Method and device for directly preparing polylactic acid foam product from polylactic acid polymer melt

A polylactic acid foaming and polymerizing device technology is applied in the field of directly preparing foamed products from polylactic acid polymer melt, which can solve the problems of complex procedures and high costs, and achieve the effects of ensuring quality, low porosity and reducing costs.

Active Publication Date: 2019-05-21
CHTC BIO BASED MATERIAL ENG & TECH NINGBO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

To sum up, the existing patents for preparing foams from polylactic acid all use polylactic acid resin slices, which are dried, modified and granulated, dried again, cooled, dried, or directly extruded / injected / kettle pressured after modification The way of foaming, polylactic acid needs to go through multiple heating and cooling temperatures and melt mixing, the process is complicated and the cost is high

Method used

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  • Method and device for directly preparing polylactic acid foam product from polylactic acid polymer melt
  • Method and device for directly preparing polylactic acid foam product from polylactic acid polymer melt
  • Method and device for directly preparing polylactic acid foam product from polylactic acid polymer melt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0076] Example 1 The method of directly preparing polylactic acid foamed products from polylactic acid polymer melt

[0077] refer to Figure 3-6 The method for directly preparing polylactic acid foamed products from the polylactic acid polymer melt of the present invention comprises the following steps:

[0078] Step 1: Polylactic acid melt preparation

[0079] After the main raw material lactide is heated and melted, it is mixed with the catalyst stannous octoate and the initiator isooctyl alcohol to start the polymerization reaction. The mass ratio of lactide: stannous octoate: isooctyl alcohol is 7500:1:13, and the polymerization temperature 235°C. After the polymerization reaction is completed, a chain terminator 2-ethyloctanoic acid is added to terminate the reaction, and the mass ratio of lactide to terminator is 75000:1. After devolatilization and monomer removal, a polylactic acid melt with a melt flow index of about 3.7g / 10min (190°C, 2.16kg) was obtained, with a ...

Embodiment 2-3

[0103] Example 2-3 Method for directly preparing polylactic acid foamed products from polylactic acid polymer melt

[0104] Examples 2-3 adopt the same foaming process as that of Example 1, except that the proportions of each component in raw materials and additives are different, and the temperature and head pressure process parameters are controlled differently. The process conditions are shown in Table 1, and the results are shown in Table 2.

[0105] Table 1

[0106]

Embodiment 4

[0121] Example 4 A device for directly preparing foam from polylactic acid polymer melt

[0122] The following is a detailed description of the polylactic acid foamed product preparation device of the present invention:

[0123] refer to Figure 3-6 , the device for directly preparing foam from the polylactic acid polymerization melt of the present invention, comprising: a polylactic acid polymerization device 1, a first-stage twin-screw extruder 4 and a second-stage single-screw extruder 9, the first-stage twin-screw extruder Extruder 4 is mainly used for uniform mixing of polylactic acid melt and foaming aid, and preliminary mixing with foaming gas, and the second-stage single-screw extruder 9 is mainly used for mixing polylactic acid / foaming aid The mixing and cooling of the body and the foaming gas reduces the temperature to a range suitable for foaming; the first-stage twin-screw extruder 4 and the second-stage single-screw extruder 9 can be vertically arranged, and the ...

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Abstract

The invention provides a method and a device for directly preparing a polylactic acid foam product from a polylactic acid polymerization melt. The method and the device for directly preparing the polylactic acid foam product from the polylactic acid polymerization melt comprises the steps of polylactic acid melt preparation, material feeding and secondary extruding treatment. In the secondary extruding treatment, the outlet pressure of a first-stage double-screw extruder is 15-17 MPa, the material feeding speed of the polylactic acid polymerization melt is 250 kg / h, the foam auxiliary feedingspeed is 7.5-10 kg / h, and the foaming gas feeding speed is 2.8-7.5 L / h. The method and the device for directly preparing the polylactic acid foam product from the polylactic acid polymerization melt,provided by the invention, have the advantages that an influence on the foaming performance is avoided due to no need of processes such as water cooled pelletizing, repeated drying cooling and heating, melting and mixing; the foaming performance can be guaranteed; the quality can also be guaranteed; the energy consumption is saved by about 1 / 3 or above; the foaming multiplying power of an obtainedproduct is adjusted by 3-25 times; the degree of crystallinity is 40.3-48.5%; the tensile strength is 8.7-19.6 MPa; and the apparent density is 0.05-0.4 g / cm<3>.

Description

technical field [0001] The invention relates to a method and a device for directly preparing foamed products from a polylactic acid polymer melt, and belongs to the technical field of polymer material applications. Background technique [0002] In recent years, the explosive growth of the express delivery and takeaway industries has not only brought a lot of convenience to people's lives, but also brought about increasingly prominent packaging problems. The big data of Chinese food delivery released by the food delivery platform "Ele.me" shows that the number of users in the Chinese market has reached 600 million. In 2016, there were at least 400 million takeaways flying in the streets of China every week, and at least 400 million disposable packaging boxes were produced. With 400 million plastic bags and 400 million discarded disposable tableware, how to deal with takeaway garbage has become an urgent problem to be solved in today's society. [0003] Polylactic acid is a f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/14C08J9/12C08G63/08C08G63/78C08K3/34C08K5/098B29C48/92B29C48/385
CPCB29C48/385C08G63/08C08G63/78C08J9/12C08J9/14C08K3/34C08K5/098B29K2105/04B29K2067/046B29C48/625B29C48/397B29C48/362B29C48/022B29C48/0012B29C48/404B29C48/29B29C48/693B29C48/6912C08J2367/04C08J2201/03C08J9/144C08J2203/142C08J9/122C08J2203/06C08J2203/14C08J9/141B29C48/92B29C48/58B29C48/0013
Inventor 宋亚男王乐军黄伟伟郑宗强刘怡宁
Owner CHTC BIO BASED MATERIAL ENG & TECH NINGBO CO LTD
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