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Preparation method of dopamine-coated carbon nanotube-modified carbon fiber-enhanced resin base structure-damping composite material

A fiber-reinforced resin and damping composite material technology is applied in the field of composite materials to achieve the effects of good application prospects, high reliability and simple preparation equipment

Inactive Publication Date: 2019-01-11
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In order to solve the problem of carbon nanotubes agglomerating in the resin matrix, the purpose of the present invention is to provide a kind of Fe(NO 3 ) 3 Solution-treated carbon fibers, after hydrogen reduction, use a gaseous carbon source to synthesize carbon nanotubes on the surface of carbon fibers in situ, and undergo surface treatment with polydopamine, using this method to significantly improve the damping performance of carbon fiber composites

Method used

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  • Preparation method of dopamine-coated carbon nanotube-modified carbon fiber-enhanced resin base structure-damping composite material
  • Preparation method of dopamine-coated carbon nanotube-modified carbon fiber-enhanced resin base structure-damping composite material
  • Preparation method of dopamine-coated carbon nanotube-modified carbon fiber-enhanced resin base structure-damping composite material

Examples

Experimental program
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example 1

[0027] Soak the carbon fiber in an acetone solution, let it stand for 8 hours, take out the carbon fiber and place it in deionized water for 30 minutes, and then clean it with deionized water and dry it in an environment of 90°C for 8 hours; 0.404g of Fe(NO 3 ) 3 Dissolve in 100ml of absolute ethanol and stir for 30 minutes; apply the prepared solution on the surface of the dried carbon fiber, and then place the carbon fiber at 90°C for 30 minutes; place the dried carbon fiber in a tube furnace , then pass Ar into the tube furnace at 240 sccm, raise the temperature of the furnace at 10°C / min to 250°C and stop feeding Ar, put H 2 Pass it into the tube furnace at 150 sccm and keep it warm for 1 hour, raise the temperature of the furnace to 450°C at 10°C / min and keep it warm for 1 hour in an atmosphere, stop passing H 2 , Ar is passed into the tube furnace at 240 sccm, the furnace temperature is raised to 600 °C at 10 °C / min, and then C 2 h 2 , and keep warm for 1 hour. The c...

example 2

[0029] Soak the carbon fiber in an acetone solution, let it stand for 8 hours, take out the carbon fiber and place it in deionized water for 30 minutes, and then clean it with deionized water and dry it in an environment of 90°C for 8 hours; 0.404g of Fe(NO 3 ) 3 Dissolve in 100ml of absolute ethanol and stir for 30 minutes; apply the prepared solution on the surface of the dried carbon fiber, and then place the carbon fiber at 90°C for 30 minutes; place the dried carbon fiber in a tube furnace , then pass Ar into the tube furnace at 240 sccm, raise the temperature of the furnace at 10°C / min to 250°C and stop feeding Ar, put H 2 Pass it into the tube furnace at 150 sccm and keep it warm for 1 hour, raise the temperature of the furnace to 450°C at 10°C / min and keep it warm for 1 hour in an atmosphere, stop passing H 2 , Ar is passed into the tube furnace at 240 sccm, the furnace temperature is raised to 600 °C at 10 °C / min, and then C 2 h 2 , and keep warm for 1 hour. Carbo...

example 3

[0031] Soak the carbon fiber in an acetone solution, let it stand for 8 hours, take out the carbon fiber and place it in deionized water for 30 minutes, and then clean it with deionized water and dry it in an environment of 90°C for 8 hours; 0.404g of Fe(NO 3 ) 3 Dissolve in 100ml of absolute ethanol and stir for 30 minutes; apply the prepared solution on the surface of the dried carbon fiber, and then place the carbon fiber at 90°C for 30 minutes; place the dried carbon fiber in a tube furnace , then pass Ar into the tube furnace at 240 sccm, raise the temperature of the furnace at 10°C / min to 250°C and stop feeding Ar, put H 2 Pass it into the tube furnace at 150 sccm and keep it warm for 1 hour, raise the temperature of the furnace to 450°C at 10°C / min and keep it warm for 1 hour in an atmosphere, stop passing H 2 , Ar is passed into the tube furnace at 240 sccm, the furnace temperature is raised to 600 °C at 10 °C / min, and then C 2 h 2 , and keep warm for 1 hour. The c...

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Abstract

The invention relates to a preparation method of a dopamine-coated carbon nanotube-modified carbon fiber-enhanced resin base structure-damping composite material. The preparation method comprises thefollowing steps: (1) removing glue from surfaces of carbon fibers; (2) preparing a catalyst precursor solution; (3) soaking the carbon fibers into the catalyst precursor solution for 0.5-1 hours, taking out the carbon fibers, and drying at 90-120 DEG C for 0.5-1 hour; (4) putting the dried carbon fibers into a tubular furnace, heating to 250-450 DEG C in the presence of argon, carrying out thermalinsulation reduction in the presence of hydrogen, heating to 560-800 DEG C in the presence of argon, introducing acetylene (20sccm-40sccm), and maintaining the temperature; and (5) dipping the carbonfibers processed by virtue of a chemical vapor deposition carbon nano-tube into a Tris buffer solution of dopamine hydrochloride, and finishing polymerization within 24 hours, wherein the concentration of the Tris buffer solution is 1mg / ml-2mg / ml.

Description

technical field [0001] The invention belongs to the field of composite materials, and in particular relates to a method for coating carbon nanotube modified carbon fiber with dopamine and the research on the damping performance of the reinforced epoxy resin-based composite material. Background technique [0002] Carbon fiber reinforced epoxy resin-based composites have high specific strength and specific modulus, and are widely used in aerospace, high-speed railways, Military industry, construction and sports equipment and other fields. In addition, due to the light weight of carbon fiber composite materials, it shows a better application prospect in the context of reducing energy consumption, energy saving and emission reduction. However, with the development of modern mechanical systems such as aircraft and high-speed railways towards high speed and automation, carbon fiber composites are more likely to cause vibration in mechanical systems. High-frequency vibration redu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L79/04C08K9/12C08K9/10C08K9/04C08K7/06C08K3/04C08G73/06
CPCC08G73/0672C08L63/00C08L79/04C08K9/12C08K9/10C08K9/04C08K7/06C08K3/041
Inventor 何芳闫德道赵乃勤师春生何春年李家俊刘恩佐马丽颖沙军威
Owner TIANJIN UNIV