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A weather-resistant coating liquid, weather-resistant automotive glass and manufacturing method thereof

An automotive glass and manufacturing method technology, applied in the direction of coating, can solve the problems of good weather resistance, high visible light transmittance, good wear resistance, etc., and achieve improved alkali resistance, excellent wear resistance, and low VOC emissions. Effect

Active Publication Date: 2020-05-19
FUYAO GLASS IND GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a weather-resistant coating liquid, weather-resistant automotive glass and its manufacturing method

Method used

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  • A weather-resistant coating liquid, weather-resistant automotive glass and manufacturing method thereof
  • A weather-resistant coating liquid, weather-resistant automotive glass and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] Weigh 20g of absolute ethanol, 30g of isopropanol, 13.56g of ethyl orthosilicate, 5.18g of γ-methacryloxypropyl trimethoxysilane, 12.5g of deionized water, 0.1g of 10% by mass fraction Nitric acid was added to the beaker, and stirred in a water bath at 40°C for 60 minutes to obtain silica sol A1;

[0062] Weigh 10g of silica sol A1, 0.1g of fluorocarbon resin, 0.1g of DISPERBYK-171 and 0.1g of BYK-345, mix and stir for 120min to obtain weathering solution B1;

[0063] In a dust-free environment, take an appropriate amount of weather-resistant solution B1, and apply it on the surface of the cleaned curved glass substrate with a wire bar applicator, and let it stand for 20 minutes until the weather-resistant coating on the surface of the curved glass substrate is leveled , pre-dry the weather-resistant coating with an infrared lamp, then place the curved glass substrate with the weather-resistant coating at 120°C for 60 minutes, and take it out after the curved glass subs...

Embodiment 2

[0065] Weigh 50g of absolute ethanol, 10.45g of ethyl orthosilicate, 4.58g of γ-methacryloxypropyl trimethoxysilane, 10.5g of deionized water, and 0.08g of nitric acid with a mass fraction of 10% into the beaker, Stir in a water bath at 40°C for 60 minutes to obtain silica sol A2;

[0066] Weigh 10g of silica sol A2, 0.1g of fluorocarbon resin, 0.1g of DISPERBYK-171 and 0.1g of BYK-345, mix and stir for 120min to obtain weathering solution B2;

[0067] In a dust-free environment, take an appropriate amount of solution B2, and apply it on the surface of the cleaned curved glass substrate with a wire bar applicator, and let it stand for 20 minutes until the weather-resistant coating on the surface of the curved glass substrate is leveled , pre-dry the weather-resistant coating with an infrared lamp, then place the curved glass substrate with the weather-resistant coating at 120°C for 60 minutes, and take it out after the curved glass substrate naturally cools down to room temper...

Embodiment 3

[0069] Weigh 20g of absolute ethanol, 30g of isopropanol, 13.56g of ethyl orthosilicate, 5.18g of γ-methacryloxypropyltrimethoxysilane, 12.5g of deionized water, and 0.3g of acetic acid into a beaker, Stir in a water bath at 40°C for 60 minutes to obtain silica sol A3;

[0070] Weigh 10g of silica sol A3, 0.1g of fluorocarbon resin, 0.1g of DISPERBYK-171 and 0.1g of BYK-345, mix and stir for 120min to obtain weathering solution B3;

[0071] In a dust-free environment, take an appropriate amount of solution B3 and apply it on the surface of the cleaned curved glass substrate with a wire bar applicator, and let it stand for 20 minutes until the weather-resistant coating on the surface of the curved glass substrate is leveled , pre-dry the weather-resistant coating with an infrared lamp, then place the curved glass substrate with the weather-resistant coating at 120°C for 60 minutes to cure, and take it out after the curved glass substrate naturally cools down to room temperature...

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Abstract

The invention relates to the technical field of surface covering, and particularly provides weather-resistant coating liquid, automotive glass provided with a weather-resistant coating formed by the weather-resistant coating liquid, and a production method of the automotive glass. The weather-resistant coating liquid is prepared from silica sol, fluorocarbon resin, a dispersion agent and a flatting agent; the silica sol is prepared by mixing and stirring at least silicate, a solvent, a silane coupling agent, a catalyst and deionized water. By means of the weather-resistant coating liquid, theperformance, including alkali resistance, acid resistance, ageing resistance and the like, of the weather-resistant coating formed by the weather-resistant coating liquid can be effectively improved,so that a normal service life of the weather-resistant coating is prolonged; the weather-resistant coating further has excellent wear resistance; an infrared absorber and / or an ultraviolet absorber can be further added into the weather-resistant coating liquid directly; VOC discharge of the weather-resistant coating liquid is extremely low, the weather-resistant coating liquid has the advantages of being environmentally friendly, good in construction performance and the like, and the weather-resistant coating can be up to specifications of laws and regulations of glass used for automobiles.

Description

Technical field: [0001] The invention relates to the technical field of surface coating, and specifically provides a weather-resistant coating liquid, an automobile glass with a weather-resistant coating formed by the weather-resistant coating liquid, and a manufacturing method of the automobile glass. Background technique: [0002] Functional coatings can be formed on the surface of the substrate by surface coating technology, such as wear-resistant coatings, insulating coatings, UV-blocking coatings, infrared-blocking coatings, and decorative coatings. Weather resistance is one of the performance evaluation indicators of coatings, and xenon lamp aging test is usually used to evaluate weather resistance; if the weather resistance of the coating is poor, its service life will be seriously affected. [0003] In order to improve the weather resistance of the coating, the patent CN105400314A discloses a corrosion-resistant fluorocarbon resin coating, the raw materials of which ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D127/18C09D127/12C09D7/61
CPCC08K3/36C09D7/61C09D127/12C09D127/18
Inventor 郭善济邬亚斌阴倩倩柯城陈绍木
Owner FUYAO GLASS IND GROUP CO LTD