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Preparation method of photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint

An epoxy fiberglass and graphene-based technology, applied in the direction of epoxy resin coating, coating, etc., can solve the problems of poor wear resistance, oxygen polymerization inhibition, complex preparation process, etc.

Inactive Publication Date: 2019-05-14
陕西燕园众欣石墨烯科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the free radical photoinitiator system used in photocurable coatings has the disadvantages of oxygen inhibition, large curing shrinkage rate, and slow curing rate of cationic photoinitiator systems; the traditional solvent-free epoxy coating system has slow curing speed and poor wear resistance. Poor; In addition, the traditional FRP preparation process is complicated and cannot be formed at one time

Method used

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  • Preparation method of photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint
  • Preparation method of photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] A kind of photocuring graphene type solvent-free epoxy FRP coating described in the present embodiment and its preparation method are made of the following raw materials in weight percentage:

[0011] Epoxy resin E51 24%

[0012] Epoxy acrylate resin 6104 6%

[0013] Monofunctional monomer IBOA 15%

[0014] Difunctional monomer HDDA 7.5%

[0015] Multifunctional monomer (≥3) TMPTA 7.5%

[0016] Glass fiber powder 36%

[0017] Free radical photoinitiator 184 1%

[0018] Cationic photoinitiator I-160 1%

[0019] Adhesion Promoter 1%

[0020] Defoamer 0.5%

[0021] Graphene Oxide 1%

[0022] Preparation method: Feed the monomer according to the above ratio, stir evenly, slowly add photoinitiator, stir until completely dissolved, add epoxy resin and epoxy acrylate resin in sequence according to the above formula ratio, stir and mix evenly, put into glass Fiber powder, dispersed at high speed, stirred evenly, and then put into adhesion promoter, defoamer, graphene o...

Embodiment 2

[0025] Epoxy resin E51 24%

[0026] Epoxy acrylate resin 6104 6%

[0027] Monofunctional monomer IBOA 7.5%

[0028] Difunctional monomer HDDA 15%

[0029] Multifunctional monomer (≥3) TMPTA 7.5%

[0030] Glass fiber powder 36%

[0031] Free radical photoinitiator 184 1%

[0032] Cationic photoinitiator I-160 1%

[0033] Adhesion Promoter 1%

[0034] Defoamer 0.5%

[0035] Graphene Oxide 1%

[0036] Preparation process and method of use are the same as in Example 1

Embodiment 3

[0038] Epoxy resin E51 24%

[0039] Epoxy acrylate resin 6104 6%

[0040] Monofunctional monomer IBOA 7.5%

[0041] Difunctional monomer HDDA 7.5%

[0042] Multifunctional monomer (≥3) TMPTA 15%

[0043] Glass fiber powder 36%

[0044] Free radical photoinitiator 184 1%

[0045] Cationic photoinitiator I-160 1%

[0046] Adhesion Promoter 1%

[0047] Defoamer 0.5%

[0048] Graphene Oxide 1%

[0049] Preparation process and method of use are the same as in Example 1

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Abstract

The invention relates to a preparation method of a photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint, in particular to a photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint and a preparation method thereof. The photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint is made from, by percent, resin, a monomer (an active diluent), glass powder, a photoinitiator A, a photoinitiator B, a defoaming agent, an adhesion promoter, and graphene oxide. During curing, the graphene oxide is reduced into graphene, so that improved adhesion, wear resistance and the like are imparted to a coating; the photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint also has the advantages of high curing speed, excellent corrosion resistance, good mechanical properties, good construction operability and the like. The photo-curable graphene solvent-free epoxy fiberglass reinforced plastic paint is applicable to pipeline joint patch, station buried pipelines, pipeline crossing external protection, pipeline elbows of different diameters and the like.

Description

technical field [0001] The invention relates to a light-cured graphene-type solvent-free epoxy glass steel coating, in particular to a light-curable graphene-type solvent-free epoxy glass steel coating and a preparation method thereof. technical background [0002] With the development of economy and science and technology, people's awareness of environmental protection is getting stronger and stronger, and they begin to pay attention to the use of environmentally friendly coatings. Green environmental protection coatings mainly include the following types: powder coatings, water-based coatings, solvent-free coatings, high-solid coatings and radiation curing. paint etc. Among them, light-curing coatings are environmentally friendly and energy-saving coatings developed in the 1960s that can undergo physical and chemical changes in a short period of time after being irradiated by light. Compared with, it has the advantages of fast curing speed, energy saving, no pollution, no...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D163/10C09D7/61C08J7/04
Inventor 田幼华候胜华
Owner 陕西燕园众欣石墨烯科技有限公司
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