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Stratum degradation acid and application thereof

A technology of stratum and citric acid, applied in the field of petroleum additives, can solve the problems that the acidified flowback liquid cannot enter the production process, increase the discharge treatment, and deal with difficulties, so as to reduce the risk of environmental pollution and construction cost, good scale inhibition function, Suppresses the effect of water sensitivity

Pending Publication Date: 2021-01-22
四川中汇安达石油化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, acidizing is a common technology for oil well plugging removal. Conventional acidizing plugging removal agents are mainly hydrochloric acid, nitric acid, formic acid, acetic acid and other additives. The post-processing is difficult, and acid neutralization treatment must be carried out on site. At the same time, the acidified flowback liquid cannot enter the production process, which increases the requirements for discharge treatment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The preparation method of the environment-friendly stratum degradable acid of this embodiment 1 is as follows: first add 790 grams of water in the batching container, heat to 75 ° C, first weigh 10 grams of polyacrylic acid and add it to the water, stir for 1 hour with a high-speed homogenizer, and stir After uniformity, add 100 grams of citric acid and 50 grams of dodecylbenzenesulfonic acid into the batching container, and then continue to stir evenly. After the system is evenly dispersed, add 10 grams of AEC-9H and 10 grams of IS-129 in sequence , 10 grams of lactic acid, 10 grams of polyacrylamide, and 10 grams of amino polyether silicone are added to the batching container. Stir at high speed for 2 hours, stop stirring, cool down naturally, and age for 24 hours to complete the preparation. The active substance content is 21%.

Embodiment 2

[0046]The preparation method of the environment-friendly stratum degradable acid of this embodiment 2 is as follows: first add 310 grams of water in the batching container, heat to 75 ° C, first weigh 50 grams of polyacrylic acid and add it to the water, stir for 1 hour with a high-speed homogenizer, and stir After uniformity, add 250 grams of citric acid and 200 grams of dodecylbenzenesulfonic acid into the batching container, and then continue to stir evenly. After the system is uniformly dispersed, add 50 grams of gemini surfactant, tall oil imidazole Add 30 grams of phosphonate, 50 grams of lactic acid, 3730 grams of polyquaternium, and 30 grams of amino polyether silicone into the batching container. Stir at high speed for 2 hours, stop stirring, cool down naturally, and age for 24 hours to complete the preparation. The active substance content is 69%, and the effective substance refers to chemical components other than water.

Embodiment 3

[0048] The preparation method of the environment-friendly stratum degradable acid in this embodiment 3 is as follows: first add 740 grams of water to the batching container, heat to 75 ° C, first weigh 10 grams of polyacrylic acid and add it to the water, stir for 1 hour with a high-speed homogenizer, and stir After uniformity, add 150 grams of citric acid and 50 grams of dodecylbenzenesulfonic acid into the batching container, and then continue to stir evenly. After the system is uniformly dispersed, add 10 grams of AEC-9H and 10 grams of IS-129 in sequence , 10 grams of lactic acid, 10 grams of polyacrylamide, and 10 grams of amino polyether silicone oil are added to the batching container. Stir at high speed for 2 hours, stop stirring, cool down naturally, and age for 24 hours to complete the preparation. The active substance content is 26%.

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PUM

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Abstract

The invention discloses a safe and environment-friendly stratum degradation acid, which is mainly applied to acidification blockage removal during oil extraction, and comprises the following components in percentage by weight: 10-25% of citric acid; 1%-5% of polyacrylic acid; 5%-20% of dodecylbenzene sulfonic acid; 1%-5% of a surfactant; 1%-3% of a high-temperature corrosion inhibitor; 1%-5% of aniron stabilizer; 1%-3% of a clay stabilizer; 1%-3% of an intelligent agent; and remaining amount of water. The stratum degradation acid disclosed by the invention is good in acidification effect, long in lasting time, easy to biodegrade, safe and environment-friendly, has no adverse effect on stratums, and does not contain inorganic strong acids such as hydrochloric acid, hydrofluoric acid, nitric acid, organic acid formic acid, acetic acid, sulfamic acid, chlorosulfonic acid and the like which are commonly used in traditional acidification.

Description

technical field [0001] The invention belongs to the field of petroleum additives, and in particular relates to a formation degrading acid and its preparation method and application. Background technique [0002] With the rapid growth of the global economy, the dependence on petroleum resources is becoming more and more serious. Although scientific researchers have conducted systematic research on other energy sources, such as solar energy, wind energy, and nuclear energy, and have achieved gratifying results, 90 % of the energy required for transportation still needs to be obtained from petroleum, and the downstream industry chain of petroleum still plays an irreplaceable role in the whole industry. [0003] Due to the lack of protection awareness and human over-exploitation, global oil resource reserves have become less and less. As the world's energy supply becomes increasingly tense, how to improve oil recovery and obtain the highest economic benefits under the premise of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/72C09K8/74
CPCC09K8/725C09K8/74C09K2208/12C09K2208/32
Inventor 王煌
Owner 四川中汇安达石油化工有限公司
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