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A kind of implication logic gate

A technology of logic gate and logic input, which is applied in the field of nanometers, can solve problems such as difficulty in the application of logic gates, and achieve the effects of strong anti-interference ability, stable and correct output, and high stability

Active Publication Date: 2020-10-16
BEIJING NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the application of logic gates based on the change of the dispersion / aggregation state of gold nanoparticles is difficult, because the dispersion / aggregation state is easily affected by the environment, not only temperature and pH, but even changes in the ionic strength of the dispersion or the introduction of macromolecular materials. Reverse its dispersion / aggregation state (Sensors and Actuators B 155, 2011, 817–822 and Sensors and Actuators B 231, 2016, 64–69)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] In this example, the synthesis and characterization of gold nanorods are carried out.

[0042] 1.1 Synthesis of gold species: Add 5mL 0.1mol / L CTAB and 25μL 50mmol / L chloroauric acid into a 25mL flask, stir the mixture for 5min, add 300μL 10mmol / L freshly prepared sodium borohydride solution to the mixture, and stir for 25s , the color of the solution turns from brown to brown, indicating the formation of gold species, and the prepared gold species solution is stored in an environment of 27-30° C. for later use.

[0043] 1.2 Preparation of growth solution: Add 200 μL of 1mol / L hydrochloric acid and 100 μL of 50 mmol / L chloroauric acid into 10 mL of 0.1 mol / L CTAB solution, stir for 5 minutes, and then mix 120 μL of 10 mmol / L silver nitrate solution and 100 μL of 100 mmol / L The ascorbic acid solution is sequentially added to the above mixture, and the growth liquid is obtained after mixing evenly.

[0044] 1.3 Preparation of gold nanorods: inject 24 μL of the gold seed ...

Embodiment 2

[0048] This embodiment provides the input / output characteristics of the IMPLICATION logic gate constructed by the present invention.

[0049] The gold nanorods synthesized in Example 1 were used.

[0050] The etching solution contains 200mmol / L hydrogen peroxide, 0.4mmol / L sodium iodide, and 0.4mmol / L hydrochloric acid.

[0051] The first logic input is 15μL 0.8μmol / L Hg 2+ , the second logic input is 15μL 0.8mmol / L Cu 2+ .

[0052] When there is an input signal, it is defined as 1; when it does not contain an input signal, it is defined as 0. The four input signal forms are: neither adding 15μL 0.8μmol / L Hg 2+ Without adding 15μL 0.8mmol / L Cu 2+ , defined as (0,0); without adding 15 μL 0.8 μmol / L Hg 2+ But add 15μL 0.8mmol / L Cu 2+ , defined as (0,1); add 15μL 0.8μmol / LHg 2+ But do not add 15μL 0.8mmol / L Cu 2+ , defined as (1,0); adding 15μL 0.8μmol / L Hg 2+ Then add 15μL 0.8mmol / L Cu 2+ , defined as (1,1).

[0053] 2.1 The output characteristics of the IMPLICATION ...

Embodiment 3

[0062] Three batches of gold nanorod working solutions were synthesized using the method of Example 1, and logic gates were constructed using the method parameters and steps of Example 2, and three parallel experiments were performed on each batch of gold nanorod working solutions. The final solution L-LSPR wavelength blue shift value Δλ calculated by spectral measurement is as follows Figure 5As shown, when the input is (1,0), the color of the final solution does not change visually, it is red, and the results of nine spectral measurements show that the wavelength blue shift value Δλ of the final solution is 1.6nm, and the standard deviation is 0.6nm; when the input When it is (0,0), (0,1) and (1,1), the gold nanoparticles are not protected, and etching has occurred, and the final color of the solution is blue visually, and the average values ​​of Δλ measured in nine times are respectively At 201.5nm, 204.1nm and 194.6nm, the standard deviations of the blue shift values ​​ar...

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Abstract

The invention provides an IMPLICATION logic gate. The initial solution comprises a gold nanorod work solution, an etching solution and 2 logic inputs; in the gold nanorod work solution, the length-to-diameter ratios of gold nanorods are 3.0-5.5, and the concentration of gold atoms is 0.5mmol / L; the etching solution contains hydrogen peroxide at a concentration of 200mmol / L, sodium iodide at a concentration of 0.4mmol / L and hydrochloric acid at a concentration of 0.4mmol / L; in the two logic inputs, the first logic input is Hg<2+>, and the second logic input is Cu<2+>. The introduced Hg<2+> is used for reduction reaction on the surfaces of the gold nanorods and then generates gold / mercury alloy to prevent the etching solution from etching the gold nanorods, while the introduced Cu<2+> increases the etching capacity of the etching solution, and the protective effect of the gold / mercury alloy on the gold nanorods is eliminated. The logic gate, which is constructed on the basis of a non-aggregated mechanism, has high stability and anti-interference capacity, and the invention further provides a method for constructing the IMPLICATION logic gate through adopting the gold nanorod work solution, the etching solution and the 2 logic inputs.

Description

technical field [0001] The invention relates to the field of nanotechnology, in particular to an IMPLICATION logic gate based on gold nanorods and a construction method thereof. Background technique [0002] Due to the strong surface plasmon resonance absorption of gold nanomaterials, its molar extinction coefficient is 3 to 4 orders of magnitude larger than that of ordinary organic dyes, and the wavelength of this absorption depends on the size, shape and environment of gold nanomaterials. nature. Gold nanospherical particles are easy to synthesize, and their dispersed and aggregated states are red and blue, respectively, so they are widely used in the construction of logic gates. For example, Dengue et al. (Analyst, 2013, 138, 6677–6682) reported an IMPLICATION logic gate based on gold nanoparticles, with thiocyanate and iodide ions as inputs. When there is no input (0,0), the acidic environment The ionization of citrate on the surface of the gold nanoparticles is inhibi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/25G01N21/552
CPCG01N21/25G01N21/554
Inventor 秦卫东李彤
Owner BEIJING NORMAL UNIVERSITY