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A workshop system for producing cryolite from mold liquid

A cryolite and generation system technology, applied in aluminum halide, aluminum fluoride and other directions, can solve the problems of low recycling rate, waste of resources, high disposal costs, and achieve the effect of saving drug costs and reducing labor intensity

Active Publication Date: 2020-01-14
FOSHAN SANSHUI XIONGYING INNOVATION CENT FOR ALUMINUM SURFACE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] 2.1. Extrusion mold waste liquid waste water waste residue
[0018] 2. Current status of aluminum industry waste slag treatment and utilization
At present, there are three main routes for resource utilization of aluminum ash: (1) recycle alumina and return it to electrolysis, and recycle chloride salt as a melting and casting refining agent. However, the main component in aluminum ash is α-Al2O3, which has poor activity, and its ionization requires Consumes more energy, causing cell voltage to rise
(2) Acid or alkali treatment to remove impurities, production of inorganic materials such as synthetic brown corundum, Sialon ceramics and refractory materials, production of water purification materials such as polyaluminum chloride and aluminum sulfate, and production of slagging desulfurizers for steelmaking, but due to The cost is higher than the existing ones, and industrial production cannot be realized
(3) Production of building materials or road construction materials, such as aluminate cement, calcium aluminate powder, clear water bricks, and road construction materials, etc., but the fluoride and chloride salts contained in them have an impact on performance, and the added value of the product is low, limiting practical application
This method is simple, but has the following disadvantages: first, it loses sulfuric acid, wastes aluminum ions, and the consumption of sulfuric acid reaches more than 60kg / t;
[0039] The recovery of hexavalent chromium ions is still a difficult problem, and it is impossible to realize online recovery of chromium-containing agents
[0043] The traditional waste water and residue treatment methods have the following disadvantages: first, the waste water can be discharged after treatment, but the reuse rate of reclaimed water is low; second, the cost of waste water treatment is high, which increases the consumption of labor, chemicals, and power; third, a large amount of acid, alkali, and metal aluminum , chemicals and other useful resources are wasted; Fourth, the waste residue is hazardous waste, the disposal cost is high, and environmental protection tax must be paid
[0051] 3. There are problems in the treatment of waste water and residue in extrusion surface treatment
[0052] First, high water consumption, lack of mature water-saving technology, and low water reuse rate; second, online classification of wastewater has not become a pre-procedure, resulting in a large amount of waste residue; third, the comprehensive utilization of waste residue has little effect, and waste residue treatment Become a corporate burden and environmental risk
[0053] At present, there are three prominent contradictions and problems in the treatment of waste residues: First, the state implements the management of enterprise pollutant discharge permits to control the total amount of pollutants discharged by enterprises, but the actual amount of waste water and residues of enterprises is far greater than the allowable discharge amount; second, waste residues must be It is legally transferred to a qualified third party for disposal, but the disposal capacity is obviously insufficient to legally dispose of such a huge amount of waste residue; the third is to dispose of waste residue according to hazardous waste regulations, which has complicated procedures, low efficiency and high cost
[0054] To sum up, the current domestic aluminum processing industry waste water and slag treatment contradiction is prominent, comprehensive treatment is difficult, high cost, and low recycling rate, which not only causes a lot of waste of resources, but also seriously pollutes the environment

Method used

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  • A workshop system for producing cryolite from mold liquid
  • A workshop system for producing cryolite from mold liquid
  • A workshop system for producing cryolite from mold liquid

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Embodiment Construction

[0088] The technical solutions of the present invention will be further described below in conjunction with the accompanying drawings and through specific implementation methods.

[0089] The theoretical basis for the recovery of aluminum ions from pot mold waste liquid to produce cryolite:

[0090] When the mold is potted, the aluminum material in the abrasive tool undergoes the following chemical reaction in the alkaline etching solution:

[0091] al 2 o 3 +2NaOH=2NaAlO 2 +H 2 O (Natural Oxide Removal) (1)

[0092] 2Al+2NaOH+2H 2 O=2NaAlO 2 +3H 2 ↑(melted aluminum) (2)

[0093] NaAlO 2 +2H 2 O=Al(OH) 3 ↓+NaOH (bath solution decomposition, regenerated lye) (3)

[0094] 2Al(OH) 3 =Al2O 3 ·3H 2 O (scaling on the tank wall, clogged pipes) (4)

[0095] According to the two formulas (1) and (2), the higher the alkali concentration, the faster the aluminum dissolution rate; according to the two formulas (3) and (4), the potting liquid is unstable, easy to decompose,...

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Abstract

The invention relates to a workshop system for producing cryolite by pot mold liquid. The system comprises a pot mold liquid generating system, a pot mold liquid collecting system, a pot mold liquid treating system and a pot mold liquid separating system, wherein the pot mold liquid generating system comprises a plurality of pot mold groove, a waste water flow guide ditch, a pool and a fourth pump; the pot mold liquid generating system is used for treating a mold and guiding the pot mold liquid to the pot mold liquid collecting system; the pot mold liquid collecting system comprises a pot moldliquid recovering tank and a first pump; the pot mold liquid collecting system is used for collecting the pot mold liquid; the pot mold liquid treating system comprises a reaction tank, a second pumpand a hydrofluoric acid storage tank; the pot mold liquid separating system comprises a recovering tank and a centrifugal machine; the pot mold liquid separating system is used for performing solid and liquid separation on the produced cryolite; the pot mold liquid is collected timely from a pot mold factory, so that the pot mold liquid is prevented from being polluted, other impurities are avoided, all the pot mold liquid and waste water can be recovered from the pot mold tank, and energy conservation and emission reduction are realized.

Description

technical field [0001] The invention relates to the technical field of aluminum processing, in particular to a workshop system for producing cryolite from mold liquid. Background technique [0002] Aluminum and aluminum alloys have the advantages of excellent processing performance, good corrosion resistance, beautiful surface, high recovery rate, etc., and have been widely used in construction, transportation, machinery, electric power and other industries. In recent years, the trend of expanding the application of aluminum by replacing steel with aluminum has become more obvious . The aluminum processing industry is a traditional industry, and it is a sunrise industry full of vitality. According to statistics, the per capita annual consumption of aluminum in developed countries in Europe and the United States is more than 32kg, while the per capita consumption in my country is only about 13kg, which is only about one-third of that in developed countries. There is still hu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F7/54
CPCC01F7/54
Inventor 熊映明
Owner FOSHAN SANSHUI XIONGYING INNOVATION CENT FOR ALUMINUM SURFACE TECH
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