Ordinary pressure preparation method for aluminium oxide composite aerogel rapped by silicon dioxide

A technology of composite airgel and silica, which is applied in the direction of airgel preparation, chemical instruments and methods, colloid chemistry, etc., can solve the problems of reducing the heat insulation effect of materials, harsh conditions, and high density, and achieve equipment and daily Low maintenance investment, mild reaction conditions, and reduced production costs

Inactive Publication Date: 2019-04-16
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional silica airgel has good thermal insulation performance at low temperatures, but its internal structure will be damaged if used in a high temperature environment for a long time, which will greatly reduce the thermal insulation effect of the material and limit its use in high temperature environments. At the same time, the use of supercritical drying methods to dry wet gels also has disadvantages such as low safety factor and harsh conditions, which limit the industrialization and large-scale application of airgel materials
Due to its high temperature resistance and high strength, alumina is often used in high temperature fields, but it also has defects such as high thermal conductivity and high density.

Method used

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  • Ordinary pressure preparation method for aluminium oxide composite aerogel rapped by silicon dioxide
  • Ordinary pressure preparation method for aluminium oxide composite aerogel rapped by silicon dioxide
  • Ordinary pressure preparation method for aluminium oxide composite aerogel rapped by silicon dioxide

Examples

Experimental program
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Effect test

Embodiment 1

[0030] Drying at normal pressure to prepare silica-coated alumina composite airgel comprises the following steps:

[0031] 1) Mix aluminum chloride hexahydrate, absolute ethanol, deionized water and formamide in a beaker at a mass ratio of 2:2.5:2.3:0.25 to form a mixed solution, stir and hydrolyze for 3 hours, add to the hydrolyzed mixed solution Add propylene oxide at a volume ratio of 2:1 (that is, the volume ratio of the mixture to propylene oxide is 2:1), continue to stir for 1 minute, then stop, and wait for gel at room temperature;

[0032] 2) After the solution in the beaker is solidified into a gel, place the beaker in a 40°C water bath for constant temperature aging for 20 hours, then add absolute ethanol to the aged gel in the beaker at a mass ratio of 1:1.5 (i.e. The mass ratio of glue to absolute ethanol is 1:1.5), cover the plastic wrap through the upper opening of the beaker, seal and soak for 24 hours for solvent exchange;

[0033] 3) Step 2) After the solvent...

Embodiment 2

[0044] Drying at normal pressure to prepare silica-coated alumina composite airgel comprises the following steps:

[0045] 1) Mix aluminum chloride hexahydrate, absolute ethanol, deionized water and formamide in a beaker at a mass ratio of 2:3.5:3:0.35 to form a mixed solution, stir and hydrolyze for 5 hours, add to the hydrolyzed mixed solution Add propylene oxide at a volume ratio of 2:1.3, continue to stir for 3 minutes and then stop, and stand at room temperature to wait for the gel;

[0046] 2) After the solution in the beaker is solidified into a gel, place the beaker in a 40°C water bath for constant temperature aging for 20 hours, then add absolute ethanol to the aged gel in the beaker at a mass ratio of 1:1.5, and pass through the beaker The upper opening is covered with plastic wrap, sealed and soaked for 36 hours for solvent exchange;

[0047] 3) Step 2) After the solvent exchange, remove the ethanol in the beaker, and add a mixture of tetraethyl orthosilicate and ...

Embodiment 3

[0051] Drying at normal pressure to prepare silica-coated alumina composite airgel comprises the following steps:

[0052] 1) Mix aluminum chloride hexahydrate, absolute ethanol, deionized water and formamide in a beaker at a mass ratio of 2:3:2.8:0.3 to form a mixed solution, stir and hydrolyze for 4 hours, add to the hydrolyzed mixed solution Add propylene oxide at a volume ratio of 2:1.1, continue to stir for 2 minutes and then stop, and stand at room temperature to wait for the gel;

[0053] 2) After the solution in the beaker is solidified into a gel, place the beaker in a 40°C water bath for constant temperature aging for 18 hours, then add absolute ethanol to the aged gel in the beaker at a mass ratio of 1:1.2, and pass through the beaker Cover the upper opening with plastic wrap, seal and soak for 28 hours for solvent exchange;

[0054] 3) Step 2) After the solvent exchange, remove the ethanol in the beaker, and add a mixture of tetraethyl orthosilicate and absolute e...

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Abstract

The invention discloses an ordinary pressure preparation method for aluminium oxide composite aerogel wrapped by silicon dioxide. According to the method, cheap inorganic aluminium salt is taken as araw material, aluminium oxide wet gel is prepared through a collosol-gel method, a framework of the wet gel is wrapped by a silicon dioxide layer, and the effects of surface modification and anti-sintering at the high temperature are achieved; then the aluminium oxide composite aerogel wrapped by the silicon dioxide is obtained through steps of hydrophobic modification and normal-pressure drying.The prepared composite aerogel has the advantages of being lower in density, capable of resisting high temperature and high in temperature preservation performance and can be widely applied to the fields of aerospace, industrial furnaces and the like which need heat insulation under the high temperature condition.

Description

technical field [0001] The invention belongs to the technical field of preparation of inorganic materials, and in particular relates to a normal-pressure preparation method of silica-coated alumina composite airgel. Background technique [0002] Energy saving has been paid more and more attention by the governments of various countries. Among them, the research and application of thermal insulation materials is one of the main measures for energy saving. Effectively prevent the temperature transfer between the surface and the substrate with near-zero energy consumption, and realize thermal protection in an environment where space and overall quality are strictly limited, which is of great significance to promote the development of aerospace, national defense, construction and other industries. [0003] The construction industry and aerospace and other fields all need thermal insulation materials with high temperature resistance, light weight, high strength and excellent perf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J13/00
CPCB01J13/0091
Inventor 王建国宋鑫包志康孔祥宇杨骏许在祥
Owner ZHEJIANG UNIV OF TECH
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