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Spilled oil adsorption product based on spent catalytic cracking catalyst

A waste catalyst, catalytic cracking technology, applied in the directions of alkali metal oxides/hydroxides, inorganic chemistry, alkali metal compounds, etc. problems, to achieve the effect of easy long-term storage, low price, convenient use and cleaning

Inactive Publication Date: 2019-02-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In view of the high cost of oil products and chemical leakage treatment, the large amount of spent catalytic cracking catalysts in hand, and the complicated process and high cost of using modified catalytic cracking spent catalysts, the present invention provides a spillover method based on catalytic cracking spent catalysts. Oil adsorption products, through physical methods, encapsulate the spent catalytic cracking catalyst powder in oil-absorbing and waterproof packaging materials to prepare various styles of oil spill adsorption products. Oil and some chemicals can be adsorbed to catalytic cracking catalysts through packaging materials powder on

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The spent catalytic cracking catalyst is ball milled to obtain a fine powder of spent catalytic cracking catalyst with a specific surface area of ​​220m 2 / kg, airtightly packaged in reinforced polypropylene non-woven fabric, in the shape of strips, the mass of a single package is 80Kg, used for the containment and adsorption of diesel oil spilled on the ground.

Embodiment 2

[0024] The catalytic cracking spent catalyst was not ball-milled (specific surface area is 120m 2 / kg), airtightly packaged in reinforced spandex non-woven fabric, the shape is bagged, and the quality of a single package is 50Kg, which is used for the containment and adsorption of p-xylene (PX) leaked from the ground.

Embodiment 3

[0026] The catalytic cracking waste catalyst is ball milled, and the specific surface area is 280m 2 / kg, after mixing a part of polystyrene foam, airtightly pack it in reinforced acrylic non-woven fabric, the shape is a rectangular sheet, the total mass of a single package is 10Kg, and the spent catalytic cracking catalyst accounts for 95% of the total weight. This product is used for the adsorption of crude oil leaked on the water surface.

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Abstract

The invention provides a spilled oil adsorption product based on a spent catalytic cracking catalyst. The spilled oil adsorption product is prepared from spent catalytic cracking catalyst powder, an oil-absorbing waterproof packaging material and further a light-weight foam material, wherein the spent catalytic cracking catalyst powder is hermetically packaged in the oil-absorbing waterproof packaging material and is prepared by ball milling, the specific surface area of the spent catalytic cracking catalyst powder is 100-300 m<2> / g, the light-weight foam material can be better used for absorbing spilled oil on the water surface, and the oil-absorbing waterproof packaging material can select and use reinforced polypropylene, polyester, nylon, spandex or acrylic non-woven fabrics and can bemade into a bag shape, a pie shape, a strip shape or a sheet shape. The spilled oil adsorption product prepared through a physical method has the advantages that the spent catalytic cracking catalystdoes not need to be subjected to chemical or thermal treatment, energy conservation and environmental protection are realized, the cost is low, use and cleaning are convenient, the adsorption capability is high, and high-value resource utilization of the spent catalytic cracking catalyst is realized.

Description

technical field [0001] The invention relates to the field of oil spill adsorption, in particular to an oil spill adsorption product based on catalytic cracking waste catalyst. Background technique [0002] In my country, the amount of catalytic cracking catalysts accounts for about 85% of the total amount of refining catalysts. After the catalytic cracking catalysts are repeatedly regenerated and used in this device, some catalysts are destroyed by the hydrothermal environment due to the molecular sieve structure or due to the excessive adsorption of heavy metals and carbon deposits. , will be irreversibly deactivated and discharged. This part of the discarded catalytic cracking spent catalyst is included in the "National Hazardous Waste List" and belongs to hazardous waste. In my country, the annual production of catalytic cracking spent catalysts is about 100,000 tons. In order to prevent environmental pollution, it must be disposed of in a harmless manner or utilized as a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/28E02B15/10
CPCB01J20/28042B01J2220/4893E02B15/10Y02A20/204
Inventor 房师平张宏哲张志远牟桂芹
Owner CHINA PETROLEUM & CHEM CORP
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