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Preparation method of green restoration material for heavy metal polluted soil

A technology of contaminated soil and repair materials, applied in the field of heavy metal contaminated soil repair, to achieve the effect of improving the repair effect, wide application, and increasing the usable value

Inactive Publication Date: 2019-01-01
GUANGXI BOSSCO ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a preparation method of a green repair material for heavy metal-contaminated soil, which not only solves the problem of disposal of agricultural waste, improves the usable value of agricultural waste, but also solves the problem of heavy metal-contaminated soil Repair problems without secondary pollution, achieving environmental protection effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A preparation method of a green restoration material for heavy metal polluted soil, the operation process is as follows:

[0025] Wash balsam pear vine, a plant fibrous waste that has been decomposed for 72 hours and air-dried, with tap water for 5 times, and then with deionized water for 2 times. Bitter gourd vines are pyrolyzed in a muffle furnace. The pyrolysis process includes a heating section, a holding section and a cooling section. The heating section heats up to 450°C at 10°C / min; During the whole pyrolysis process, nitrogen gas is kept flowing as the carrier gas, and the flow rate of the carrier gas is 150ml / min; then the product that has been pyrolyzed and naturally cooled is soaked in 0.4mol / L hydrochloric acid for 12h, wherein the mass ratio of the product to the hydrochloric acid solution 1:500; rinse the product soaked in hydrochloric acid 4 times with deionized water, put it into boiled deionized water until neutral pH = 7, and dry it at 105°C for 12 hou...

Embodiment 2

[0027] A method for preparing a green repair material for heavy metal polluted soil, the operation steps are as follows:

[0028] The plant fibrous waste pumpkin vines that were decomposed for 72 hours and air-dried were washed 6 times with tap water, then washed 3 times with deionized water, dried naturally at 105°C for 24 hours, shortened to 1 cm, and set aside. Put the shortened pumpkin vines in a muffle furnace for pyrolysis. The pyrolysis process includes a heating section, a holding section and a cooling section. The heating section heats up to 500°C at 15°C / min; the holding section is kept at 500°C for 60 minutes; Natural cooling is used in the cooling section, and argon gas is maintained as a carrier gas during the entire pyrolysis process, and the flow rate of the carrier gas is 130ml / min. Take the product that has been pyrolyzed and cooled naturally and soak it in 0.5mol / L hydrochloric acid for 12h, wherein the mass ratio of the product to the hydrochloric acid solut...

Embodiment 3

[0030] The plant fibrous waste loofah vines that were decomposed for 72 hours and air-dried were washed 6 times with tap water, and then washed 3 times with deionized water. After natural air-drying, they were dried at 105°C for 24 hours, shortened to 1 cm, and set aside. Put the shortened pumpkin vines in a muffle furnace for pyrolysis. The pyrolysis process includes a heating section, a holding section and a cooling section. The heating section heats up to 550°C at 15°C / min; the holding section is kept at 550°C for 60 minutes; In the cooling section, natural cooling is used, and nitrogen gas is kept fed as the carrier gas during the whole pyrolysis process, and the flow rate of the carrier gas is 150ml / min. Take the product that has been pyrolyzed and cooled naturally and soak it in 0.6mol / L hydrochloric acid for 12h, wherein the mass ratio of the product to the hydrochloric acid solution is 1:500. Rinse the product soaked in hydrochloric acid four times with deionized water...

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Abstract

The invention discloses a preparation method of a green restoration material for heavy metal polluted soil. The preparation method comprises the following steps: (1) decomposing plant fiber waste, airdrying the plant fiber waste, then washing the air dried plant fiber waste separately by using water and deionized water, then naturally drying, baking at 105 DEG C, and cutting into segments of 1 to2 cm; (2) pyrolyzing the cut plant fiber waste under an air insulation condition; (3) soaking a pyrolyzed product in an acidic solution for 12 hours, then filtering, and collecting filter residues; and (4) washing the filter residues by using deionized water, boiling in the boiled deionized water to be neutral, baking at a constant temperature of 70 to 105 DEG C for 12 to 24 hours, and obtainingthe green restoration material. The preparation method provided by the invention is wide in raw material source, low in cost and simple in preparation process; and the prepared green restoration material has good adsorption characteristics for heavy metals, also has good restoration effect for the heavy metals in the soil at the same time, can be stored in the soil in a form of carbon sink for a long time, can prevent the secondary pollution for the environment, and can recycle the agriculture waste.

Description

technical field [0001] The invention belongs to the technical field of remediation of heavy metal-contaminated soil, in particular to a preparation method of a green remediation material for heavy metal-contaminated soil. Background technique [0002] In recent years, with the development of industry, human factors have caused a large amount of heavy metals to enter the environment. Soil is the most fundamental and important component of the ecosystem, and heavy metal pollution has become a very common environmental phenomenon. Soil heavy metal pollution refers to the phenomenon that heavy metals enter the soil due to human activities, making the content of heavy metals in the soil exceed the background value of the soil, and causing existing or potential soil quality degradation, ecological and environmental degradation. [0003] The anthropogenic sources of soil heavy metals can be divided into industrial sources and agricultural sources, but with the development of urban...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/04C02F1/28C02F101/20
CPCC02F1/283C02F2101/20C09K17/04
Inventor 杨崎峰周永信宋海农高原廖长君蒋林伶高坤涂春艳廖谨宣张德明赖文学何锡超
Owner GUANGXI BOSSCO ENVIRONMENTAL PROTECTION TECH