Laminated body and production method therefor
A manufacturing method and a technology for a laminated body, which are applied in chemical instruments and methods, coatings, layered products, etc., can solve the problems of measurement object error, limited interpretation, and no multiple maxima, and achieve excellent weather resistance. and the effect of adhesion
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[0214] Synthesis examples, production examples, examples, and comparative examples are shown below to describe the present invention in detail, but the present invention is not limited to the following examples.
[0215] In addition, molecular weight is the number average molecular weight of polystyrene conversion calculated|required by GPC measurement. The viscosity is a value at 25° C. measured using a rotational viscometer.
[0216] (1) Synthesis of compounds
Synthetic example 1
[0217] [Synthesis Example 1] Synthesis of (A)-1
[0218] [chemical 9]
[0219]
[0220]Methyl Silicate 51 (manufactured by Colcoat Co. Ltd., 235 g, 0.5 mol), TBT700 (Nippon Soda ( Co., Ltd., 0.1 g), di-tert-butylhydroxytoluene (0.6 g), and heated to 85°C. Hydroxyethyl acrylate (551 g, 5 mol) was added and reacted there. Distillation of methanol (80 g) was seen. The reaction mixture was heated under reduced pressure (100° C. / 5 mmHg) for 2 hours to obtain (A)-1 as a colorless liquid (95% yield).
Synthetic example 2
[0221] [Synthesis Example 2] Synthesis of (A)-2
[0222] [chemical 10]
[0223]
[0224] Methyl Silicate 51 (manufactured by Colcoat Co. Ltd., 235 g, 0.5 mol), TBT700 (Nippon Soda ( Co., Ltd., 0.1 g), di-tert-butylhydroxytoluene (0.6 g), and heated to 85°C. Hydroxyethyl acrylate (61 g, 0.55 mol) was added and reacted there. Distillation of methanol (15 g) was seen. The reaction mixture was heated under reduced pressure (100° C. / 5 mmHg) for 2 hours to obtain (A)-2 as a colorless liquid (95% yield).
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