Extraction method of metal ions in lithium ion battery leaching solution by using ionic liquid

A technology of lithium ion battery and ionic liquid, which is applied in the field of extraction and separation of metal ions in leachate of waste nickel cobalt lithium manganate battery cathode sheet, can solve the problems of volatility, toxicity, flammability of extractant, etc., and achieve high extraction capacity and stability good effect

Active Publication Date: 2019-04-30
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Most of the extraction agents used in traditional liquid-liquid extraction are fl

Method used

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  • Extraction method of metal ions in lithium ion battery leaching solution by using ionic liquid
  • Extraction method of metal ions in lithium ion battery leaching solution by using ionic liquid
  • Extraction method of metal ions in lithium ion battery leaching solution by using ionic liquid

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0017] Implementation case 1: Ionic liquid extraction-stripping cycle.

[0018] The details are as follows:

[0019] step one:

[0020] Extraction process: Add a certain volume of water to dilute the ionic liquid to reduce the viscosity, take 5 mL of extractant and mix the same volume with the metal ion leaching solution of the lithium battery positive electrode sheet, and shake and mix for 15 minutes at 60 degrees Celsius. In the metal ion leaching solution of the lithium battery positive electrode sheet, the concentration of each metal ion is 4502 ppm for nickel ions, 1782 ppm for cobalt ions, 2846 ppm for manganese ions, and 734 ppm for lithium ions.

[0021] Step two:

[0022] Separation process: Centrifuge for 2 minutes under the condition of 5000 revolutions per minute, layer the extract phase and raffinate phase, and separate the two phases.

[0023] Step three:

[0024] Stripping process: Add a certain volume of water to the extraction phase and mix, shake and mix for 15 minutes ...

Example Embodiment

[0027] Implementation case 2: ionic liquid continuous extraction cycle.

[0028] The details are as follows:

[0029] step one:

[0030] Extraction process: Add a certain volume of water to dilute the ionic liquid to reduce the viscosity, take 5 mL of extractant and mix the same volume with the metal ion leaching solution of the lithium battery positive electrode sheet, and shake and mix for 15 minutes at 60 degrees Celsius. In the metal ion leaching solution of the lithium battery positive electrode sheet, the concentration of each metal ion is 4502 ppm for nickel ions, 1782 ppm for cobalt ions, 2846 ppm for manganese ions, and 734 ppm for lithium ions.

[0031] Step two:

[0032] Separation process: Centrifuge for 2 minutes under the condition of 5000 revolutions per minute, layer the extract phase and raffinate phase, and separate the two phases.

[0033] Step three:

[0034] Cyclic extraction process: Take 5 mL of the extractant in step 2 and mix the same volume with the metal ion le...

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Abstract

The invention belongs to the technical field of recycling and reusing of waste cathode materials for lithium ion batteries. The invention provides a green extraction and separation method based on ionic liquids to realize the extraction and separation of metal ions in a leaching solution of waste nickel-cobalt manganic acid lithium battery anode pieces. The extraction method of the metal ions in alithium ion battery leaching solution by using the ionic liquids comprises the steps of extraction, separation, back extraction and the like to realize the extraction and the separation of the metalions in the waste lithium ion battery leaching solution without adding organic solvent diluents. The extraction agent has good stability, can be recycled for many times and has a high extraction capacity.

Description

technical field [0001] The invention belongs to the technical field of recovery and reuse of positive electrode materials of waste lithium-ion batteries, and relates to a method for extracting and separating metal ions in leachate of positive plates of waste nickel-cobalt-lithium-manganese-oxide batteries based on extraction and separation of green solvent ionic liquids. Background technique [0002] With the adjustment of the global energy structure and the development of electronic information and other technologies, various electronic devices such as mobile phones, notebook computers, and new energy vehicles basically require lithium batteries. The output of lithium batteries in my country in 2010 was 2.687 billion. With the rapid development of new energy vehicles, especially pure electric vehicles, the national output of lithium batteries reached 13.987 billion in 2018. Due to the inevitable capacity decay caused by the increase in the number of charge and discharge dur...

Claims

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Application Information

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IPC IPC(8): C22B7/00C22B26/12C22B47/00C22B23/00
CPCC22B7/006C22B23/0453C22B26/12C22B47/00Y02P10/20
Inventor 付明来徐垒
Owner INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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