High-transparency glass hydrophobic agent and preparation method thereof

A light-transmitting glass and hydrophobic agent technology, applied in coatings and other directions, can solve problems such as limited application range, weak sand and dust erosion resistance, and harsh service conditions, and achieve broad market prospects, unaffected light transmittance, and low cost. The effect of environmental protection

Active Publication Date: 2019-04-26
湖北隆胜四海新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] There are glass hydrophobic agents for daily car maintenance on the market, but they are generally short-acting hydrophobic agents with weak sand and dust resistance, and the glass surface needs to be cleaned to achieve a good hydrophobic effect. The use conditions are relatively harsh. limited range

Method used

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  • High-transparency glass hydrophobic agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of water-repellent agent for high light-transmitting glass, each substance and content in the raw material are as shown in Table 1, and the unit of each substance content is g;

[0027] Dimethylcyclosiloxane is octamethylcyclotetrasiloxane;

[0028] Phenyl-containing siloxanes include octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyldiphenylsiloxane, short-chain methylphenylsiloxane, The weight ratio is 1:2:1:3;

[0029] The silane coupling agent is N-β-(aminoethyl)-γ-aminopropylmethyltrimethoxysilane;

[0030] Basic catalyst tetramethylammonium hydroxide;

[0031] Non-ionic surfactants include nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, isomeric tridecyl alcohol polyoxyethylene ether, and the weight ratio is 2:1:3;

[0032] The solvent is ethanol.

[0033] A preparation method of a high-transparency glass hydrophobic agent based on the above-mentioned material components, comprising the f...

Embodiment 2

[0035] A kind of water-repellent agent for high light-transmitting glass, each substance and content in the raw material are as shown in Table 1, and the unit of each substance content is g;

[0036] Dimethylcyclosiloxane is dimethylcyclosiloxane;

[0037] The phenyl-containing siloxane is octaphenylcyclotetrasiloxane;

[0038] The silane coupling agent is N-β-(aminoethyl)-γ-aminopropylmethyl trimethoxysilane;

[0039] The basic catalyst is tetramethylammonium hydroxide;

[0040] The nonionic surfactant is isomeric tridecyl alcohol polyoxyethylene ether;

[0041] The solvent is acetone.

[0042] A preparation method of a high-transparency glass hydrophobic agent based on the above-mentioned material components, comprising the following steps: S1, weighing dimethylcyclosiloxane, phenyl-containing siloxane and silane coupling agent in proportion, mixing and stirring Homogeneous, heated to 90°C to get the hot material; S2, under the condition of 125-130°C, continuously add th...

Embodiment 3

[0044] A kind of water-repellent agent for high light-transmitting glass, each substance and content in the raw material are as shown in Table 1, and the unit of each substance content is g;

[0045] Dimethylcyclosiloxane includes octamethylcyclotetrasiloxane and dimethylcyclosiloxane in a weight ratio of 1:1;

[0046] Phenyl-containing siloxanes include octaphenylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, short-chain dimethyldiphenylsiloxane, short-chain methylphenylsiloxane , the weight ratio is 3:3:1:1;

[0047] The silane coupling agent is N-β-(aminoethyl)-γ-aminopropylmethyltrimethoxysilane;

[0048] The basic catalyst is tetramethylammonium hydroxide;

[0049] Non-ionic surfactants include nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, isomeric tridecyl alcohol polyoxyethylene ether, and the weight ratio is 1:1:1;

[0050] The solvents are methanol, ethanol, and isopropanol, and the weight ratio is 1:1:1.

[0051] A prepara...

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Abstract

The invention belongs to the technical field of hydrophobic treatment on surface of glass, and particularly relates to a high-transparency glass hydrophobic agent and a preparation method thereof. Thehigh-transparency glass hydrophobic agent is prepared from the following raw materials in parts by weight: 100 parts of dimethylcyclosiloxane, 20-50 parts of phenylsiloxane, 5-10 parts of a silane coupling agent, 0.1-1 part of an alkaline catalyst, 5-100 parts of a nonionic surfactant and 10-90 parts of a solvent. A transparent hydrophobic film can be formed on the surface of glass, when water issprayed on the surface of the glass, water drops are formed, a contact angle reaches up to 110 degrees, the dropping speed of the water drops is greatly increased, and the water drops can automatically roll off without marks, so that the problem of unclear line of sight is solved.

Description

technical field [0001] The invention belongs to the technical field of glass surface hydrophobic treatment, and in particular relates to a highly transparent glass hydrophobic agent and a preparation method thereof. Background technique [0002] The surface of ordinary glass is a hydrophilic surface. When water droplets spread on the glass, the light transmission of the glass will deteriorate. The blurring of car windshields, side windshields, and front and rear view mirrors is an important cause of traffic accidents. In the case of rain or high humidity, attached droplets will form on the surface of the car glass and affect the line of sight. [0003] There are glass hydrophobic agents for daily car maintenance on the market, but they are generally short-acting hydrophobic agents with weak sand and dust resistance, and the glass surface needs to be cleaned to achieve a good hydrophobic effect. The use conditions are relatively harsh. The scope is limited. Contents of the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/28C03C17/30
CPCC03C17/006C03C17/28C03C17/30C03C2217/29C03C2217/40C03C2217/70C03C2218/11
Inventor 王薛成耿学辉杨帆杨开柱
Owner 湖北隆胜四海新材料有限公司
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