Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Manufacturing process of glassfiber reinforced plastic pultrusion unsaturated resin rapid curing formula

A rapid solidification and manufacturing process technology, applied in the field of FRP production, can solve the problems of low pultrusion speed, achieve the effect of increasing pultrusion speed, increasing pultrusion output, and improving product yield

Inactive Publication Date: 2019-03-01
DONGGUAN DONGSHI NEW MATERIAL DEV
View PDF2 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The general pultrusion speed of FRP pultrusion production line is 500mm / min~1000mm / min, but the conventional pultrusion speed is too low to meet the high speed and high quality of modern pultrusion technology, so it is necessary to use unsaturated resin fast curing formula, through adjustment The ratio of the resin and its curing system enables it to achieve rapid curing molding, improve the yield rate of the product and increase the pultrusion speed to achieve rapid mass production. For this reason, we propose a FRP pultrusion unsaturated resin rapid curing formula manufacturing process

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of FRP pultrusion unsaturated resin rapid curing formulation manufacturing process, comprising the following steps:

[0027] The proportioning that described unsaturated resin curing agent forms is:

[0028] Resin (191#) 100%, curing agent (dibenzoyl peroxide) 0.5%, catalyst (dodecyl mercaptan) 0.5%, initiator (N.N-dimethyl p-toluidine) 0.5%, filler ( Calcium carbonate, aluminum hydroxide) 25%, anti-cracking agent (liquid nitrile rubber, polyvinyl butyral) 0.5%, brightener (titanium dioxide) 0.5%, anti-ultraviolet agent (JADEWIN UV 320) 0.5%, anti-cracking agent Combustion agent (magnesium hydroxide, red phosphorus) 0.2%, color paste 0.1%, pigment 0.5%.

[0029] Including the following steps:

[0030] S1. Blank pressing: choose glass fibers and mats that meet the process requirements and distribute them evenly after treatment, and press the blank under the action of external force;

[0031] S2. Curing agent configuration: resin (191#) 100%, curing agent (diben...

Embodiment 2

[0039] The proportioning that described unsaturated resin curing agent forms is:

[0040] Resin (191#) 100%, curing agent (dibenzoyl peroxide) 1.5%, catalyst (dodecyl mercaptan) 1.5%, initiator (N.N-dimethyl p-toluidine) 1.5%, filler ( Calcium carbonate, aluminum hydroxide) 40%, anti-cracking agent (liquid nitrile rubber, polyvinyl butyral) 0.8%, brightener (titanium dioxide) 0.8%, anti-ultraviolet agent (JADEWIN UV 320) 0.8%, anti-cracking agent Combustion agent (magnesium hydroxide, red phosphorus) 0.6%, color paste 0.3%, pigment 1.5%

[0041] S1. Blank pressing: choose glass fibers and mats that meet the process requirements and distribute them evenly after treatment, and press the blank under the action of external force;

[0042] S2. Curing agent configuration: resin (191#) 100%, curing agent (dibenzoyl peroxide) 1.5%, catalyst (dodecyl mercaptan) 1.5%, initiator (N.N-dimethyl p-formaldehyde) Aniline) 1.5%, filler (calcium carbonate, aluminum hydroxide) 40%, anti-cracki...

Embodiment 3

[0050] The proportioning that described unsaturated resin curing agent forms is:

[0051] Resin (191#) 100%, curing agent (dibenzoyl peroxide) 1.1%, catalyst (dodecyl mercaptan) 1.1%, initiator (N.N-dimethyl p-toluidine) 0.9%, filler ( Calcium carbonate, aluminum hydroxide) 31%, anti-cracking agent (liquid nitrile rubber, polyvinyl butyral) 0.7%, brightener (titanium dioxide) 0.7%, anti-ultraviolet agent (JADEWIN UV 320) 0.6%, anti-cracking agent Combustion agent (magnesium hydroxide, red phosphorus) 0.4%, color paste 0.2%, pigment 0.8%

[0052] S1. Blank pressing: choose glass fibers and mats that meet the process requirements and distribute them evenly after treatment, and press the blank under the action of external force;

[0053] S2. Curing agent configuration: resin (191#) 100%, curing agent (dibenzoyl peroxide) 1.1%, catalyst (dodecyl mercaptan) 1.1%, initiator (N.N-dimethyl p-formaldehyde) Aniline) 0.9%, filler (calcium carbonate, aluminum hydroxide) 31%, anti-cracki...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a manufacturing process of a glassfiber reinforced plastic pultrusion unsaturated resin rapid curing formula. An unsaturated resin curing agent is prepared from the following components in percentage by weight: 100% of resin (191#), 0.5-1.5% of a curing agent (dibenzoyl peroxide), 0.5-1.5% of a catalyst (dodecylthiol), 0.5-1.5% of an initiator (N.N-dimethyl-p-toluidine), 25-40% of a filler (calcium carbonate and aluminum hydroxide), 0.5-0.8% of an anti-cracking agent (liquid nitrile rubber and polyvinyl butyral), 0.5-0.8% of a brightener (titanium dioxide), 0.5-0.8% ofan anti-ultraviolet agent (JADEWIN UV 320), 0.2-0.6% of a flame retardant (magnesium hydroxide and red phosphorus), 0.1-0.3% of color paste and 0.5-1.5% of pigment. Compared with other process technologies, the technology is low in cost, the process is mature, by adjusting the ratio of resin to a resin curing system, the resin is subjected to rapid curing molding, and the yield of products and thepultrusion speed are increased to achieve rapid mass production.

Description

technical field [0001] The invention relates to the technical field of glass fiber reinforced plastics production, and more specifically relates to a manufacturing process of a glass fiber reinforced plastics pultrusion unsaturated resin rapid curing formula. Background technique [0002] In the FRP pultrusion industry, reinforced materials such as continuous rovings and felts soaked in glue are solidified and formed by heated metal molds under the action of traction to continuously produce products. [0003] The general pultrusion speed of FRP pultrusion production line is 500mm / min~1000mm / min, but the conventional pultrusion speed is too low to meet the high speed and high quality of modern pultrusion technology, so it is necessary to use unsaturated resin fast curing formula, through adjustment The ratio of the resin and its curing system enables it to achieve rapid curing molding, improve the yield rate of the product and increase the pultrusion speed to achieve rapid ma...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/06C08L9/02C08L29/14C08K3/26C08K3/22C08K3/02C08K7/14C08J5/04
CPCC08J5/043C08J2367/06C08K2003/026C08K2003/2224C08K2003/2227C08K2003/265C08L67/06C08L9/02C08L29/14C08K3/26C08K3/22C08K3/02C08K7/14
Inventor 王丹巩恩勇白海波杨奎徐雪吴伟李红道
Owner DONGGUAN DONGSHI NEW MATERIAL DEV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products