A workshop system for producing cryolite from mold liquid
A cryolite and generation system technology, applied in aluminum halide, aluminum fluoride and other directions, can solve the problems of low recycling rate, waste of resources, high disposal costs, and achieve the effect of saving drug costs and reducing labor intensity
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[0088] The technical solutions of the present invention will be further described below in conjunction with the accompanying drawings and through specific implementation methods.
[0089] The theoretical basis for the recovery of aluminum ions from pot mold waste liquid to produce cryolite:
[0090] When the mold is potted, the aluminum material in the abrasive tool undergoes the following chemical reaction in the alkaline etching solution:
[0091] al 2 o 3 +2NaOH=2NaAlO 2 +H 2 O (Natural Oxide Removal) (1)
[0092] 2Al+2NaOH+2H 2 O=2NaAlO 2 +3H 2 ↑(melted aluminum) (2)
[0093] NaAlO 2 +2H 2 O=Al(OH) 3 ↓+NaOH (bath solution decomposition, regenerated lye) (3)
[0094] 2Al(OH) 3 =Al2O 3 ·3H 2 O (scaling on the tank wall, clogged pipes) (4)
[0095] According to the two formulas (1) and (2), the higher the alkali concentration, the faster the aluminum dissolution rate; according to the two formulas (3) and (4), the potting liquid is unstable, easy to decompose,...
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