White light quantum dot light-emitting diode and its preparation method
A quantum dot light-emitting and diode technology, which is applied in semiconductor/solid-state device manufacturing, semiconductor devices, electrical components, etc., can solve the problems of inability to prepare stacked quantum dot light-emitting layers, achieve stable polychromatic light, improve stability, and expand options range effect
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[0035] As an implementation, X 2 For -COOH, -OH, -CN, -NHCO-CH 3 , -NH 2 , -SH, -CHO, the replacement ligands formed can be understood as strong polar ligands, including but not limited to thioglycolic acid, 3-mercaptopropionic acid, 3-mercaptobutyric acid, 6-mercaptohexanoic acid, mercaptoethyl Amine, 3-mercaptopropylamine, 4-mercaptobenzoic acid, mercaptoglycerol, 1-trimethylamineethanethiol, mercaptoaniline, nitroaniline, sulfoaniline, aminobenzoic acid, 4-(diphenylphosphino) At least one of benzoic acid.
[0036] As another embodiment, X 2 For -CO-, -COOR, -NO 2 , -O-, -O-CH 3 , -CH 3 When, the formed replacement ligand can be understood as a weakly polar replacement ligand, including but not limited to octylamine, propylamine, hexadecylamine, 4-mercaptoanisole, 1-hydroxy-3-methoxy-propane At least one of. Of course, the embodiment of the present invention can also adjust the polarity of the replacement ligand by adjusting the carbon chain length of R. Specifically, the long...
Embodiment 1
[0075] This embodiment provides a white light quantum dot light-emitting diode and a manufacturing method thereof. The white light quantum dot light emitting diode includes laminated ITO glass, a PEDOT layer, a TFB layer, a CdSe red light quantum dot light emitting layer, a CdSe green light quantum dot light emitting layer, a CdSe blue light quantum dot light emitting layer, a ZnO layer and an Al layer. And in the surface layer of the bonding surface of the CdSe red light quantum dot light-emitting layer and the CdSe green light quantum dot light-emitting layer, the quantum dots and the CdSe green light quantum dot light-emitting layer and the CdSe blue quantum dot light-emitting layer are bonded with 3-mercapto groups on the surface layer. Propionic acid ligands, and adjacent 3-mercaptopropionic acid ligands are cross-linked.
[0076] The quantum dot light-emitting diode of this embodiment is prepared according to the following method:
[0077] S11. Dissolve 3-mercaptopropionic a...
Embodiment 2
[0083] This embodiment provides a white light quantum dot light-emitting diode and a manufacturing method thereof. The white light quantum dot light emitting diode includes laminated ITO glass, a PEDOT layer, a TFB layer, a CdSe red light quantum dot light emitting layer, a CdSe green light quantum dot light emitting layer, a CdSe blue light quantum dot light emitting layer, a ZnO layer and an Al layer. And in the surface layer of the bonding surface of the CdSe red light quantum dot light-emitting layer and the CdSe green light quantum dot light-emitting layer, the quantum dots and the CdSe green light quantum dot light-emitting layer and the CdSe blue quantum dot light-emitting layer are bonded with 3-mercapto groups respectively on the surface layer. The propylamine ligand and the propylamine ligand, and the adjacent 3-mercaptopropylamine ligands, the propylamine ligands, and the 3-mercaptopropylamine ligand and the propylamine ligand are cross-linked.
[0084] The quantum dot...
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