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Anode oxidizable high-strength 6xxx series aluminum alloy and preparation method thereof

An anodic oxidation and aluminum alloy technology, which is applied in the field of aluminum alloy materials, can solve the problems of corrosion pits, low profile strength, and small retention of strengthening effect, and achieve uniform appearance and color, dense film layer, excellent mechanical properties and stability. Effect

Active Publication Date: 2019-03-19
上海铱钡新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

"The disadvantage of this invention technology is that: the Si content is high, which is very unfavorable to the anodic oxidation effect, and the Mg in the subsequent oxidation and coloring process of the profile 2 The Si phase is easy to cause corrosion pits, resulting in discoloration of patterns; if the content of Cu and Fe is high at the same time, the oxide film of the 6-series alloy is dark and can only be dyed in a dark color; Zn is used as an impurity element At the same time, the extruded profile has not been subjected to solution treatment, and direct artificial aging has failed to fully exert the second phase strengthening effect, so the mechanical properties are low
"The disadvantage of this invention technology is: only Mg and Si form the second phase as the main strengthening phase, although the strength can be significantly improved, but the anodic oxidation performance is relatively limited; the trace elements that inhibit dynamic recrystallization such as Mn, Cr, Zr, etc. Less addition, less retention of deformation strengthening effect during extrusion, resulting in lower profile strength

Method used

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  • Anode oxidizable high-strength 6xxx series aluminum alloy and preparation method thereof
  • Anode oxidizable high-strength 6xxx series aluminum alloy and preparation method thereof
  • Anode oxidizable high-strength 6xxx series aluminum alloy and preparation method thereof

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Effect test

Embodiment 1

[0036] The composition elements of the aluminum alloy material are: Mg1wt%, Si0.3wt%, Zn0.3wt%, Cu0.6wt%, Mn0.4wt%, Cr0.15wt%, Ti0.08wt%, the content of other impurity elements is ≤ 0.12wt%, the rest is aluminum Al.

[0037] After preparing the materials according to the components and drying them, put the aluminum ingots with a purity ≥99.9% in a heating furnace to melt, the temperature of the molten aluminum is 670°C, and add aluminum-silicon, aluminum-copper, aluminum-manganese and aluminum-chromium master alloys into the melt, And pure Zn, after all the melting, adjust the temperature to 680°C, add pure Mg and AlTiB, then heat up to 740°C after the alloy is completely melted, fully stir, then stand for 40 minutes and then refine and degas at 720°C slag, and after standing for 40 minutes, the molten metal was semi-continuously cast at 690°C into cast rods. The cast rods were subjected to homogenization heat treatment at 520°C, kept at room temperature for 10 hours, then co...

Embodiment 2

[0039] The composition elements of the aluminum alloy material are: Mg1.2wt%, Si0.4wt%, Zn0.6wt%, Cu0.4wt%, Mn0.4wt%, Cr0.2wt%, Ti0.1wt%, other impurity elements The content is ≤0.12wt%, and the rest is aluminum Al.

[0040] After preparing the materials according to the components and drying them, put the aluminum ingots with a purity ≥99.9% in a heating furnace to melt, the temperature of the molten aluminum is 670°C, and add aluminum-silicon, aluminum-copper, aluminum-manganese and aluminum-chromium master alloys into the melt, And pure Zn, after all the melting, adjust the temperature to 680°C, add pure Mg and AlTiB, then heat up to 740°C after the alloy is completely melted, fully stir, then stand for 40 minutes and then refine and degas at 720°C slag, and after standing for 40 minutes, the molten metal was semi-continuously cast at 690°C into cast rods. The cast rods were subjected to homogenization heat treatment at 520°C, kept at room temperature for 10 hours, then co...

Embodiment 3

[0050] The composition elements of the aluminum alloy material are: Mg: 0.7wt%, Si: 0.2wt%, Zn: 0.2wt%, Cu: 0.3wt%, Mn: 0.2wt%, Cr: 0.1wt%, Ti: 0.03wt%, other impurity element content ≤ 0.13%.

[0051] A method for preparing an anodizable high-strength 6xxx series aluminum alloy, comprising the following steps:

[0052] The first step is melting and casting. After the materials are prepared according to the components and dried, the aluminum ingot with a purity ≥ 99.9% is melted in a heating furnace. Alloy, Al-Mn master alloy, Al-Cr master alloy and pure zinc, after they are all melted, adjust the temperature to 680°C, add pure Mg and AlTiB, then heat up to 740°C after all the alloy is melted, fully stir, and then let stand After 40 minutes, carry out refining degassing and slag removal at 730°C, and after standing for 40 minutes, semi-continuously cast the molten metal into cast rods at 690°C;

[0053] In the second step, the cast rod is subjected to homogenization heat tre...

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Abstract

The invention relates to an anode oxidizable high-strength 6xxx series aluminum alloy and a preparation method thereof. The aluminum alloy comprises the following components of 0.7-1.5wt% of Mg, 0.2-0.5wt% of Si, 0.2-0.8wt% of Zn, 0.3-0.7wt% of Cu, 0.2-0.6wt% of Mn, 0.1-0.3wt% of Cr, 0.03-0.12% of Ti, less than or equal to 0. 13wt% of other impurity elements, and the balance Al. The specific preparation method comprises the following steps that pure Al ingots, pure Mg ingots, pure Zn ingots, AlSi intermediate alloy, AlCu intermediate alloy, AlZr intermediate alloy and AlMn intermediate alloy are taken as raw materials, and are put into a smelting furnace in proportion, a melt is subjected to stirring, refining, purifying, degassing and slagging off and standing treatment, then casting is conducted into cast ingots, then extruding is conducted into an aluminum alloy profile according to the extrusion ratio of 15-30:1, and then quenching, T6 heat treatment and anodic oxidation treatmentare conducted. Compared with the prior art, the anode oxidizable high-strength 6xxx series aluminum alloy and the preparation method thereof have the advantages that the Vickers hardness of the 6xxx series alloy extruded profile prepared by the method is greater than 130 HV, the yield strength is larger than 350 Mpa, the elongation rate is larger than 8%, and the surface is uniform in color, and free of the defects such as spots and lines after being subjected to anode oxidation.

Description

technical field [0001] The invention belongs to the field of aluminum alloy materials, and in particular relates to an anodizable high-strength 6xxx aluminum alloy used in appearance parts of electronic products and a preparation method thereof. Background technique [0002] At present, the aluminum alloys used in the manufacture of electronic product appearance parts are still mainly 6-series aluminum alloys. Due to their excellent anodic oxidation performance and good mechanical properties, they are widely used in electronic products such as mobile phone casings, tablet computer casings, desktop computer casings, and liquid crystal display casings. The product shell field is widely used, and it also shows broad application prospects in the field of smart home. However, with the trend of thinner and lighter electronic products, various manufacturers have put forward higher requirements on the performance of housing materials. Traditional 6063 (σs≤220MPa) and 6061 aluminum ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/08C22C1/03C22F1/047
CPCC22C1/026C22C1/03C22C21/08C22F1/047
Inventor 谷立东应韬肖珩周志勇曾小勤邓瑞祥
Owner 上海铱钡新材料科技有限公司
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