polysorbate 0.4, barium naphthenate 0.1, nano silicon dioxide 4-5, stearic acid 3.
[0038] Described bisphenol A modified phenolic resin is made up of the raw material of following weight part:
[0039] Triethanolamine 7, oleic acid 5, bisphenol A2-3, phenol 20, 37% formaldehyde 40, sodium hydroxide 1, rosin 3, silane coupling agent kh5502.
[0040] The preparation method of described bisphenol A modified phenolic resin, comprises the following steps:
[0041] (1) Mix oleic acid and rosin, add to toluene that is 3 times the weight of the mixture, stir evenly, raise the temperature to 70°C, add triethanolamine, keep stirring for 1 hour, add bisphenol A, stir evenly, and send Into the reaction kettle, feed nitrogen, adjust the temperature of the reaction kettle to 90°C, heat and stir for 30 minutes, ...
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