Novel calcium precipitation-free acidizing blockage remover for horizontal well in ultra-low-permeability oil field and preparation method thereof
A horizontal well, ultra-low permeability technology, applied in chemical instruments and methods, drilling composition, etc., can solve the problems of many slugs, long construction period, many liquid dispensing tanks, etc., to inhibit metal corrosion and achieve good bonding Stability, good effect of anti-scaling function
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Embodiment 1
[0020] A novel calcium-free precipitation acidizing plugging remover for horizontal wells in ultra-low permeability oilfields, which is composed of the following raw materials in parts by weight:
[0021] Polyoxypropylene glyceryl ether 1, glycidol 3, methyl methacrylate 10, catalyst 0.1, corrosion inhibitor 2, clay stabilizer 1, mixed acid 100, sodium hypochlorite 3.
[0022] The mixed acid is composed of hydrofluoric acid, fatty alcohol ether sulfosuccinic acid and glycolic acid in a weight ratio of 17:3:1.
[0023] The catalyst is lithium methylate.
[0024] The corrosion inhibitor is cetylpyridinium chloride.
[0025] The clay stabilizer is 2-chloroethyltrimethylammonium chloride.
[0026] The preparation method of described plugging agent, comprises the following steps:
[0027] (1) Get corrosion inhibitor, join in the toluene of its weight 10 times, stir evenly, obtain toluene solution;
[0028] (2) Mix methyl methacrylate and glycidyl alcohol, add it to the above-me...
Embodiment 2
[0033] A novel calcium-free precipitation acidizing plugging remover for horizontal wells in ultra-low permeability oilfields, which is composed of the following raw materials in parts by weight:
[0034] Polyoxypropylene glyceryl ether 2, glycidol 5, methyl methacrylate 14, catalyst 0.2, corrosion inhibitor 3, clay stabilizer 4, mixed acid 130, sodium hypochlorite 5.
[0035] The mixed acid is composed of hydrofluoric acid, fatty alcohol ether sulfosuccinic acid and glycolic acid in a weight ratio of 20:4:1.
[0036] The catalyst is lithium methylate.
[0037] The corrosion inhibitor is cetylpyridinium chloride.
[0038] The clay stabilizer is 2-chloroethyltrimethylammonium chloride.
[0039] The preparation method of described plugging agent, comprises the following steps:
[0040] (1) Get corrosion inhibitor, join in the toluene of its weight 20 times, stir evenly, obtain toluene solution;
[0041] (2) Mix methyl methacrylate and glycidyl alcohol, add it to the above-me...
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