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Alkali-activated gelling material with low alkali dissolution rate cured at room temperature and preparation method thereof

A technology of normal temperature curing and cementitious materials, which is applied in the direction of cement production, etc. It can solve the problems of slag falling, unsuccessful plastering, and the decrease of the bonding force between plastering mortar and material matrix, so as to achieve the improvement of compressive strength and flexural strength , compressive strength and flexural strength improvement, the effect of restricting the migration of alkali metal ions

Active Publication Date: 2021-08-31
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Although the alkali-activated gelling material prepared from metakaolin-rich raw materials has many performance advantages such as fast strength development and excellent chemical erosion resistance, it also has two defects: one is that it needs a short period of time during the batching process. Curing at room temperature, then curing at high temperature, and then curing at room temperature is a relatively cumbersome process; the second is that the surface of the cementitious material is frosted after construction, also called pan-alkaline, which is manifested by the formation of "hoarfrost" or "white spots" on the surface of the cementitious material , not only affect the appearance, but also cause the adhesive force between the plastering mortar and the material matrix to decrease due to the loose "hoarfrost" in the subsequent construction, which will cause unsuccessful plastering or peeling, slag, etc.

Method used

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  • Alkali-activated gelling material with low alkali dissolution rate cured at room temperature and preparation method thereof
  • Alkali-activated gelling material with low alkali dissolution rate cured at room temperature and preparation method thereof
  • Alkali-activated gelling material with low alkali dissolution rate cured at room temperature and preparation method thereof

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preparation example Construction

[0036] The present invention also proposes a method for preparing the aforementioned alkali-activated gelling material with low alkali dissolution rate maintained at normal temperature, which comprises the following steps: 1) weighing the powder raw material and water glass respectively; 2) taking the powder The raw materials are uniformly mixed to obtain a gelled powder; 3) the gelled powder and water glass are mixed with water to obtain a slurry of an alkali-activated gelled material; 4) the slurry is molded and maintained at room temperature.

[0037] Preferably, in the aforementioned method for preparing an alkali-activated gelling material with low alkali dissolution rate cured at room temperature, the water-cement ratio of the slurry is 0.5 in parts by mass.

[0038] The alkali-activated gelling material has a fast setting time and can be prepared immediately after use.

[0039] The alkali-activated gelling material can be cured at normal temperature to achieve the requi...

Embodiment 1-19

[0048] According to the formula shown in Table 1, the alkali-activated gelling material of the low alkali dissolution rate of normal temperature curing is prepared, and the steps are as follows: 1) weigh tailings, slag powder and water glass according to the above-mentioned formula table; The raw materials described above are mixed uniformly to obtain gelled powder; 3) the described gelled powder is mixed with water glass and water, and the quality of adding water is "(tailings quality+slag powder quality+aluminate cement quality+amorphous alumina quality)×0.5-the quality of water in water glass ", obtain the slurry of alkali-activated gelling material; Wherein, the quality of water in water glass is the quality of water in the aqueous solution of water glass, and its amount can be By the water glass dosage described in above-mentioned table 1 and obtain according to its solid content, modulus calculation; Wherein, modulus is that the water glass solution solid content of 1.8 i...

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Abstract

The invention provides an alkali-activated gelling material cured at room temperature with low alkali dissolution and a preparation method thereof. The alkali-activated gelling material includes in parts by mass: gelling powder, 100 parts; water glass, with Na contained therein 2 O meter, 5-6 parts, the modulus of described water glass is 1.8-2.2; Aluminate cement, 1-5 parts; Amorphous alumina, 1-4 part; Wherein, described amorphous alumina Together with aluminate cement, it is called aluminum-containing additive; the mass part of described aluminum-containing additive is 4-8 parts; The raw material of described alkali-activated cementitious material comprises Na 2 O and Al 2 o 3 , the Na 2 O and Al 2 o 3 The molar ratio is 0.97‑1.08. The gelling material is added with highly active aluminum-containing additives so that the alkali dissolution rate is ≦4%; at the same time, only normal temperature curing is required in the preparation process to achieve better comprehensive performance.

Description

technical field [0001] The invention relates to the field of building materials, in particular to an alkali-activated gelling material cured at room temperature with low alkali dissolution and a preparation method thereof. Background technique [0002] Alkali-activated gelling material is a new type of gelling material that uses silicon-aluminum waste as the main raw material and is hydraulically hardened under the action of alkali. The material is considered as a low-carbon cementitious material because of its low energy consumption and low emissions during the preparation process, and it can provide similar properties to cement-based cementitious materials, and has become a research hotspot in recent years. [0003] Although the alkali-activated gelling material prepared from metakaolin-rich raw materials has many performance advantages such as fast strength development and excellent chemical erosion resistance, it also has two defects: one is that it needs a short period ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/153
CPCC04B7/1535Y02P40/10
Inventor 叶家元张文生史迪
Owner CHINA BUILDING MATERIALS ACAD
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