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Novel calcium precipitation-free acidizing blockage remover for horizontal well in ultra-low-permeability oil field and preparation method thereof

A horizontal well, ultra-low permeability technology, applied in chemical instruments and methods, drilling composition, etc., can solve the problems of many slugs, long construction period, many liquid dispensing tanks, etc., to inhibit metal corrosion and achieve good bonding Stability, good effect of anti-scaling function

Inactive Publication Date: 2019-05-31
陕西利源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the acidizing plugging remover commonly used in domestic oilfields consists of three slugs of pre-acid, main acid and post-acid, which need to be configured separately when used in the field. The on-site injection procedure is complicated, and there are several main disadvantages: ①Many slugs , the on-site liquid mixing intensity is high, and there is a certain risk of environmental pollution; ②There are many liquid mixing tanks, which occupy the construction site; ③The construction period is long, the construction is complicated, and the construction cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A novel calcium-free precipitation acidizing plugging remover for horizontal wells in ultra-low permeability oilfields, which is composed of the following raw materials in parts by weight:

[0021] Polyoxypropylene glyceryl ether 1, glycidol 3, methyl methacrylate 10, catalyst 0.1, corrosion inhibitor 2, clay stabilizer 1, mixed acid 100, sodium hypochlorite 3.

[0022] The mixed acid is composed of hydrofluoric acid, fatty alcohol ether sulfosuccinic acid and glycolic acid in a weight ratio of 17:3:1.

[0023] The catalyst is lithium methylate.

[0024] The corrosion inhibitor is cetylpyridinium chloride.

[0025] The clay stabilizer is 2-chloroethyltrimethylammonium chloride.

[0026] The preparation method of described plugging agent, comprises the following steps:

[0027] (1) Get corrosion inhibitor, join in the toluene of its weight 10 times, stir evenly, obtain toluene solution;

[0028] (2) Mix methyl methacrylate and glycidyl alcohol, add it to the above-me...

Embodiment 2

[0033] A novel calcium-free precipitation acidizing plugging remover for horizontal wells in ultra-low permeability oilfields, which is composed of the following raw materials in parts by weight:

[0034] Polyoxypropylene glyceryl ether 2, glycidol 5, methyl methacrylate 14, catalyst 0.2, corrosion inhibitor 3, clay stabilizer 4, mixed acid 130, sodium hypochlorite 5.

[0035] The mixed acid is composed of hydrofluoric acid, fatty alcohol ether sulfosuccinic acid and glycolic acid in a weight ratio of 20:4:1.

[0036] The catalyst is lithium methylate.

[0037] The corrosion inhibitor is cetylpyridinium chloride.

[0038] The clay stabilizer is 2-chloroethyltrimethylammonium chloride.

[0039] The preparation method of described plugging agent, comprises the following steps:

[0040] (1) Get corrosion inhibitor, join in the toluene of its weight 20 times, stir evenly, obtain toluene solution;

[0041] (2) Mix methyl methacrylate and glycidyl alcohol, add it to the above-me...

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PUM

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Abstract

The invention discloses a novel calcium precipitation-free acidizing blockage remover for a horizontal well in an ultra-low-permeability oil field. The novel calcium precipitation-free acidizing blockage remover is prepared from, by weight, the following raw materials: 1-2 parts of polyoxypropylene glycerol ether, 3-5 parts of glycidol, 10-14 parts of methyl methacrylate, 0.1-0.2 part of a catalyst, 2-3 parts of a corrosion inhibitor, 1-4 parts of a clay stabilizer, 100-130 parts of a mixed acid and 3-5 parts of sodium hypochlorite. The blockage remover also has a good scale inhibition function, and protective film can be formed on the metal surface by adopting epoxy modification, so that metal corrosion is effectively inhibited. In addition, the acidizing blockage remover is free of calcium precipitation, good in treatment effect and high in quality.

Description

technical field [0001] The invention belongs to the field of oilfield chemistry, and in particular relates to a novel calcium-free precipitation acidification plugging remover for horizontal wells in ultra-low permeability oilfields and a preparation method thereof. Background technique [0002] Oil well oil layer pollution is the most common production problem commonly encountered in new and old oil fields. The direct consequence of oil layer pollution will reduce the fluid production of oil wells, and in severe cases it will cause oil wells to stop production, resulting in huge economic losses. Oil layer pollution is the production process of oil fields. Inevitably, acidizing plugging removal is the most commonly used economical and effective method to decontaminate oil reservoirs at home and abroad, and it has been developed for nearly a hundred years. At present, the acidizing plugging remover commonly used in domestic oilfields consists of three slugs of pre-acid, main ...

Claims

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Application Information

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IPC IPC(8): C09K8/524C09K8/528
Inventor 袁海滨武娟郭超赵飞彭国勋陈辉张斌刘亭张涛刘洋张立原赵幸东野升富苗军李静瑞张威
Owner 陕西利源科技有限公司
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