Preparation method of (methyl)acrylate substances and application of 2-acrylamide-2-methylpropanesulfonic acid
A technology of methylpropanesulfonic acid and acrylamide, which is applied to the preparation of carboxylic acid esters, the preparation of organic compounds, chemical instruments and methods, etc., can solve the problems of cumbersome operation, difficult separation and removal, waste of acrylic acid, etc., and meet the equipment requirements. High, wide application prospects, the effect of avoiding waste
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Embodiment 1
[0088] This embodiment provides a preparation method of a trimethylolpropane triacrylate composition, which includes the following steps.
[0089] In a 1000 ml four-necked reaction flask equipped with electric stirring, thermometer, LZB-2 glass rotameter, water separator (connected to the condenser), add 228g trimethylolpropane, 400g acrylic acid, 112g heptane, 28g of toluene, 32g of 2-acrylamide-2-methylpropanesulfonic acid (AMPS), 1.3g of cuprous chloride, 1.0g of 4-methoxyphenol, 3.5g of hypophosphorous acid, passed through 1.8-2.5 mL / min Air, heat up until the esterification reaction is in a reflux state, and the toluene and heptane water azeotrope will take the water generated by the reaction out of the esterification reaction bottle through the water separator until the water produced per hour is less than 1 mL and the temperature of the reaction solution is stable. , as the end point of the esterification reaction. Cool the esterification reaction mixture to below 40°C...
Embodiment 2
[0096] This embodiment provides a preparation method of tripropylene glycol diacrylate composition, including the following steps.
[0097] In a 1000 ml four-necked reaction flask equipped with an electric stirrer, a thermometer, and a water separator (connected to a condenser), add 342 g of tripropylene glycol, 270 g of acrylic acid, 128 g of toluene, and 18 g of 2-acrylamide-2-methylpropane in sequence. Sulfonic acid (AMPS), 2.8g copper sulfate pentahydrate, 1.0g 4-methoxyphenol, 3.9g hypophosphorous acid, 1.0g triphenylphosphine, heat up to the state of reflux in the esterification reaction, toluene and water azeotrope The water generated by the reaction is taken out of the esterification reaction bottle through the water separator until the water produced per hour is less than 1 mL and the temperature of the reaction solution is stable, which is used as the end point of the esterification reaction. Cool the esterification reaction mixture to below 40°C, add 220g of toluene...
Embodiment 3
[0102] This embodiment provides a preparation method of propoxylated (5PO) pentaerythritol tetraacrylate composition, which includes the following steps.
[0103] In a 1000 ml four-necked reaction flask equipped with electric stirring, thermometer, LZB-2 type glass rotameter, water separator (connected to the condenser), add 320g of propoxylated (5PO) pentaerythritol, 246g of acrylic acid, 160g of toluene, 36g 2-acrylamide-2-methylpropanesulfonic acid (AMPS), 1.5g cuprous oxide, 0.9g copper dibutyldithiocarbamate, 1.6g 4-methoxyphenol, 5.2g phosphorous acid, pass Inject 2.8-3.5 mL / min of air, heat up until the esterification reaction is in a reflux state, toluene and water are azeotroped, and the water generated by the reaction is taken out of the esterification reaction bottle through the water separator until the water produced per hour is less than 1 mL and the temperature of the reaction solution is stable, as the end point of the esterification reaction. Cool the esterif...
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