Molding and foaming process and device of macromolecule with supercritical rapid swelling through mold pressing

A supercritical fluid and polymer technology, applied in the field of polymer molding and foaming, can solve the problems of slow physical penetration process, low production efficiency, long foaming cycle, etc., to solve the problem of excessive swelling time, improve production efficiency, The effect of solubility increase

Pending Publication Date: 2019-07-02
JIANGSU JICUI ADVANCED POLYMER MATERIAL RES INST CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention proposes a molded supercritical foaming process in order to solve the slow physical penetration process when the polymer matrix and the supercritical fluid are in c

Method used

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  • Molding and foaming process and device of macromolecule with supercritical rapid swelling through mold pressing
  • Molding and foaming process and device of macromolecule with supercritical rapid swelling through mold pressing
  • Molding and foaming process and device of macromolecule with supercritical rapid swelling through mold pressing

Examples

Experimental program
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Effect test

Example Embodiment

[0098] Example 1

[0099] Taking the production of polypropylene foam material as an example, first, polypropylene and supercritical liquid carbon dioxide are mixed according to a mass ratio of 100:3, and heated to 200°C in an injection molding system. Fill the mold cavity with high-pressure carbon dioxide of 20 MPa, and then inject the homogeneous solution in the injection molding system into the molded foaming mold. The raised lines 20 in the mold are parallel strips with a depth of 0.5mm, adjacent lines The interval is 3mm, and the width of the pattern is 1mm. After the mold is filled with polymer, it is quickly cooled to room temperature to form a pattern on the surface of the polymer to increase the surface area. The average cooling rate is about 35-45°C / min. After the surface is solidified, move the movable plate to the direction away from the cavity 9 so that the pattern can contact with high-pressure carbon dioxide and continue to swell for 20 minutes, and then the pressu...

Example Embodiment

[0100] Example 2

[0101] Take the production of polylactic acid foam material as an example. First, polylactic acid and supercritical liquid carbon dioxide are mixed according to a mass ratio of 100:3, and heated to 200°C in an injection molding system. Fill the mold cavity with high-pressure carbon dioxide of 20 MPa, and then inject the homogeneous solution in the injection molding system into the molded foaming mold. The raised lines 20 in the mold are parallel strips with a depth of 0.5mm, adjacent lines The interval is 3mm, and the width of the pattern is 1mm. After the mold is filled with polymer, it is quickly cooled to room temperature to form a pattern on the surface of the polymer to increase the surface area. The average cooling rate is about 35-45°C / min. After the surface is solidified, move the movable plate to the direction away from the cavity 9 so that the pattern can contact with high-pressure carbon dioxide and continue to swell for 20 minutes, and then the pres...

Example Embodiment

[0102] Example 3

[0103] Take the production of polyethylene terephthalate foam material as an example. First, the polyethylene terephthalate and supercritical liquid carbon dioxide are mixed according to a mass ratio of 100:2, and heated to 300 in the injection molding system. ℃. Fill the mold cavity with high-pressure carbon dioxide of 20MPa, and then inject the homogeneous solution in the injection molding system into the molded foaming mold. The raised patterns 20 in the mold are parallel strips with a depth of 0.5mm, and the adjacent patterns are separated 3mm, the width of the pattern is 1mm. After the mold is filled with polymer, it is quickly cooled to room temperature to form a pattern on the surface of the polymer to increase the surface area. The average cooling rate is about 35-45°C / min. After the surface is solidified, move the movable plate to the direction away from the cavity 9 so that the pattern can contact with high-pressure carbon dioxide and continue to swe...

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Abstract

The invention provides a molding and foaming process of a macromolecule with supercritical rapid swelling through mold pressing. The problem of low production efficiency of supercritical foaming materials due to the long contact penetration time between polymers and gas during supercritical mold pressing foaming is solved. Supercritical fluid and a polymer melt can be mixed quickly and evenly through mechanical stirring of a screw in a charging cylinder of an injection molding machine, and after a homogeneous solution is injected from the injection molding machine to a mold cavity, through regulation of the temperature and further diffusion of the supercritical fluid, regulation of the melt strength before foaming and further increasing of the gas solubility can be achieved. A two-step grading method of melt blending and solid swelling foaming can ensure rapid diffusion and swelling of the supercritical fluid in a polymer matrix, the advantages of mold pressing foaming products are remained, meanwhile, the problem of the too long swelling time caused by gas diffusion in existing mold pressing foaming processes is solved, the production efficiency of mold pressing foaming is significantly improved, and industrialization of supercritical mold pressing foaming is further promoted.

Description

technical field [0001] The invention relates to a technology and device for forming and foaming polymers that are quickly swollen by molding supercritical fluids, and belongs to the technical field of supercritical polymer foaming. Background technique [0002] At present, the preparation of microcellular foamed materials by molding supercritical foaming has attracted extensive attention from new materials and related industries. This process has many advantages such as controllable foaming ratio, large cell density and small pore size, excellent mechanical properties, wide range of applicable materials, and environmental protection. However, the biggest bottleneck of this technology is the supercritical fluid in the polymer matrix. The diffusion process is slow, which leads to the formation of a relatively stable homogeneous solution between the gas and the polymer matrix after a long time of swelling, which makes the production cycle longer, that is, the production effic...

Claims

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Application Information

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IPC IPC(8): B29C44/42B29C44/34B29C44/58
CPCB29C44/3415B29C44/3442B29C44/425B29C44/428B29C44/58
Inventor 龚鹏剑李光宪王素真黄亚江蒋根杰洪江
Owner JIANGSU JICUI ADVANCED POLYMER MATERIAL RES INST CO LTD
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