Device and method for recycling low concentration ammonia nitrogen wastewater

A low-concentration ammonia nitrogen and wastewater recycling technology, applied in chemical instruments and methods, water pollutants, water/sewage treatment, etc., can solve the problems of unbalanced amount of leaching wastewater, unsealed filter press, and high labor intensity. Achieve the effect of improving the level of automatic operation, improving the efficiency of equipment use, and reducing the consumption of new water

Pending Publication Date: 2019-02-19
CHINA NORTHERN RARE EARTH (GROUP) HIGH TECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The wastewater treated in this way still contains a certain concentration of rare earth ions. In order to avoid the pollution of different rare earth ions to high-purity rare earth products, it can only be reused in the corresponding production lines.
The amount of leaching wastewater produced by different types of rare earth carbonates is unbalanced. When reused in the respective precipitant preparation processes, there will be some surpluses and some shortages
Because the precipitant cannot be uniformly prepared, all the wastewater cannot be reused in the production line, resulting in a waste of part of the water, and the equipment used is large, occupying a large area, and the utilization rate is low; the filter press used for filtering wastewater cannot be sealed and needs to be manually disassembled regularly Filter plate, poor operating environment, high labor intensity

Method used

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  • Device and method for recycling low concentration ammonia nitrogen wastewater

Examples

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Comparison scheme
Effect test

Embodiment 1

[0049] Take 500L of rare earth precipitation wastewater containing La / Ce rare earth ion impurities (the total concentration of rare earth ions is 0.02g / L) and ammonia nitrogen concentration of 3g / L, add it to the surface filter, collect after filtration to obtain 495L of wastewater from which rare earth particles have been filtered . The above-mentioned waste water is added to the operation of the nanofiltration system, and the rare earth ions are filtered out to finally obtain 405L of waste water containing no rare earth ions and an ammonia nitrogen concentration of 3g / L. This waste water is directly used to prepare the precipitant (ammonium bicarbonate) used in the rare earth precipitation. solution).

Embodiment 2

[0051] Get containing La / Ce / Pr rare earth ion impurity (rare earth ion total concentration is 0.02g / L), ammonia nitrogen concentration is 500L of rare earth precipitation waste water 500L, joins in the surface filter, collects after filtering and obtains and has filtered the rare earth particle Wastewater 495L. The above-mentioned waste water is added to the operation of the nanofiltration system, and the rare earth ions are filtered out to finally obtain 405L of waste water containing no rare earth ions and an ammonia nitrogen concentration of 3g / L. This waste water is directly used to prepare the precipitant (ammonium bicarbonate) used in the rare earth precipitation. solution).

Embodiment 3

[0053] Take 500L of rare earth precipitation wastewater containing Ce / Pr rare earth ion impurities (the total concentration of rare earth ions is 0.02g / L) and ammonia nitrogen concentration of 3g / L, add it to the surface filter, collect after filtration to obtain 495L of wastewater that has filtered out rare earth particles . The above-mentioned waste water is added to the operation of the nanofiltration system, and the rare earth ions are filtered out to finally obtain 405L of waste water containing no rare earth ions and an ammonia nitrogen concentration of 3g / L. This waste water is directly used to prepare the precipitant (ammonium bicarbonate) used in the rare earth precipitation. solution).

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Abstract

The invention discloses a device for recycling low concentration ammonia nitrogen wastewater, which comprises a storage tank for the low concentration ammonia nitrogen wastewater before filtration, asurface filter, a storage tank for the low concentration ammonia nitrogen wastewater after filtration and an ultrafiltration and nanofiltration system, wherein the storage tank for low concentration ammonia nitrogen wastewater before filtration, the surface filter, the storage tank for lowconcentration ammonia nitrogen wastewater after filtration and the ultrafiltration and nanofiltration system are sequentially connected through pipelines. The invention also discloses a method for recycling the low concentration ammonia nitrogen wastewater. According to the device and the method for recyclinglow concentration ammonia nitrogen wastewater, the low concentration ammonia nitrogen wastewater treatment process is shortened, the product quality remains unaffected, and the mixing and recycling of the low concentration ammonia nitrogen wastewater generated by different kinds of rare earth carbonate products are achieved.

Description

technical field [0001] The invention relates to a wastewater treatment technology, in particular to a device and method for recycling low-concentration ammonia nitrogen wastewater. Background technique [0002] The rare earth elements contained in northern rare earth mines are mainly La, Ce, Pr, and Nd. Most of the single or mixed rare earths produced in the production process are transferred to the next process in the form of carbonate. In the production process of rare earth carbonate, the leaching wastewater produced by washing rare earth carbonate contains low concentration of ammonia nitrogen, a small amount of rare earth carbonate particles and trace amounts of rare earth ions. If it is discharged directly, it will cause ecological damage. [0003] At present, the main treatment methods for this low-concentration ammonia nitrogen wastewater are: [0004] 1. Concentrated crystallization method [0005] After the low-concentration ammonia nitrogen wastewater is filtere...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/02C02F101/16
CPCC02F9/00C02F1/442C02F1/444C02F2101/16C02F1/001
Inventor 高媛张永华孙祥聂磊孟凡娟贺琳曲堂超高天佐崔辰
Owner CHINA NORTHERN RARE EARTH (GROUP) HIGH TECH CO LTD
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