Unlock instant, AI-driven research and patent intelligence for your innovation.

High-air permeability high-moisture emission superfine fiber synthetic leather and preparation method thereof

A super-fine fiber, highly breathable technology, applied in applications, coatings, road vehicles, etc., can solve problems such as solvent pollution, product safety issues, and damage to the health of industrial workers

Inactive Publication Date: 2019-04-12
SHAANXI UNIV OF SCI & TECH
View PDF7 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the production of microfiber synthetic leather still adopts a solvent-based production system, which has the following main problems: First, in the production of microfiber synthetic leather, the combination of superfine fiber and PU adopts a wet coagulation process, To use a large amount of dimethylformamide (DMF) solvent, a large amount of waste water containing DMF will be produced, and the residual DMF in the finished product will also cause product safety problems
However, since the current synthetic leather still uses a solvent-based production system, it will not only cause serious solvent pollution problems, damage the health of industrial workers, restrict products from entering the high-end product market at home and abroad, but also easily cause product safety problems caused by solvent residues.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) In parts by mass, 5 parts of sodium hydroxide, 5 parts of urea, and 75 parts of water are fully mixed and dissolved to obtain solution A; in parts by mass, 100 parts of solution A are added to low-temperature alkali-resistant solution In the container, pre-cool at -15°C for 3 hours, then add 10 parts of pulp board, after adding the pulp board into the solution A, stir for 5 minutes to fully dissolve the cellulose, and obtain the impregnation solution B.

[0038] (2) Place the orange petal microfiber nonwoven fabric in the dipping tank filled with impregnation solution B, make the impregnation solution B fully soak the orange petal superfine fiber nonwoven fabric, and then pass the liquid through a pair of rolling sticks to make the orange petal The added weight of the microfiber nonwoven fabric is 70% of the mass of the microfiber nonwoven fabric before impregnation. Place the weighted orange segment microfiber nonwoven fabric in a coagulation tank filled with a 10%...

Embodiment 2

[0041] (1) In parts by mass, 6 parts of sodium hydroxide, 15 parts of urea, and 90 parts of water are fully mixed and dissolved to obtain solution A; in parts by mass, 100 parts of solution A are added to low-temperature alkali-resistant solution In the container, pre-cool at -5°C for 10 hours, then add 15 parts of pulp board, after adding the pulp board into the solution A, stir for 80 minutes to fully dissolve the cellulose, and obtain the impregnation solution B.

[0042] (2) Place the split-type microfiber nonwoven fabric in an impregnation tank filled with impregnation solution B, make the impregnation solution B fully soak into the split-type ultrafine fiber nonwoven fabric, and then pass a pair of rolls to squeeze the liquid to make the split-type The added weight of the microfiber nonwoven fabric is 90% of the mass of the microfiber nonwoven fabric before impregnation. The weight-increased split-type ultra-fine fiber nonwoven fabric is coagulated for 15 minutes in a co...

Embodiment 3

[0045] (1) In parts by mass, 7 parts of sodium hydroxide, 10 parts of urea, and 80 parts of water are fully mixed and dissolved to obtain solution A; in parts by mass, 100 parts of solution A are added to low-temperature alkali-resistant solution In the container, pre-cool at -10°C for 4 hours, then add 10 parts of pulp board, after adding the pulp board into the solution A, stir for 10 minutes to fully dissolve the cellulose, and obtain the impregnation solution B.

[0046] (2) Place the split-type microfiber nonwoven fabric in an impregnation tank filled with impregnation solution B, make the impregnation solution B fully soak into the split-type ultrafine fiber nonwoven fabric, and then pass a pair of rolls to squeeze the liquid to make the split-type The added weight of the microfiber nonwoven is 80% of the mass of the microfiber nonwoven before impregnation. The weight-increased split-type ultra-fine fiber nonwoven fabric is coagulated for 14 minutes in a coagulation tank...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
degree of polymerizationaaaaaaaaaa
Login to View More

Abstract

The invention discloses high-air permeability high-moisture emission superfine fiber synthetic leather and a preparation method thereof. The preparation method comprises the following steps: by takingsuperfine fiber non-woven cloth of a three-dimensional interwoven structure as a base material, combining cellulose with a superfine fiber by using a dipping and curing combination technique so as toobtain high-air permeability high-moisture emission composite base cloth, and carrying out a common aftertreatment process of superfine fiber synthetic leather, thereby obtaining the high-air permeability high-moisture emission superfine fiber synthetic leather. The high-air permeability high-moisture emission superfine fiber synthetic leather has very good sanitation properties and anti-electrostatic properties, has air permeability greater than or equal to 10000(mL / cm<2>*h), has moisture permeability greater than or equal to 2.0(mg / cm<2>*h), is free of substances of very high concern (SVHC)of the European Union, has an atomization value less than or equal to 5mg (DIN75-201B), is an environmental-friendly superfine fiber synthetic leather, and can be used as an automobile trim material,a chair skin material, a high-end sports shoe material, and the like.

Description

【Technical field】 [0001] The invention relates to the technical field of superfine fiber synthetic leather, in particular to a highly air-permeable and high-humidity-discharging superfine fiber synthetic leather and a preparation method thereof. 【Background technique】 [0002] The raw hides used to produce natural leather are limited, and the production of natural leather is a process of high energy consumption and high pollution, which will bring great pollution load to the environment. In recent years, developed countries such as the European Union have also proposed new standards for the safety of natural leather itself, strictly restricting the presence of toxic chemicals such as Cr(VI), azo dyes, pentachlorophenol (PCP) and free formaldehyde in natural leather. . From the perspective of raw leather resources, environmental protection, product safety and market, the production of natural leather is facing great challenges. [0003] For the above reasons, countries all ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/00
CPCD06N3/00D06N3/0004D06N3/0011D06N2203/026D06N2209/046D06N2209/123D06N2209/126D06N2209/141D06N2211/106D06N2211/14D06N2211/263D06N2211/28
Inventor 马兴元何远鑫贺营花吴晓珍
Owner SHAANXI UNIV OF SCI & TECH